scholarly journals Utilizing industrial by-products as eco-friendly adsorbent for phosphate removal: An experimental approach

2021 ◽  
Vol 877 (1) ◽  
pp. 012050
Author(s):  
S. Mohammed

Abstract One of the widely present elements in the groundwater and surface water is phosphate due to two reasons; firstly, it is available at high concentrations in the soil, and secondly, it is widely available in wastewaters (industrial, agricultural and domestic wastewaters). Although phosphate causes many problems to the aquatic environment, eutrophication is the most severe problem due to its effects on water quality, economy, and health. Therefore, a number of studies have been made to evaluate the ability of different remedies to eliminate phosphates from wastewaters. Recently, phosphorus extraction may be achieved by filtering the contaminated solution. However, the cost of filtration materials is still high. Due to this reason, research to date has focused on employing inexpensive materials to reduce the cost of the filtering process. In this research, a by-product of steel manufacturing, kiln bottom ashes, was used to extract phosphates from polluted wastewater, considering the impacts of a number of operating parameters, such as to achieve the best possible extraction efficiency for the lowest possible cost. The findings of this study proved the excellent ability of the bottom ash in the extraction of phosphate from wastewater, where it removed more than 90% of 5 mg/L of phosphate after 40 minutes of treatment using 530 mg/L of bottom ash.

Soil Research ◽  
2004 ◽  
Vol 42 (7) ◽  
pp. 755 ◽  
Author(s):  
R. W. McDowell

A study was conducted of the effectiveness of applying various rates (0–50 g/kg) of fly and bottom ash (<2 mm and 2–4 mm) from a coal-fired power plant, and melter (AP10B and PAP5) and basic (KOBM) slags from a steel-manufacturing plant on mitigating phosphorus (P) loss from a Pallic soil sown to pasture. Measurements were made of soil pH, Olsen P, and H2O-P (as a measure of P loss in overland flow), and soluble P and contaminants (B, As, Cd, Pb, Se) from a weekly leaching regime for 9 weeks. Results shows that H2O-P had decreased up to 40% in soils treated at the greatest rate of melter slag (50 g/kg), and increased in KOBM and fly ash treated soils. The effect on Olsen P relative to H2O-P was much less in metler slag and bottom ash treated soils than soils treated with fly ash or KOBM slag. The fly ash was considered unsuitable for the mitigation of P loss from soils due to B toxicity to plants, while KOBM is also unsuitable due to a liming effect and the increase in soluble P loss. At the rates applied, no treated soil leached toxic metals (As, Cd, Hg, or Se) above current guidelines. In contrast, the incorporation of melter slag and bottom ash is considered an effective P loss mitigation strategy.


2010 ◽  
Vol 61 (3) ◽  
pp. 599-606 ◽  
Author(s):  
Johnsely S. Cyrus ◽  
G. B. Reddy

Constructed wetland systems have gained attention as attractive solutions for wastewater treatment. Wetlands are not efficient to treat wastewater with high concentrations of phosphorus (P). In order to remove high soluble P loads by wetland, sorbent beds can be added prior to the discharge of wastewater into wetlands. Sorption by sorbent materials is identified as a method for trapping excess P in wastewaters. In the present investigation, shale has been identified as a sorbent material for removal of phosphate (PO4-P) due to the cost effectiveness, stability and possibility of regeneration. The study focuses on the removal of PO4-P from wastewater using shale and the feasibility of using the P-sorbed material as slow-release fertilizer. Phosphorus sorption experiments were conducted by using shale (2 mm and 2–4.7 mm). Results indicate that Shale I (particle size = 2 mm) showed the highest sorption of PO4-P (500 ± 44 mg kg−1). Breakthrough point was reached within 10 h in columns with flow rates of 2 and 3 ml min−1. Lower flow rate of 1 ml min−1 showed an average residence time of about 2 h while columns with a higher flow rate of 3 ml min−1 showed a residence time of about 40 minutes. Variation in flow rate did not influence the desorption process. Since very low concentrations of PO4-P are released, Shale saturated with PO4-P may be used as a slow nutrient release source of P or as a soil amendment. The sorbent can also be regenerated by removing the sorbed PO4-P by using 0.1 N HCl.


1996 ◽  
Vol 33 (3) ◽  
pp. 119-130 ◽  
Author(s):  
Allen C. Chao ◽  
Sergio J. de Luca ◽  
Carlos N. Idle

Studies concerning the treatment, stabilization and final disposal of biosolids, one of the by-products of wastewater treatment, in environmental recovery, have been intensified by the sanitary and environmental effects of land disposal. The careful assessment of biosolid quality shows that, when appropriately managed, the environmental risks of their uses can be minimized by chemical stabilization, and biosolids could even be used as fertilizer and soil conditioner. A research study of biosolid stabilization was performed using lime as a standard process compared to potassium ferrate (VI). The chances of leaching and solubilization of metals were tested, simulating conditions for disposal in the environment. The sanitary effectiveness in terms of pathogens (bacteria, fungi and helminth eggs) were also evaluated. Experiments were performed on the lime and ferrate(VI) treatment of compounds such as ammonia, nitrate, soluble sulphides, and total sulphates, indicators of odouriferous offensive compounds which might occasionally prevent some uses of the solids, and the results are presented in this paper. Wastewater Treatment Plants emit offensive odours generated during the sewage treatment process, as well as during the treatment and the management of biosolids. This occurs in the drying beds and the spreading of biosolids on land, due to the high concentrations of sulphur compounds, nitrogen compounds, acids and organic compounds (aldehydes and ketones). The potassium ferrate(VI) utilized in the research is a powerful oxidizing agent throughout the pH scale, with the advantage of not generating by-products which will cause toxicity or mutagenicity (DE LUCA, 1981). The ion ferrate(VI) has greater oxidizing power than permanganate, e.g., it oxidizes reduced sulfur forms to sulphate, ammonia to nitrate, hypochlorite to chlorite and chlorite to chlorate(DE LUCA et al., 1992; CHAO et al., 1992). This paper shows that, as expected, the potassium ferrate (VI) treatment replaces several chemical products utilized for odour control of sludges, mainly aggressive odours caused by ammonia and sulphides, through the formation of precipitates with iron compounds. Ferrate (VI) has often been shown to destroy soluble sulphides, transforming them into sulphate. The generation of oxygen in the decomposition of ferrate(VI) increases its oxidizing power. Ferrate(VI) applied to sludges also has the double effect of transforming ammonia into nitrates, such that this product takes the place of sulphates, acting as an electron acceptor, thus preventing the development of further odours when biosolids are utilized.


2005 ◽  
Vol 50 (4) ◽  
pp. 213-217 ◽  
Author(s):  
Brian J Cox ◽  
Nancy Yu ◽  
Tracie O Afifi ◽  
Robert Ladouceur

Objective: The 1990s saw widespread expansion of new forms of legalized gambling involving video lottery terminals (VLTs) in community settings (that is, in bars and restaurant lounges) and permanent casinos in several Canadian provinces. To date, there has never been a national survey of gambling problems with representative interprovincial data. Using a new survey, we sought to compare prevalence figures across the 10 Canadian provinces. Method: Using the Canadian Problem Gambling Index, we investigated the current 12-month prevalence of gambling problems in the Canadian Community Health Survey: Cycle 1.2—Mental Health and Well-Being, in which a random sample of 34 770 community-dwelling respondents aged 15 years and over were interviewed. The response rate was 77%. The data are representative at the provincial level and were compared with the availability of VLTs per 1000 population and with the presence of permanent casinos for each province. Results: Manitoba (2.9%) and Saskatchewan (also 2.9%) had the highest prevalence of gambling problems (specifically, moderate and severe problem levels combined). These 2 provinces had significantly higher levels than the 2 provinces with the lowest prevalence of gambling problems: Quebec (1.7%) and New Brunswick (1.5%). Conclusions: The 12-month prevalence of gambling problems in Canada was 2.0%, with interprovincial variability. The highest prevalence emerged in areas with high concentrations of VLTs in the community combined with permanent casinos. These findings support earlier predictions that the rapid and prolific expansion of new forms of legalized gambling in many regions of the country would be associated with a considerable public health cost.


2021 ◽  
Vol 47 (1) ◽  
pp. 1-18
Author(s):  
Keolebogile R. Sebogodi ◽  
Jonas K. Johakimu ◽  
B. Bruce Sithole

Acid mine drainage (AMD) is one of the repercussions that result from earth-moving activities around the sulfide-bearing mineral hosts. The detrimental effects associated with this AMD are driven by its characteristics, which include low pH and high concentrations of sulfate and toxic dissolved metals. Traditionally, the prevention and treatment of AMD are achieved by using technologies that use, amongst other, naturally occurring soils and carbonates. However, the continual use of these materials may eventually lead to their depletion. On the other hand, industrial by-products have been proven to occupying land that could have otherwise been used for profitable businesses. Additionally, the handling and maintenance of landfills are costly. In this current trend of a circular economy that is driven by industrial symbiosis, scientists are concerned with valorizing industrial by-products. One such by-product is the green liquor dregs (GLD) from Kraft mills. The neutralizing and geotechnical properties of these wastes have prompted the research pioneers to seek their potential use in handling the challenges associated with AMD. In this review, the formation AMD, trends in technologies for treatment and prevention of AMD are critically analyzed. This includes the feasibility of using GLD as an alternative, promising sustainable material.


2020 ◽  
Vol 165 ◽  
pp. 05033
Author(s):  
Guoming Zeng ◽  
Jing Luo ◽  
Xiaowan Liu ◽  
Maolan Zhang ◽  
Hengjun Tang

With the increasing of water pollution, water eutrophication is seriously affecting people’s daily life and production. Therefore, it is particularly important to explore safe and efficient algae control technology. In the current algal bloom treatment methods, the physical method is not complete in algae dissolving, and the cost of algal control is high. The chemical method is easy to produce secondary pollution and toxic by-products, and the safety is not high. However, the biological method has the advantages of low cost, high ecological security and good ecological compatibility. It is considered to be a more promising method to remove algae and biological toxins, and it is also an inevitable trend to control water eutrophication in the future.


2005 ◽  
Vol 2005 ◽  
pp. 222-222 ◽  
Author(s):  
R. Feizi ◽  
A. Ghodratnama ◽  
M. Zahedifar ◽  
M. Danesh Mesgaran ◽  
M. Raisianzadeh

Pomegranate by-products (peel and seed) contain about 40-45 percent of the fruit’s weight, but little information is available on their nutritive value. Chemical analysis of the pomegranate seed (PS) show that it contains average of 10-12 percent of crude protein. PS also contain a little amount of tannin (about 2.7 percent). Since feed accounts for 75-85% of the total costs of meet production and the use of them in feeding ruminant may decrease the cost of feeding. The objective of this experiment was also to determine nutrients digestibility of PS.


2016 ◽  
Vol 2016 ◽  
pp. 1-6 ◽  
Author(s):  
M. Adama ◽  
R. Esena ◽  
B. Fosu-Mensah ◽  
D. Yirenya-Tawiah

Waste incineration is the main waste management strategy used in treating hospital waste in many developing countries. However, the release of dioxins, POPs, and heavy metals in fly and bottom ash poses environmental and public health concerns. To determine heavy metal (Hg, Pb, Cd, Cr, and Ag) in levels in incinerator bottom ash and soils 100 m around the incinerator bottom ash dump site, ash samples and surrounding soil samples were collected at 20 m, 40 m, 60 m, 80 m, 100 m, and 1,200 m from incinerator. These were analyzed using the absorption spectrophotometer method. The geoaccumulation (Igeo) and pollution load indices (PLI) were used to assess the level of heavy metal contamination of surrounding soils. The study revealed high concentrations in mg/kg for, Zn (16417.69), Pb (143.80), Cr (99.30), and Cd (7.54) in bottom ash and these were above allowable limits for disposal in landfill. The study also found soils within 60 m radius of the incinerator to be polluted with the metals. It is recommended that health care waste managers be educated on the implication of improper management of incinerator bottom ash and regulators monitor hospital waste incinerator sites.


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