New experimental researches on some of the leading doctrines of Caloric ; particularly on the relation between the elasticity, temperature, and latent heat of different vapours; and thermometric admeasurement and capacity
This paper is divided into three sections. In the first the author, after taking an historical view' of the different experiments under taken by Robinson, Watt, Dalton, Biot, and some others, relating to the elastic force of vapours arising from different bodies at different temperatures, and after pointing out the sources of error and imperfection to which they are liable, proceeds to describe the apparatus which he employed, wdiieh is further illustrated by an annexed drawing. The space which contains the vapour for experiment is about half an inch of a barometer tube, against which the oblong bulb of a delicate thermometer rests so as to indicate the true temperature. The contrivance is such, that though the liquid and in cumbent vapour are restricted to the summit of the tube, its progressive range of elasticity may be measured from 0° to 200° above the boiling point of wrater, or from an elasticity of 0'07 inch to that capable of sustaining 36 feet of mercury, without heating the mercurial column itself. In this section of the paper are several tables of results, showing the elastic force of the vapour of water in inches of mercury, at temperatures between 24° and 312° ; and also that of alcohol, ether, oil of turpentine, and naphtha. The second section of Dr. Ure’s paper relates to thermometric admeasurement, and to the doctrine of capacity. He does not consider the thermometer liable to the uncertainties which are supposed to belong to it by Mr. Dalton, but that it is an equable measure of heat, in consequence of its possessing an increasing rate of expansion, and w'hich is compensated for by a quantity of the quicksilver getting out of the bulb into the tube, and consequently out of the action of the heat, the bulb being the only part heated in all ordinary cases. In the third section, relating to the latent heat of different vapours, Dr. Ure details experiments made to ascertain the caloric existing in different vapours, and the temperatures at which they respectively acquire the same elastic force.