scholarly journals Modification of the copper wettability by nanosecond laser texturing

2021 ◽  
Vol 2119 (1) ◽  
pp. 012126
Author(s):  
M M Vasilev ◽  
Y G Shukhov ◽  
A A Rodionov ◽  
Y P Li ◽  
M K Lei

Abstract Nanosecond laser microstructuring of copper surfaces was performed in this work. The contact angle value immediately after laser treatment decreased sharply and all samples were hydrophilic or superhydrophilic. Hydrophobization of the textured samples occurs as a result of environmental exposure over time. Oxidation and adsorption of carbon and its compounds from the atmosphere leads to a change in the wettability of the irradiated surfaces. The acceleration of hydrophobization process with decrease of fluence was found. It is shown that the stable contact angle, reached after one month, does not depend on the value of the fluence and is about 140°.

Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2240 ◽  
Author(s):  
Peter Gregorčič ◽  
Marjetka Conradi ◽  
Luka Hribar ◽  
Matej Hočevar

Controlling the surface wettability represents an important challenge in the field of surface functionalization. Here, the wettability of a stainless-steel surface is modified by 30-ns pulses of a Nd:YAG marking laser (λ = 1064 nm) with peak fluences within the range 3.3–25.1 J cm−2. The short- (40 days), intermediate- (100 days) and long-term (1 year) superhydrophilic-to-(super)hydrophobic transition of the laser-textured surfaces exposed to the atmospheric air is examined by evaluating its wettability in the context of the following parameters: (i) pulse fluence; (ii) scan line separation; (iii) focal position and (iv) wetting period due to contact angle measurements. The results show that using solely a short-term evaluation can lead to wrong conclusions and that the faster development of the hydrophobicity immediately after laser texturing usually leads to lower final contact angle and vice versa, the slower this transition is, the more superhydrophobic the surface is expected to become (possibly even with self-cleaning ability). Depending on laser fluence, the laser-textured surfaces can develop stable or unstable hydrophobicity. Stable hydrophobicity is achieved, if the threshold fluence of 12 J cm−2 is exceeded. We show that by nanosecond-laser texturing a lotus-leaf-like surface with a contact angle above 150° and roll-off angle below 5° can be achieved.


2021 ◽  
Vol 15 (4) ◽  
pp. 8592-8600
Author(s):  
M.H. Zul ◽  
Mahadzir Ishak@Muhammad ◽  
M. H. Aiman ◽  
M. M. Quazi

The use of lasers in surface engineering has recently made significant progress. The hydrophobic surface is commonly studied because of the application in various fields, including vehicles, aerospace, biomedicine, etc. Since these laser methods require many combination parameters, such as laser power (P), frequency (ƒ), scan speed (ʋ) and laser beam diameter (D), the effect of the parameters must therefore be investigated to produce the hydrophobic condition. This research tries to relate the laser power with the morphological properties and contact angle of the SS316L surfaces. Samples are subjected to laser texturing with different laser power settings. The surface is then characterised by surface roughness, and the contact angle is measured according to a specific time interval. The laser power output and energy density function on the surface and contact angle were investigated in these contexts experimentally. Surface roughness was defined and validated to show that the laser parameters' effect is effective and controllable. This study shows that the laser output intensity significantly contributes to regulating surface roughness and the substrate's wetting activity. The 18W and 24W laser outputs produce a spiked surface with various peaks that cause the surface to become hydrophobic over time because of the air-trap that happens in the valley.


2019 ◽  
Vol 60 ◽  
pp. 124-141 ◽  
Author(s):  
Naser Ali ◽  
Joao Amaral Teixeira ◽  
Abdulmajid Addali

This research investigates the effect of surface roughness, water temperature, and pH value on the wettability behaviour of copper surfaces. An electron beam physical vapour deposition technique was used to fabricate 25, 50, and 75 nm thin films of copper on the surface of copper substrates. Surface topographical analysis, of the uncoated and coated samples, was performed using an atomic force microscopy device to observe the changes in surface microstructure. A goniometer device was then employed to examine the surface wettability of the samples by obtaining the static contact angle between the liquid and the attached surface using the sessile drops technique. Waters of pH 4, 7, and 9 were employed as the contact angle testing fluids at a set of fixed temperatures that ranged from 20°C to 60°C. It was found that increasing the deposited film thickness reduces the surface roughness of the as-prepared copper surfaces and thus causing the surface wettability to diverge from its initial hydrophobic nature towards the hydrophilic behaviour region. A similar divergence behaviour was seen with the rise in temperature of water of pH 4, and 9. In contrast, the water of pH 7, when tested on the uncoated surface, ceased to reach a contact angle below 90o. It is believed that the observed changes in surface wettability behaviour is directly linked to the liquid temperature, pH value, surface roughness, along with the Hofmeister effect between the water and the surface in contact.


2014 ◽  
Vol 62 ◽  
pp. 9-16 ◽  
Author(s):  
Andrew Dunn ◽  
Jesper V. Carstensen ◽  
Krystian L. Wlodarczyk ◽  
Erica B. Hansen ◽  
Jack Gabzdyl ◽  
...  

Vacuum ◽  
2021 ◽  
pp. 110635
Author(s):  
Yongfeng Qian ◽  
Minqiang Jiang ◽  
Zhiyu Zhang ◽  
Hu Huang ◽  
Jiwang Yan

Author(s):  
F. Arias-González ◽  
A. Badaoui ◽  
R. Comesaña ◽  
F. Lusquiños ◽  
J. Pou ◽  
...  

2021 ◽  
Vol 899 ◽  
pp. 326-331
Author(s):  
Zhanna I. Kurdanova ◽  
Kamila T. Shakhmurzova ◽  
V.A. Guchinov ◽  
Ilya Kobyhno ◽  
Andrey Bezborodov

The wettability of reinforcing fillers such as glass and carbon fibers is a significant factor influencing the mechanical properties of the composite. This study focuses on the effect of finishing glass fiber surfaces with different concentrations of oligophenylene sulfide sulfone solution on fiber wettability, which is determined by contact angle and wetting time. The Adam-Schütte method was chosen as a method for determining the contact angle. According to the study results a 1.5% solution of oligophenylene sulfide sulfone in N, N'-dimethylacetamide gives a contact angle of 45°, forming over time a thin film on the fiber surface, which indicates a sufficiently high sizing ability.


2010 ◽  
Vol 23 (7) ◽  
pp. 848-853 ◽  
Author(s):  
Juan R. Sanchez-Valencia ◽  
Johann Toudert ◽  
Ana Borras ◽  
Angel Barranco ◽  
Ruth Lahoz ◽  
...  

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