Removal Efficiency of High-Concentration H2S in a Pilot-Scale Biotrickling Filter

2006 ◽  
Vol 27 (7) ◽  
pp. 759-766 ◽  
Author(s):  
J. M. Chen ◽  
L. Y. Jiang ◽  
H. L. Sha
2021 ◽  
Author(s):  
Rania Ibrahim ◽  
Abdessamad El Hassni ◽  
Shahram Navaee-Ardeh ◽  
Hubert Cabana

Abstract Hydrogen sulfide (H2S) is one of the main contaminants found in biogas which is one of the end products of the anaerobic biodegradation of proteins and other sulfur-containing compounds in solid waste. The presence of H2S is one of the factors limiting the valorization of biogas. To valorize biogas, H2S and other contaminants must be removed. This study evaluated the performance of a pilot-scale biotrickling filter system on H2S removal from landfill biogas. The biotrickling filter system, which was packed with stainless-steel pall rings and inoculated with an H2S-oxidizing consortium, was designed to process 1 to 10 SCFM of biogas and used to determine the removal efficiency of a high concentration of hydrogen sulfide from landfill biogas. The biofiltration system consisted of two biotrickling filters connected in series. Results indicate that the biofiltration system reduced H2S concentration by 94–97% without reduction of the methane concentration in the outlet biogas. The inlet concentration of hydrogen sulfide, supplied to the two-phase bioreactor, was in the range of 900 to 1500 ppmv. The hydraulic retention times (HRT) of the two biotrickling filters were 3.9 and 0.9 min, respectively. Approximately 50 ppmv of H2S gas was detected in the outlet gas. The maximum elimination capacity of the biotrickling filter system was found to be 272 g H2S.m− 3.h− 1. During the biological process, the performance of biotrickling filter was not affected when the pH of the recirculated liquid decreased to 2–3. The overall performance of the biotrickling filter system was described using a modified Michaelis–Menten equation, and the Ks and Vm values for the biosystem were 34.7 ppmv and 200 mg H2S/L.h− 1, respectively.


2021 ◽  
Vol 13 (8) ◽  
pp. 4591
Author(s):  
Shuanglei Huang ◽  
Daishe Wu

The tremendous input of ammonium and rare earth element (REE) ions released by the enormous consumption of (NH4)2SO4 in in situ leaching for ion-adsorption RE mining caused serious ground and surface water contamination. Anaerobic ammonium oxidation (anammox) was a sustainable in situ technology that can reduce this nitrogen pollution. In this research, in situ, semi in situ, and ex situ method of inoculation that included low-concentration (0.02 mg·L−1) and high-concentration (0.10 mg·L−1) lanthanum (La)(III) were adopted to explore effective start-up strategies for starting up anammox reactors seeded with activated sludge and anammox sludge. The reactors were refrigerated for 30 days at 4 °C to investigate the effects of La(III) during a period of low-temperature. The results showed that the in situ and semi in situ enrichment strategies with the addition of La(III) at a low-concentration La(III) addition (0.02 mg·L−1) reduced the length of time required to reactivate the sludge until it reached a state of stable anammox activity and high nitrogen removal efficiency by 60–71 days. The addition of La(III) promoted the formation of sludge floc with a compact structure that enabled it to resist the adverse effects of low temperature and so to maintain a high abundance of AnAOB and microbacterial community diversity of sludge during refrigeration period. The addition of La(III) at a high concentration caused the cellular percentage of AnAOB to decrease from 54.60 ± 6.19% to 17.35 ± 6.69% during the enrichment and reduced nitrogen removal efficiency to an unrecoverable level to post-refrigeration.


2017 ◽  
Vol 77 (1) ◽  
pp. 70-78 ◽  
Author(s):  
Yanjun Mao ◽  
Xie Quan ◽  
Huimin Zhao ◽  
Yaobin Zhang ◽  
Shuo Chen ◽  
...  

Abstract The activated sludge (AS) process is widely applied in dyestuff wastewater treatment plants (WWTPs); however, the nitrogen removal efficiency is relatively low and the effluent does not meet the indirect discharge standards before being discharged into the industrial park's WWTP. Hence it is necessary to upgrade the WWTP with more advanced technologies. Moving bed biofilm processes with suspended carriers in an aerobic tank are promising methods due to enhanced nitrification and denitrification. Herein, a pilot-scale integrated free-floating biofilm and activated sludge (IFFAS) process was employed to investigate the feasibility of enhancing nitrogen removal efficiency at different hydraulic retention times (HRTs). The results showed that the effluent chemical oxygen demand (COD), ammonium nitrate (NH4+-N) and total nitrogen (TN) concentrations of the IFFAS process were significantly lower than those of the AS process, and could meet the indirect discharge standards. PCR-DGGE and FISH results indicated that more nitrifiers and denitrifiers co-existed in the IFFAS system, promoting simultaneous nitrification and denitrification. Based on the pilot results, the IFFAS process was used to upgrade the full-scale AS process, and the effluent COD, NH4+-N and TN of the IFFAS process were 91–291 mg/L, 10.6–28.7 mg/L and 18.9–48.6 mg/L, stably meeting the indirect discharge standards and demonstrating the advantages of IFFAS in dyestuff wastewater treatment.


2011 ◽  
Vol 58-59 ◽  
pp. 154-161 ◽  
Author(s):  
F.J. Álvarez-Hornos ◽  
C. Lafita ◽  
V. Martínez-Soria ◽  
J.M. Penya-Roja ◽  
M.C. Pérez ◽  
...  

2017 ◽  
Vol 77 (4) ◽  
pp. 988-998 ◽  
Author(s):  
Tadesse Alemu ◽  
Andualem Mekonnen ◽  
Seyoum Leta

Abstract In the present study, a pilot scale horizontal subsurface flow constructed wetland (CW) system planted with Phragmites karka; longitudinal profile was studied. The wetland was fed with tannery wastewater, pretreated in a two-stage anaerobic digester followed by a sequence batch reactor. Samples from each CW were taken and analyzed using standard methods. The removal efficiency of the CW system in terms of biological oxygen demand (BOD), chemical oxygen demand (COD), Cr and total coliforms were 91.3%, 90%, 97.3% and 99%, respectively. The removal efficiency for TN, NO3− and NH4+-N were 77.7%, 66.3% and 67.7%, respectively. Similarly, the removal efficiency of SO42−, S2− and total suspended solids (TSS) were 71.8%, 88.7% and 81.2%, respectively. The concentration of COD, BOD, TN, NO3−N, NH4+-N, SO42 and S2− in the final treated effluent were 113.2 ± 52, 56 ± 18, 49.3 ± 13, 22.75 ± 20, 17.1 ± 6.75, 88 ± 120 and 0.4 ± 0.44 mg/L, respectively. Pollutants removal was decreased in the first 12 m and increased along the CW cells. P. karka development in the first cell of CW was poor, small in size and experiencing chlorosis, but clogging was higher in this area due to high organic matter settling, causing a partial surface flow. The performance of the pilot CW as a tertiary treatment showed that the effluent meets the permissible discharge standards.


2017 ◽  
Vol 76 (4) ◽  
pp. 776-784 ◽  
Author(s):  
Mijia Zhu ◽  
Jun Yao ◽  
Zhonghai Qin ◽  
Luning Lian ◽  
Chi Zhang

Wastewater produced from polymer flooding in oil production features high viscosity and chemical oxygen demand because of the residue of high-concentration polymer hydrolysed polyacrylamide (HPAM). In this study, steel slag, a waste from steel manufacturing, was studied as a low-cost adsorbent for HPAM in wastewater. Optimisation of HPAM adsorption by steel slag was performed with a central composite design under response surface methodology (RSM). Results showed that the maximum removal efficiency of 89.31% was obtained at an adsorbent dosage of 105.2 g/L, contact time of 95.4 min and pH of 5.6. These data were strongly correlated with the experimental values of the RSM model. Single and interactive effect analysis showed that HPAM removal efficiency increased with increasing adsorbent dosage and contact time. Efficiency increased when pH was increased from 2.6 to 5.6 and subsequently decreased from 5.6 to 9.3. It was observed that removal efficiency significantly increased (from 0% to 86.1%) at the initial stage (from 0 min to 60 min) and increased gradually after 60 min with an adsorbent dosage of 105.2 g/L, pH of 5.6. The adsorption kinetics was well correlated with the pseudo-second-order equation. Removal of HPAM from the studied water samples indicated that steel slag can be utilised for the pre-treatment of polymer-flooding wastewater.


2013 ◽  
Vol 16 (3) ◽  
pp. 96-105
Author(s):  
Anh Thi Kim Nguyen ◽  
Mi Thi Tra Le ◽  
Phu Ly Sy Nguyen ◽  
Nga Diep Yen Dang ◽  
Hien Thi To

This research aimed at investigating the species of microorganisms from activated sludge is capable of handling gas-containing phenol vapor by means of trickling biofilter. By isolating and culturing microorganisms, two species, Bacillus pumilus and Bacillus thuringiensis, was discovered to dominate in phenol vapor removal equipment with high efficiency (about 90% with B. pumilus strain and 92% with B. thuringiensis strains) at inlet concentration about 650 - 850 mg/Nm3 and air flow of 1.5 L/min. Simultaneously, similar experiments were carried out with mixed microorganisms obtained removal efficiency of more than 80%. This result showed that microorganisms after being isolated gave higher performance than mixture of microorganisms. In particular, strain of B. thuringiensis could handle up to 3600 mg/Nm3 in inlet concentration at about 184.3 gphenolm-3.h-1 elimination capacity when removal efficiency was over 92%.


2020 ◽  
Vol 58 (5A) ◽  
pp. 22
Author(s):  
Dao Thanh Son ◽  
Van Tai Nguyen ◽  
Thuy Nhu Quynh Vo ◽  
Vinh Quang Tran ◽  
Thi My Chi Vo ◽  
...  

Heavy metal contamination is among the globally environmental and ecological concerns. In this study we assessed the development of the two green algae Schroederia setigera and Selenastrum bibraianum under exposures to 5 – 200 µg/L of Ni, Zn, and Cd in the laboratory conditions. Heavy metal removal efficiency of S. setigera was also tested in 537 µg Ni/L, 734 µg Zn/L, and 858 µg Cd/L. We found that the exposures with these heavy metals caused inhibitory on the growth of S. bibraianum. The S. bibraianum cell size in the 200 µg Zn/L treatment was around two times smaller than the control. However, Zn and Cd at the concentration of 200 µg/L did not inhibit the growth of S. setigera over 18 days of exposure. The S. setigera also grew well during 8 days exposed to Ni at the same concentration. Besides, the alga S. setigera could remove 66% of Zn, 18% of Cd and 12% of Ni out of the test medium after 16 days of incubation. The Vietnam Technical Regulation related to metals should be considered for ecological protection. We recommend to test the metal removal by the alga S. setigera at pilot scale prior to apply it in situ


2020 ◽  
Vol 82 (9) ◽  
pp. 1795-1807 ◽  
Author(s):  
Dejun Bian ◽  
Zebing Nie ◽  
Fan Wang ◽  
Shengshu Ai ◽  
Suiyi Zhu ◽  
...  

Abstract A micro-pressure swirl reactor (MPSR) was developed for carbon and nitrogen removal of wastewater, in which dissolved oxygen (DO) gradient and internal circulation could be created by setting the aerators along one side of the reactor, and micro-pressure could be realized by sealing most of the top cap and increasing the outlet water level. In this study, velocity and DO distribution in the reactor was measured, removal performance treating high-concentration wastewater was investigated, and the main functional microorganisms were analyzed. The experiment results indicated that there was stable swirl flow and spatial DO gradient in MPSR. Operated in sequencing batch reactor mode, distinct biological environments spatially and temporally were created. Under the average influent condition of chemical oxygen demand (COD) concentration of 2,884 mg/L and total nitrogen (TN) of 184 mg/L, COD removal efficiency and removal loading was 98% and 1.8 kgCOD/(m3·d) respectively, and TN removal efficiency and removal loading reached up to 90% and 0.11 kgTN/(m3·d) respectively. With efficient utilization of DO and simpler configuration for simultaneous nitrification and denitrification, the MPSR has the potential of treating high-concentration wastewater at lower cost.


2018 ◽  
Vol 1 (3) ◽  
Author(s):  
Nusa Idaman Said ◽  
Firly Firly

An experiment of anaerobic biofilter using honeycomb plastic media was conducted in semi-pilot scale. This paper describes the pilot plan study of chicken’s slaughterhouse wastewater treatment using anaerobic and aerobic submerged biofilter using honeycomb plastic media. The main research was conducting by continuous operation under condition 4 days, 2 days and 1 day retention time. The result of experiment shows that within the anaerobic process under conditions 1- 4 days retention time, the removal efficiency of COD were 78 – 87 %, BOD  were 78 – 89   %, 73 – 83 % , and Total Suspended Solids (TSS) were 83 – 96 %  respectively.  Using combined anaerobic and aerobic process under same conditions 1 - 4 days retention time shows increasing of removal efficiency.  The removal efficiency of COD were 86 – 90 %, BOD were 85 – 90 %, Organics (KMnO4) were 81 – 88 % and Total Suspended Solids (TSS) were 94 – 96 % respectively.  The longer retention time has resulted in higher removal efficiency. Kata Kunci : Biofilter anaerobik, media sarang tawon, air limbah, rumah potong ayam.


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