The Full Extent

Author(s):  
J. S. Weiner ◽  
Chris Stringer

Almost any single one of the techniques employed in the investigations suffices to reveal the elaborateness of the deception which was perpetrated at Piltdown. The anatomical examination, the tests for fluorine and nitrogen bear particularly good witness to this; even the radio-activity results taken alone, led the physicists to remark on the ‘great range of activity shown by specimens from this one little site’; ‘it is difficult to avoid the conclusion that the different bones in the Piltdown assemblage have had very different geological and chemical histories’. We have merely to take account of the stained condition of the whole assemblage, to realize the thoroughness of the fraud. From the Vandyke brown colour of the unnaturally abraded canine we infer with certainty that it was deliberately ‘planted’. The superficiality of the iron impregnation, combined with the chromium, tells as much as regards the orang jaw. And it is this iron-staining which finally shows that the rest, human and animal, was without doubt, all ‘planted’. The iron-staining has two peculiar features. It seems probable that ferric ammonium sulphate (iron alum) was the salt employed. This salt is slightly acid. The peculiarity of this salt (and, indeed, of any acid sulphate) is that in bone which contains little organic matter such as the cranium of Piltdown I, or Piltdown II, the beaver bones and hippo teeth, it brings about a detectable change in the crystal structure of the bone. In the apatite in which the calcium of the bone is held, the phosphate is replaced by sulphate to form gypsum. This change is quite unnatural, for neither gypsum nor sufficient sulphate occur in the gravels at Piltdown to bring it about. So the iron-sulphate-staining is an integral part of the forger’s necessary technique. He also used chromium compounds to aid the iron-staining probably because he thought it would assist the production of iron oxide. Chromium compounds are oxidizing. The basic strategy underlying the Piltdown series of forgeries now seems reasonably clear. Two main elements in the plan taken together explain nearly all the features of the affair quite satisfactorily.

Author(s):  
J. S. Weiner ◽  
Chris Stringer

In 1908 (as far as we can ascertain), long before he went to see his ‘old friend’ the Keeper of Geology at South Kensington, some time before he met Teilhard de Chardin, Dawson had in his hands the first piece of the skull of Eoanthropus. This piece, we know, had been chemically treated, by iron sulphate, to produce the brown colour, and in the process the bone had undergone the change in its crystal structure revealed by the X-ray diffraction method. This piece was part of the braincase, the ‘coconut’, smashed by the labourers, according to the story the origins of which are by no means clear. Once again a question faces us which raises sharply and finally the issue of Dawson’s complicity. We might put the question as the ‘Piltdown Riddle’:—Was the pit completely barren at the birth of Piltdown Man or did he begin life there as a burial? Was the cranium genuinely in the gravel or had it been planted where the workmen found it? In the first stages of the investigation, before we fully appreciated the artificiality of the iron-staining, we were inclined to regard the skull-case in the gravel as a genuine though not very ancient fossil. The fluorine values, while not really high, taken with the reduced content of organic matter, certainly gave grounds for accepting a semi-fossilized condition in the cranium. So it was presumed at first that the hoax had been based on a genuine discovery of portions of an ancient skull in the gravel, and that the ape jaw and canine and the other animal remains and implements had been subsequently planted. As the investigations went on, stage by stage, this view became untenable. The iron-staining threw serious doubt on the skull’s derivation from the gravel; the sulphate in the bone, in the form of gypsum, is the result of artificial and deliberate chemical treatment, and gypsum does not occur in the Piltdown or Barcombe Mills gravel. The chemical conditions in the Piltdown subsoil and gravel water are not at all such that this unusual alteration in the bone could have taken place naturally in the gravel.


1959 ◽  
Vol 39 (2) ◽  
pp. 193-201 ◽  
Author(s):  
H. Doornenbal

Haemoglobin levels, haematocrit values and erythrocyte counts were determined at weekly intervals from 3 to 45 days of age for 60 pigs which received iron in the form of: injectable iron-dextran (A); injectable iron-dextran (B); injectable ferric ammonium citrate; oral iron in the form of paste, or sods sprinkled with iron sulphate. The iron-dextran and ferric ammonium citrate compounds were administered at 3 days of age as single injections supplying 100 mgm. of iron and 30 mgm. of ferric ammonium citrate respectively. The paste was administered at 3, 10, 17 and 24 days of age. Sods were fed twice a week during the period of 3 days to 28 days of age.The sod treatment maintained normal blood values while the iron-dextran compounds and the paste resulted in values somewhat below normal, although visible evidence of anaemia was not apparent. Blood values for the group receiving ferric ammonium citrate were extremely low and two pigs on this treatment died at 42 and 60 days of age. Both exhibited severe anaemia.Significant differences were obtained in weaning weights. The heaviest pigs were those receiving sods; the lightest pigs those receiving injectable ferric ammonium citrate. The effect of the different treatments on growth was not apparent until after 21 days of age.


1986 ◽  
Vol 41 (5) ◽  
pp. 629-639 ◽  
Author(s):  
Anna-Margarete Hinke ◽  
Axel Hinke ◽  
Wilhelm Kuchen ◽  
Wolfgang Hönle

Abstract Reduction of MentPBr2M(CO)5 1 (M = Cr, W) with magnesium in THF yields the diphos­phene complex (CO)5M(Ment)P=P(Ment)M(CO)5 2 as the main product. In addition, a phosphinidene complex, (CO)5M(Ment)PM(CO)5 (3) is also formed. The latter is obtained in larger amounts, if the reaction is carried out in the presence of M(CO)5THF. The proposed structures are confirmed by NMR and UV data as well as - in the case of the chromium compounds (2a, 3a) - by crystal structure analysis. Compound 2a is obtained only as the frans-isomer. The P-P distance in 2a (204.0 pm) indicates a double bond which does not participate in the complex formation. The P-Cr distance in 3a (average: 230.3 pm) is within the low est range found for this element combination. Reaction of 2a with LiAlH4 yields the diphosphane complex (CO)5CrMent(H)P-P(H)MentCr(CO)5 4 as a mixture of “meso” and “rac” diastereomers.


2010 ◽  
Vol 10 (3-4) ◽  
pp. 139-145 ◽  
Author(s):  
Katarzyna Kowalczewska-Madura ◽  
Renata Dondajewska ◽  
Ryszard Gołdyn

Total phosphorus and organic matter content in bottom sediments of lake under restoration measures with iron treatmentRusałka Lake is a shallow, man-made, strongly eutrophicated reservoir, being a place of recreational activities for Poznan citizens. Restoration measures with the use of iron sulphate were conducted in years 2006-2007. Phosphorus and organic matter concentrations in lake sediments were analyzed in years 2005-2007 at two research stations (profundal and littoral) to determine its changes under the influence of restoration. Greater phosphorus concentrations were noted in profundal (max 1.55 mg P g-1dry weight (DW)) than in littoral (max 0.98 mg P g-1DW). An increase of P amount in sediment was observed after iron treatment. Among phosphorus fractions Res-P dominated, i.e. phosphorus biologically unavailable for organisms. Organic matter content reached 23.1% in profundal, while 14.8% in littoral. Its amount decreased in following years.


2020 ◽  
Vol 68 ◽  
pp. 23-35
Author(s):  
Bo Pagh Schulz ◽  
Madeleine Larissa Vickers ◽  
Jennifer Huggett ◽  
Henrik Madsen ◽  
Claus Heilmann-Clausen ◽  
...  

Pristinely preserved mineral pseudomorphs called glendonites, up to 1.6 m long, from the Palaeogene strata of Denmark allow detailed crystallographic characterisation and add to the understanding of the transformation of the precursor mineral, ikaite (CaCO3·6H2O), to calcite, which constitutes the glendonite. We describe Danish pseudomorphs after ikaite from two localities and formations: the Early Eocene Fur Formation and the Late Oligocene Brejning Formation. This detailed study highlights that key aspects such as morphology and mode of occurrence of these ancient glendonites are identical to those of their parent mineral ikaite, when it grows in marine sediments. Systematic distortion of the angles in glendonite and marine sedimentary ikaite relative to the ideal ikaite symmetry may arise due to the incorporation of organic matter into the crystal structure, and we demonstrate the similarity between modern and ancient ikaite formation zones in the marine sedimentary realm with respect to organic matter.


1984 ◽  
Vol 62 (11) ◽  
pp. 2566-2569 ◽  
Author(s):  
Eva M. Campi ◽  
Bryan M. K. Gatehouse ◽  
W. Roy Jackson ◽  
Ian D. Rae ◽  
Margaret G. Wong

The 1H nmr spectra of 1,3-di-tert-butyl-2-methoxybenzenedicarbonyltriphenylphosphinechromium (5) and some related compounds at low temperatures show the presence of two species which interconvert with free energy of activation near 50 kJ mol−1. The species differ in the orientation of the methoxy with respect to the chromium, since the same type of process is observed in a chelate complex in which a phosphinite ligand on chromium is also attached to the arene. Hindered rotation about the arene–chromium axis is not involved. The crystal structure of 5 shows the Ph3P anti to the methoxy and the O-methyl group proximal to chromium.


2002 ◽  
Vol 755 ◽  
Author(s):  
Masamichi Tsuji ◽  
Makoto Yamaguchi ◽  
Satoshi Murao

ABSTRACTBismuth nitrate basic, which chemical content is given by 4BiNO3(OH)2.BiO(OH), was studied for anion-intercalation or anion-exchange properties. A crystal structure of the bismuth nitrate basic has not been known. In the present study, its XRD pattern was indexed using a possible orthorhombic system having the lattice parameters of ao=3.021(1) nm, bo=3.029(1) nm and co=0.9572(3) nm. This compound was found to incorporate CH3COO-, halides and several oxyanions including CO32-. Incorporation of these anions by this solid was evidenced by broadening of infrared absorption band by NO3-, suggesting involvement with NO3- ions. Intercalation of CO32- by the bismuth nitrate basic in full extent yielded a bismutite represented by the chemical composition Bi2O2CO3. The bismuth nitrate basic will serve as a new host for anion-intercalation and anion-exchange.


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