scholarly journals Preparation of tin coating on the surface of copper-coated carbon fiber and its effect on the microstructures and properties of the composite coating

Author(s):  
Wendong Xu ◽  
Guanglong Li ◽  
Yingdong Qu ◽  
Wei Zhang ◽  
Qiwen Zhou ◽  
...  

Abstract In order to prevent the copper coating on the carbon fiber surface from oxidizing and falling off, the tin coating is plated on the surface of copper-coated carbon fiber. In this paper, the copper-tin composite coating with different thicknesses of tin coatings were successfully prepared by electroless plating. The results show that with the increasing of electroless tin plating time, the thickness of the copper-tin composite coating increases. The test results of the bonding force between the composite coating and the carbon fiber show that the coating bonding force is the best when the thickness of composite coating is between 1.31 μm and 1.55 μm. This is due to the formation of copper-tin intermetallic compounds preventes direct contact between the copper coating and oxygen, which can effectively inhibit the oxidation of the copper plating layer, thereby making the plating layer less likely to fall off. However, the excessively thick tin coating would increase the internal stress of the coating, and promote the generation of cracks on the surface of the composite coating, which would cause the composite coating to fall off. This research will provide new ideas for the preparation of high-performance copper plating on the surface of carbon fiber, and provide an important theoretical and practical basis for the application of copper coatings.

1989 ◽  
Vol 170 ◽  
Author(s):  
Benjamin S. Hsiao ◽  
J. H. Eric

AbstractTranscrystallization of semicrystalline polymers, such as PEEK, PEKK and PPS, in high performance composites has been investigated. It is found that PPDT aramid fiber and pitch-based carbon fiber induce a transcrystalline interphase in all three polymers, whereas in PAN-based carbon fiber and glass fiber systems, transcrystallization occurs only under specific circumstances. Epitaxy is used to explain the surface-induced transcrystalline interphase in the first case. In the latter case, transcrystallization is probably not due to epitaxy, but may be attributed to the thermal conductivity mismatch. Plasma treatment on the fiber surface showed a negligible effect on inducing transcrystallization, implying that surface-free energy was not important. A microdebonding test was adopted to evaluate the interfacial strength between the fiber and matrix. Our preliminary results did not reveal any effect on the fiber/matrix interfacial strength of transcrystallinity.


1994 ◽  
Vol 3 (4) ◽  
pp. 096369359400300
Author(s):  
G. Carotenuto ◽  
A. Gallo ◽  
L. Nicolais

The wetting kinetics of a solid surface by a molten metal decrease with increase of its roughness. The topography of the growing copper coating, produced on carbon fiber surface by electroplating from a sulphat bath, has been studied by scanning electron microscopy. The smoothes surface is produced after 200÷300 milliampere-hour of plating.


Materials ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 400 ◽  
Author(s):  
Agnieszka Ślosarczyk ◽  
Łukasz Klapiszewski ◽  
Tomasz Buchwald ◽  
Piotr Krawczyk ◽  
Łukasz Kolanowski ◽  
...  

Silica aerogel-based materials exhibit a great potential for application in many industrial applications due to their unique porous structure. In the framework of this study, carbon fiber and nickel coated carbon fiber–silica aerogel nanocomposites were proposed as effective electromagnetic shielding material. Herein, the initial oxidation of the surface of carbon fibers allowed the deposition of a durable Ni metallic nanolayer. The fibers prepared in this way were then introduced into a silica aerogel structure, which resulted in obtaining two nanocomposites that differed in terms of fiber volume content (10% and 15%). In addition, analogous systems containing fibers without a metallic nanolayer were studied. The conducted research indicated that carbon fibers with a Ni nanolayer present in the silica aerogel structure negatively affected the structural properties of the composite, but were characterized by two-times higher electrical conductivity of the composite. This was because the nickel nanolayer effectively blocked the binding of the fiber surface to the silica skeleton, which resulted in an increase of the density of the composite and a reduction in the specific surface area. The thermal stability of the material also deteriorated. Nevertheless, a very high electromagnetic radiation absorption capacity between 40 and 56 dB in the frequency range from 8 to 18 GHz was obtained.


2021 ◽  
Vol 6 ◽  
pp. 40-59
Author(s):  
D. V. Belov ◽  
◽  
M. V. Maximov ◽  
S. N. Belyaev ◽  
T. I. Devyatkina ◽  
...  

This article discusses a new method for producing copper electrolytic coatings with high performance properties applied to oxidized aluminum alloys. The purpose of this work is to reveal the effect of the azo compound additive, methyl red (MR), on the structure and physicomechanical properties of copper coatings deposited on oxidized aluminum. To achieve this goal, the following tasks were solved: the microstructure and adhesive properties of the copper coating formed on oxidized aluminum alloys were determined, and the physical and mechanical properties of the copper coating (microhardness, open porosity, adhesion) were connected with the action of an azo dye in the copper plating electrolyte. Samples of aluminum alloys AD1M and AMg6BM were subjected to anodic treatment under the same conditions in two oxidation electrolytes of various compositions. The process of applying a copper coating to samples of oxidized aluminum alloys was carried out using a standard copper plating electrolyte. The comparison was carried out with a copper plating electrolyte of the same composition, in which an additive of azo dye, methyl red (MR). The use of this technology will not only increase the reliability and durability of machine parts and mechanisms, but also restore old ones, which is an important and relevant scientific and technical task.


2018 ◽  
Vol 284 ◽  
pp. 1242-1247 ◽  
Author(s):  
R.F. Gallyamova ◽  
S.N. Galyshev ◽  
F.F. Musin ◽  
A.G. Badamshin ◽  
V.A. Dokichev

The article shows the possibility of applying a silicon dioxide coating on the carbon fiber by the sol-gel method. The evaluation of the protective properties of the obtained coatings at a temperature of 600 ° C is given; the changing of the a coated fiber surface morphology during the destruction process is shown for the first time. The destruction of the carbon fiber surface without coating begins at a soaking time of 120 min, which is accompanied by a significant decrease in the diameter of the fiber. The destruction of the coated carbon fiber surface begins at a soaking time of 360 minutes, the fiber diameter changes insignificantly. The paper shows that the sol-gel coatings slow down the oxidation of the carbon fiber more than 2 times.


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