Transparent EVA film with spectrally selective blocking capacity of ultraviolet and high-energy visible light

Author(s):  
Puzhong Gu ◽  
Mengsi Zhang ◽  
Zhihong Liu ◽  
Jun Zhang
2017 ◽  
Vol 41 (15) ◽  
pp. 7562-7570 ◽  
Author(s):  
Fanxia Kong ◽  
Yuguo Xia ◽  
Xiuling Jiao ◽  
Dairong Chen

Annular TiO2 nanoparticles were synthesized through a combined solvothermal and etching process.


2020 ◽  
Author(s):  
Katie Rykaczewski ◽  
Corinna Schindler

<div> <p>One of the most efficient ways to synthesize oxetanes is the light-enabled [2+2] cycloaddition reaction of carbonyls and alkenes, referred to as the Paternò-Büchi reaction. The reaction conditions for this transformation typically require the use of high energy UV light to excite the carbonyl, limiting the applications, safety, and scalability. We herein report the development of a visible light-mediated Paternò-Büchi reaction protocol that relies on triplet energy transfer from an iridium-based photocatalyst to the carbonyl substrates. This mode of activation is demonstrated for a variety of aryl glyoxylates and negates the need for both, visible light-absorbing carbonyl starting materials or UV light to enable access to a variety of functionalized oxetanes in up to 99% yield.</p> </div> <br>


2020 ◽  
Author(s):  
Michael O'Hagan ◽  
Javier Ramos Soriano ◽  
Susanta Haldar ◽  
Juan Carlos Morales ◽  
Adrian Mulholland ◽  
...  

<div><p>Photoresponsive ligands for G-quadruplex oligonucleotides (G4) offer exciting opportunities for the reversible regulation of these assemblies with potential applications in biological chemistry and responsive nanotechnology. However, achieving the robust regulation of G4 ligand activity with low-energy visible light sources that are easily accessible and compatible with biological systems remains a significant challenge to realizing these applications. Herein, we report the G4-binding properties of a photoresponsive dithienylethene (DTE). We demonstrate the first example of G4-specific acceleration of the photoswitching kinetics of a small molecule and the visible-light mediated switching of the G4 ligand binding mode in physiologically-relevant conditions, which in turn allows control over the G4 tetrad structure of telomeric G4 in potassium buffer. The process is fully reversible and avoids the need for high-energy UV light. This affords an efficient, practical and biologically-relevant means of control that may be applied in the generation of new responsive G4/ligand supramolecular systems.</p></div><br>


2018 ◽  
Vol 3 ◽  
pp. AB024-AB024
Author(s):  
Marie-Christine Lambert ◽  
Mathieu Ouellette ◽  
Élodie Boisselier ◽  
Patrick J. Rochette

Author(s):  
Rohini Singh ◽  
Suman Dutta

This chapter explores the concept of visible light active nanocomposites for the enhanced photocatalytic hydrogen generation and dye degradation. Since the late 1960s, A. Fujishima has been involved in unfolding the fascinating characteristics of titanium dioxide (TiO2) as semiconductor oxide. The increased growth in population and industrial development has tremendously increased the generation of waste products and consumption of energy worldwide. This situation creates an immense need of clean and sustainable alternative sources of energy. Hydrogen, having a high energy capacity, is considered as a reliable fuel for the future energy requirements. In addition to that, due to the rapid industrialisation, our water is being contaminated with various harmful industrial effluents. This chapter illustrates the significance of visible light nanocomposites for the photocatalytic application of hydrogen generation for future energy security and dye degradation for the effective effluent treatment of textile industries.


2015 ◽  
Vol 3 (42) ◽  
pp. 21244-21256 ◽  
Author(s):  
Meryam Zalfani ◽  
Benoit van der Schueren ◽  
Zhi-Yi Hu ◽  
Joanna C. Rooke ◽  
Ramzi Bourguiga ◽  
...  

BiVO4 nanoparticles in the 3DOM TiO2 inverse opal structure act as a sensitizer to absorb visible light and to transfer efficiently high energy electrons to TiO2 to ensure long lifetime of photogenerated charges and keep them well separated, explaining the extraordinarily high photocatalytic performance of 3DOM BiVO4/TiO2 nanocomposites.


2016 ◽  
Vol 4 (1) ◽  
pp. 28-32 ◽  
Author(s):  
Wei Teng Neo ◽  
Ching Mui Cho ◽  
Zugui Shi ◽  
Soo-Jin Chua ◽  
Jianwei Xu

Neutral-state black electrochromic polymers were achieved by incorporating an additional donor to enhance the blue-absorption.


1995 ◽  
Vol 41 (139) ◽  
pp. 445-454
Author(s):  

AbstractThe first four strings of phototubes for the AMANDA high-energy neutrino observatory are now frozen in place at a depth of 800-1000 m in ice at the South Pole, During the 1995-96 season, as many as six more strings will be deployed at greater depths. Provided absorption, scattering and refraction of visible light are sufficiently small, the trajectory of a muon into which a neutrino converts can be determined by using the array of phototubes to measure the arrival times of Cherenkov light emitted by the muon. To help in deciding on the depth for implantation of the six new strings, we discuss models of age vs depth for South Pole ice, we estimate mean free paths for scattering from bubbles and dust as a function of depth and we assess distortion of light paths due to refraction at crystal boundaries and interfaces between air-hydrate inclusions and normal ice. We conclude that the interval 1600-2100 m will be suitably transparent for a future 1 km3 observatory except possibly in a region a few tens of meters thick at a depth corresponding to a peak in the dust concentration at 60 k year BP.


RSC Advances ◽  
2020 ◽  
Vol 10 (41) ◽  
pp. 24555-24569
Author(s):  
Yi-en Du ◽  
Wanxi Li ◽  
Yang Bai ◽  
Zewen Huangfu ◽  
Weijin Wang ◽  
...  

TiO2/Ag3PO4 composites with co-exposed {101}, {010}/{100}, {001} and [111]-facets were successfully synthesized by combining hydrothermal and ion-exchange methods.


2015 ◽  
Vol 3 (6) ◽  
pp. 2701-2706 ◽  
Author(s):  
Mu Xiao ◽  
Yaguang Li ◽  
Yangfan Lu ◽  
Zhizhen Ye

The cubic form ZrO2:Fe nanostructures with high energy level of CBM and visible light driven hydrogen production performance were synthesized.


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