Storage stability characterization and improvement of SBS and crumb rubber composite modified asphalt

Author(s):  
Feipeng Xiao ◽  
Qidi Zong ◽  
Jingang Wang ◽  
Jun Chen ◽  
Ji Liu
2013 ◽  
Vol 703 ◽  
pp. 86-89
Author(s):  
Zhao Hui Liu ◽  
Jing Yi Zhang ◽  
Ting Zhou ◽  
Sheng Li

Focus on destruction features of the rigid-flexible composite pavement interlayer, Crumb rubber modified asphalt, SBS and crumb rubber composite modified asphalt, SBS modified asphalt were prepared. High temperature stability performance, medium-temperature fatigue performance and adhesive property of three knds of interlaminar material were evaluated and compared. Test results show that high temperature PG grade of SBS and crumb rubber composite modified asphalt is PG82, which showed better high temperature stability. Moreover, crumb rubber modified asphalt has more soft at normal temperature which benefited to medium-temperature fatigue performance. Besides, SBS and crumb rubber composite modified asphalt possesses better interlaminar adhesive property with 60°C viscosity is 2430Pas. So SBS and crumb rubber composite modified asphalt is recommend as spraying asphalt material in rigid-flexible composite pavement interlayer, the results can provide certain reference.


Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3679
Author(s):  
Juan Xie ◽  
Yongning Zhang ◽  
Yueming Yang ◽  
Yunlong Ma ◽  
Jing Li ◽  
...  

Poor storage stability is a key problem restricting the rapid development and wide application of rubber-modified asphalt binder, and activation of rubber has shown good prospects to solve this problem. In this study, two activation methods, coating by polyamide 6 and grafting by acrylamide, were introduced to treat crumb rubber. Then the activated rubber was added to base asphalt binder to prepare modified asphalt binder. The chemical structure and morphology of rubber powder before and after activation and of asphalt binder before and after modification were characterized by Fourier transformation infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). The conventional and rheological properties and storage stability were analyzed to reveal the influence of activation method on the performance of asphalt binder. The results showed that after being activated, the surface of the rubber is loose and rough. A chemical reaction did not occur during activation by polyamide but occurred during activation by acrylamide. The activation of the rubber effectively improved the high- and low-temperature performance, and the softening difference decreased by 79.8%. This is because the interaction between rubber and asphalt binder was enhanced through activation of rubber, and grafting activation had better effect due to the chemical reaction between the basic amide groups of acrylamide and acid groups of asphalt binder.


Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 641 ◽  
Author(s):  
Zhibin Ren ◽  
Yongqiang Zhu ◽  
Qi Wu ◽  
Minye Zhu ◽  
Feng Guo ◽  
...  

The storage stability concern, caused by phase separation for the density difference between polymers and asphalt fractions, has limited the widespread application of polymer modified asphalt (PMA). Therefore, this study aims to improve the storage concern of PMA by incorporating nano-montmorillonite. To this end, different nano-montmorillonites were incorporated to three PMAs modified with three typical asphalt modifiers, i.e., crumb rubber (CRM), styrene–butadiene-rubber (SBR) and styrene–butadiene-styrene (SBS). A series of laboratory tests were performed to evaluate the storage stability and rheological properties of PMA binders with nano-montmorillonite. As a consequence, the incorporation of nano-montmorillonite exhibited a remarkable effect on enhancing the storage stability of the CRM modified binder, but limited positive effects for the SBR and SBS modified binders. The layered nano-montmorillonite transformed to intercalated or exfoliated structures after interaction with asphalt fractions, providing superior storage stability. Among selected nano-montmorillonites, the pure montmorillonite with Hydroxyl organic ammonium performed the best on enhancing storage stability of PMA. This paper suggests that nano-montmorillonite is a promising modifier to alleviate the storage stability concern for asphalt with polymer modifiers.


Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1563 ◽  
Author(s):  
Xie ◽  
Yang ◽  
Lv ◽  
Zhang ◽  
Zhu ◽  
...  

Acrylamide with a double bond and amide group can not only copolymerize with macromolecules of crumb rubber but also react with acidic groups in asphalt, so it was selected as a modifier to activate crumb rubber through chemical graft action. The purpose is to improve the compatibility between crumb rubber and asphalt and thus improve the rheological properties and storage stability of rubber asphalt. Infrared spectroscopy (IR) and scanning electron microscopy (SEM) were used to characterize the crumb rubbers and their modified asphalt. It was found that the crumb rubber of grafting acrylamide had better compatibility in asphalt due to its larger specific surface area and chemical reaction with asphalt. In addition, the high temperature rheological test, low temperature creep test, and polymer separation test were carried out to study the effect of grafted activated crumb rubber on the properties of modified asphalt. The results showed that compared with modified asphalt with common crumb rubber (CRMA), the rheological properties and storage stability of modified asphalt with grafting activated crumb rubber (A–G–R) were improved significantly. The results of microscopic and macroscopic tests show that the activated rubber particles have a larger contact area with asphalt due to a rougher surface and the chemical cross-linking between rubber particles and asphalt further strengthens their interaction. Therefore, there is a relatively stable blend system formed in modified asphalt, and its performance of modified asphalt has been improved.


Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2693
Author(s):  
Weihong Liu ◽  
Yishen Xu ◽  
Hongjun Wang ◽  
Benan Shu ◽  
Diego Maria Barbieri ◽  
...  

Segregation of waste crumb rubber powder (WR) modified asphalt binders the large-scale application of WR in asphalt. The method of microwave activation combined with chemical activation (KMWR) was proposed to improve storage stability and rheological properties of WR modified asphalt in this work. Storage stability and rheological properties of virgin asphalt, MWR modified asphalt, and KMWR modified asphalt were comparatively studied by the standard segregation test, bending beam rheometer (BBR) test, and dynamic shear rheometer (DSR) test. The effect of composite activation on waste rubber powder particles was studied by Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), and Brunauer–Emmett–Teller (BET) tests. The main results showed that after the physical and chemical composite activation, the storage stability of waste rubber powder modified asphalt was significantly improved, WR modified asphalt had better crack resistance, better rutting resistance, and better fatigue performance. After physical and chemical activation, WR was desulfurized, and a large number of active groups was grafted on the WR particles.


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