scholarly journals Multistages mineralization and transformation of terrigenous rocks in the Vyun ore field, Yana-Kolyma metallogenic belt, Northeast Asia: insight from the sedimentary, diagenetic and hydrothermal sulfides and geochemistry of ore-hosting rocks

2021 ◽  
Vol 906 (1) ◽  
pp. 012041
Author(s):  
Lena Polufuntikova ◽  
Valery Fridovsky ◽  
Yaroslav Tarasov ◽  
Maksim Kudrin
Keyword(s):  
Trace Elements ◽  
Middle Jurassic ◽  
Chemical Elements ◽  
Northeast Asia ◽  
Upper Triassic ◽  
Terrigenous Rocks ◽  
Metallogenic Belt ◽  
Oxygen Conditions ◽  
Hydrothermal Sulfides ◽  
Epigenetic Processes

Abstract The article presents the results of studying the sulfidization zone of the Charky-Indigirka thrust fault within the Vyun ore field in the Upper Adycha sector of the Yana-Kolyma metallogenic belt. The purpose of the research is to study the composition and distribution of basic and trace elements in terrigenous rocks of the Upper Triassic and Middle Jurassic, as well as in distal metasomatites on the territory of the Vyun ore field. The petrochemical features of weakly altered terrigenous rocks, conditions of their formation and changes of composition during epigenetic processes were analyzed. Three generations of pyrite were identified: diagenetic Py1, metamorphogenic Py2 and metasomatic Py3. Typomorphic trace elements and variations of their distribution in pyrites were determined. Composition analyses of weakly altered sedimentary rocks of the Upper Triassic (V/(V+Ni)=0.5-0.8, V/Cr=0.1-2.9 and Ni/Co=2.5-10.3) and Middle Jurassic (V/(V+Ni)=0.7-0.9, V/Cr=0.2-2.0 and Ni/Co=1.3-8.8) yielded the conclusion that changes in oxygen conditions to disoxic and anoxic, as well as the enrichment of terrigenous material with ore elements, lead to the formation of authigenic sulfide mineralization at the early stages of the sedimentary strata formation. The subsequent multistage development of the territory was accompanied by an active migration of chemical elements, their input and redistribution.

DISTRIBUTION OF DISSOLVED CHEMICAL ELEMENTS IN THE YENISEI RIVER ESTUARY AND ADJACENT WATER AREA OF THE KARA SEA

2017 ◽  
Author(s):  
Alla Savenko ◽  
Alla Savenko ◽  
Oleg Pokrovsky ◽  
Oleg Pokrovsky ◽  
Irina Streletskaya ◽  
...  
Keyword(s):  
Trace Elements ◽  
River Runoff ◽  
Major Ions ◽  
Chemical Elements ◽  
River Estuary ◽  
Water Area ◽  
Kara Sea ◽  
Yenisei River ◽  
Adjacent Water ◽  
The Yenisei River

The distribution of dissolved chemical elements (major ions, nutrients, and trace elements) in the Yenisei River estuary and adjacent water area in 2009 and 2010 are presented. These results were compared to the data obtained during previous hydrochemical studies of this region. The transport of major cations (Na, K, Mg, Ca) and some trace elements (Rb, Cs, Sr, B, F, As, Mo, U) in the estuary follows conservative mixing. Alkalinity also belongs to conservative components, however this parameter exhibits substantial spatial heterogeneity caused by complex hydrological structure of the Yenisei Bay and adjoining part of the Kara Sea formed under the influence of several sources of desalination and salty waters inflow. Concentrations of Pmin, Si, and V in the desalinized waters of photic layer decrease seaward owing to uptake by phytoplankton. The losses of these elements reach 30–57, 30, and 9% of their supply by river runoff, respectively. The content of dissolved phosphates and vanadium in the intermediate and near-bottom layers of the Yenisei River estuary strongly increases with salinity due to regeneration of precipitated organic matter, whereas silica remineralization is much less pronounced. Barium is characterized by additional input of dissolved forms in the mixing zone in the quantity comparable to that carried out by river runoff. This may be caused by its desorption from river suspended matter due to ion exchange. The transport of dissolved Al and Mn in the estuarine zone is probably controlled by the coagulation and flocculation of organic and organomineral colloids, which is indicated by a decrease in the concentration of these elements at the beginning of the estuary (31 and 56%, respectively) followed by a stable concentration further seaward.

Age and Composition of Zircons From the Devonian Petrivske Kimberlite Pipe of the Azov Domain, the Ukrainian Shield

2021 ◽  
Vol 43 (4) ◽  
pp. 50-55
Author(s):  
L.V. SHUMLYANSKYY ◽  
V. KAMENETSKY ◽  
B.V. BORODYNYA
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Continental Crust ◽  
Kimberlite Pipe ◽  
Zircon Crystal ◽  
Precambrian Rock ◽  
Weighted Mean ◽  
Terrigenous Rocks ◽  
Devonian Age ◽  
Isotope Systematics

Results of a study of U-Pb and Hf isotope systematics and trace element concentrations in five zircon crystals separated from the Devonian Petrivske kimberlite are reported in the paper. Four zircons have yielded Paleoproterozoic and Archean ages, while one zircon grain gave a Devonian age of 383.6±4.4 Ma (weighted mean 206Pb/238U age). The Precambrian zircons have been derived from terrigenous rocks of the Mykolaivka Suite that is cut by kimberlite, or directly from the Precambrian rock complexes that constitute continental crust in the East Azov. The Devonian zircon crystal has the U-Pb age that corresponds to the age of kimberlite emplacement. It is 14 m.y. younger than zircon megacrysts found in the Novolaspa kimberlite pipe in the same area. In addition, Petrivske zircon is richer in trace elements than its counterparts from the Novolaspa pipe. Petrivske and Novolaspa zircons crystallized from two different proto-kimberlite melts, whereas the process of kimberlite formation was very complex and possibly included several episodes of formation of proto-kimberlite melts, separated by extended (over 10 M.y.) periods of time.

scholarly journals Relation among geochemical elements in soil and red chicory as a tool for geographical origin identification.

2021 ◽  
Author(s):  
Elena Marrocchino ◽  
Serena Di Sarcina ◽  
Carlo Ragazzi ◽  
Carmela Vaccaro
Keyword(s):  
Trace Elements ◽  
Geographical Origin ◽  
Chemical Elements ◽  
Accurate Determination ◽  
Analytical Techniques ◽  
Food Products ◽  
Geochemical Data ◽  
Protected Designation Of Origin ◽  
Po Delta

<p>The identification of the geographical origin of food products is important for both consumers and producers to ensure quality and avoid label falsifications. Determination and authentication of the geographical origin of food products throughout scientific research have become recently relevant in investigations against frauds for consumer protection. Advances in methods and analytical techniques led to an increase in the application of fingerprinting analysis of foods for identification of geographical origin. Since in organic material the inorganic component is more stable than the organic one, several studies examined trace elements, suggesting the potential application for determination of geographical origin. Moreover, the studies on territoriality are based on the hypothesis that chemical elements detected in plants and in their products reflect those contained in the soil and, within these studies, the geographical features of the production area, such as the soil type and the climate, are considered relevant factors affecting the specific designation, so an accurate determination of geographical origin would be necessary to guarantee the quality and territoriality of the products.</p><p>In this light, two varieties of red chicory from the southern Po Delta area have been characterized together with the soil. The two inspected red chicory varieties (long-leaves and round-leaves) are cultivated in a well-defined area in the southern part of Po Delta, in an area sited around Massenzatica (Municipality of Mesola, Province of Ferrara, NE of Italy). Sampling was undertaken between October and December 2020 and samples were collected from a randomized field. Together with the red chicory also roots and soils have been collected in order to analyze each part and correlate the geochemical data obtained using ICP-MS and XRF techniques.</p><p>Purpose of this study is to establish a method to identify the geographical origin and the results confirm that some major and trace elements could be used as geochemical markers according to the geological areas. These elements, therefore, could be useful to establish geochemical fingerprints for testing the origin of this product and create a protected designation of origin label.</p>

scholarly journals Thermal maturity of the Upper Triassic–Middle Jurassic Shemshak Group (Alborz Range, Northern Iran) based on organic petrography, geochemistry and basin modelling: implications for source rock evaluation and petroleum exploration

2011 ◽  
Vol 149 (1) ◽  
pp. 19-38 ◽  
Author(s):  
ALI SHEKARIFARD ◽  
FRANÇOIS BAUDIN ◽  
KAZEM SEYED-EMAMI ◽  
JOHANN SCHNYDER ◽  
FATIMA LAGGOUN-DEFARGE ◽  
...  
Keyword(s):  
Middle Jurassic ◽  
Vitrinite Reflectance ◽  
Upper Triassic ◽  
Petroleum Exploration ◽  
Thermal Maturity ◽  
Northern Iran ◽  
Carbonaceous Shales ◽  
Petroleum Generation ◽  
Central Eastern ◽  
Alborz Range

AbstractOrganic petrography and geochemical analyses have been carried out on shales, carbonaceous shales and coals of the Shemshak Group (Upper Triassic–Middle Jurassic) from 15 localities along the Alborz Range of Northern Iran. Thermal maturity of organic matter (OM) has been investigated using vitrinite reflectance, Rock-Eval pyrolysis and elemental analysis of kerogen. Reflectance of autochthonous vitrinite varies from 0.6 to 2.2% indicating thermally early-mature to over-mature OM in the Shemshak Group, in agreement with other maturity parameters used. The shales of the Shemshak Group are characterized by poor to high residual organic carbon contents (0.13 to 5.84%) and the presence of hydrogen-depleted OM, predominantly as a consequence of oxidation of OM at the time of deposition and the hydrogen loss during petroleum generation. According to light-reflected microscopy results, vitrinite/vitrinite-like macerals are dominant in the kerogen concentrates from the shaly facies. The coals and carbonaceous shales of the Shemshak Group show a wide range in organic carbon concentration (3.5 to 88.6%) and composition (inertinite- and vitrinite-rich types), and thereby different petroleum potentials. Thermal modelling results suggest that low to moderate palaeo-heat flow, ranging from 47 to 79 mW m−2 (57 mW m−2 on average), affected the Central-Eastern Alborz basin during Tertiary time, the time of maximum burial of the Shemshak Group. The maximum temperature that induced OM maturation of the Shemshak Group seems to be related to its deep burial rather than to a very strong heat flow related to an uppermost Triassic–Liassic rifting. The interval of petroleum generation in the most deeply buried part of the Shemshak Group (i.e. Tazareh section) corresponds to Middle Jurassic–Early Cretaceous times. Exhumation of the Alborz Range during Late Neogene time, especially along the axis of the Central-Eastern Alborz, where maximum vitrinite reflectance values are recorded, probably destroyed possible petroleum accumulations. However, on the northern flank of the Central-Eastern Alborz, preservation of petroleum accumulations may be expected. The northern part of the basin therefore seems the best target for petroleum exploration.

scholarly journals Sulfide Breccias from the Semenov-3 Hydrothermal Field, Mid-Atlantic Ridge: Authigenic Mineral Formation and Trace Element Pattern

Minerals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 321 ◽  
Author(s):  
Irina Melekestseva ◽  
Valery Maslennikov ◽  
Nataliya Safina ◽  
Paolo Nimis ◽  
Svetlana Maslennikova ◽  
...  
Keyword(s):  
Trace Elements ◽  
Hydrothermal Field ◽  
Trace Element Pattern ◽  
Modes Of Occurrence ◽  
Element Pattern ◽  
Authigenic Mineral ◽  
Mid Atlantic Ridge ◽  
Lower Temperature ◽  
Hydrothermal Sulfides

The aim of this paper is the investigation of the role of diagenesis in the transformation of clastic sulfide sediments such as sulfide breccias from the Semenov-3 hydrothermal field (Mid-Atlantic Ridge). The breccias are composed of marcasite–pyrite clasts enclosed in a barite–sulfide–quartz matrix. Primary hydrothermal sulfides occur as colloform, fine-crystalline, porous and radial marcasite–pyrite clasts with inclusions or individual clasts of chalcopyrite, sphalerite, pyrrhotite, bornite, barite and rock-forming minerals. Diagenetic processes are responsible for the formation of more diverse authigenic mineralization including framboidal, ovoidal and nodular pyrite, coarse-crystalline pyrite and marcasite, anhedral and reniform chalcopyrite, inclusions of HgS phase and pyrrhotite–sphalerite–chalcopyrite aggregates in coarse-crystalline pyrite, zoned bornite–chalcopyrite grains, specular and globular hematite, tabular barite and quartz. The early diagenetic ovoid pyrite is enriched in most trace elements in contrast to late diagenetic varieties. Authigenic lower-temperature chalcopyrite is depleted in trace elements relative to high-temperature hydrothermal ones. Trace elements have different modes of occurrence: Se is hosted in pyrite and chalcopyrite; Tl is related to sphalerite and galena nanoinclusions; Au is associated with galena; As in pyrite is lattice-bound, whereas in chalcopyrite it is related to tetrahedrite–tennantite nanoinclusions; Cd in pyrite is hosted in sphalerite inclusions; Cd in chalcopyrite forms its own mineral; Co and Ni are hosted in chalcopyrite.

A Comprehensive Review of Minerals, Trace Elements, and Heavy Metals in Saffron

2022 ◽  
Vol 23 ◽  
Author(s):  
Sayyed Mohammad Ali Noori ◽  
Mohammad Hashemi ◽  
Sajjad Ghasemi
Keyword(s):  
Heavy Metals ◽  
Trace Elements ◽  
Inductively Coupled Plasma ◽  
Chemical Elements ◽  
Absorption Spectrometry ◽  
Atomic Emission ◽  
Emission Spectrometry ◽  
Inductively Coupled ◽  
Wide Range ◽  
The World

Abstract: Saffron is one of the most expensive spices in the world, and its popularity as a tasty food additive is spreading rapidly through many cultures and cuisines. Minerals and heavy metals are minor components found in saffron, which play a key role in the identification of the geographical origin, quality control, and food traceability, while they also affect human health. The chemical elements in saffron are measured using various analytical methods, such as techniques based on spectrometry or spectroscopy, including atomic emission spectrometry, atomic absorption spectrometry, inductively coupled plasma optical emission spectrometry, and inductively coupled plasma mass spectrometry. The present study aimed to review the published articles about heavy metals and minerals in saffron across the world. To date, 64 chemical elements have been found in different types of saffron, which could be divided into three groups of macro-elements, trace elements, and heavy metals (trace elements with a lower gravity/greater than five times that of water and other inorganic sources). Furthermore, the chemical elements in the saffron samples of different countries have a wide range of concentrations. These differences may be affected by geographical condition such as physicochemical properties of the soil, weather and other environmental conditions like saffron cultivation and its genotype.

Major and Trace Elements of Magnetite from the Qimantag Metallogenic Belt: Insights into Evolution of Ore-forming Fluids

2015 ◽  
Vol 89 (4) ◽  
pp. 1226-1243 ◽  
Author(s):  
YI Liwen ◽  
GU Xiangping ◽  
LU Anhuai ◽  
LIU Jianping ◽  
LEI Hao ◽  
...  
Keyword(s):  
Trace Elements ◽  
Major And Trace Elements ◽  
Metallogenic Belt

scholarly journals Age and microfacies of oceanic Upper Triassic radiolarite components from the Middle Jurassic ophiolitic mélange in the Zlatibor Mountains (Inner Dinarides, Serbia) and their provenance

2017 ◽  
Vol 68 (4) ◽  
pp. 350-365 ◽  
Author(s):  
Hans-Jürgen Gawlick ◽  
Nevenka Djerić ◽  
Sigrid Missoni ◽  
Nikita Yu. Bragin ◽  
Richard Lein ◽  
...  
Keyword(s):  
Continental Slope ◽  
Oceanic Crust ◽  
Middle Jurassic ◽  
Sedimentary Cover ◽  
Upper Triassic ◽  
Late Triassic ◽  
Ophiolitic Mélange ◽  
Reef Limestone ◽  
Sedimentary Succession ◽  
Unit Yield

AbstractOceanic radiolarite components from the Middle Jurassic ophiolitic mélange between Trnava and Rožanstvo in the Zlatibor Mountains (Dinaridic Ophiolite Belt) west of the Drina–Ivanjica unit yield Late Triassic radiolarian ages. The microfacies characteristics of the radiolarites show pure ribbon radiolarites without crinoids or thin-shelled bivalves. Beside their age and the preservation of the radiolarians this points to a deposition of the radiolarites on top of the oceanic crust of the Neo-Tethys, which started to open in the Late Anisian. South of the study area the ophiolitic mélange (Gostilje–Ljubiš–Visoka–Radoševo mélange) contains a mixture of blocks of 1) oceanic crust, 2) Middle and Upper Triassic ribbon radiolarites, and 3) open marine limestones from the continental slope. On the basis of this composition we can conclude that the Upper Triassic radiolarite clasts derive either from 1) the younger parts of the sedimentary succession above the oceanic crust near the continental slope or, more convincingly 2) the sedimentary cover of ophiolites in a higher nappe position, because Upper Triassic ribbon radiolarites are only expected in more distal oceanic areas. The ophiolitic mélange in the study area overlies different carbonate blocks of an underlying carbonate-clastic mélange (Sirogojno mélange). We date and describe three localities with different Upper Triassic radiolarite clasts in a mélange, which occurs A) on top of Upper Triassic fore-reef to reefal limestones (Dachstein reef), B) between an Upper Triassic reefal limestone block and a Lower Carnian reef limestone (Wetterstein reef), and C) in fissures of an Upper Triassic lagoonal to back-reef limestone (Dachstein lagoon). The sedimentary features point to a sedimentary and not to a tectonic emplacement of the ophiolitic mélange (= sedimentary mélange) filling the rough topography of the topmost carbonate-clastic mélange below. The block spectrum of the underlying and slightly older carbonate-clastic mélange points to a deposition of the sedimentary ophiolitic mélange east of or on top of the Drina–Ivanjica unit.

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