On the application of liquids formed by the condensation of gases as mechanical agents
The elasticity of vapours, in contact with the liquids from which they are produced under high pressures in high temperatures, is known to increase in a higher ratio than the arithmetical one of the temperature; but the exact law is not determined, and the loss of latent heat in compression, and the re-absorption in expansion, renders the advantage of steam under great pressure and at very high temperatures doubtful in an economical view. No such doubt, however, exists in regard to those fluids which require very great compression for their existence, and where common temperatures are sufficient to produce an immense elastic force. Thus sulphuretted hydrogen, which condenses into a liquid under a pressure of 14 atmospheres at 3°, had its elastic force increased so as to equal a pressure of 17 atmospheres by raising its temperature to 47°. Liquid muriatic acid at 3° exerted an elastic force equal to the pressure of 20 atmospheres, at 25° = 25 atmospheres, and at 51° = 45 atmospheres. After some experimental illustrations of the expansibility of the vapour of sulphuret of carbon at different temperatures, the author adverts to the possible application of the difficultly compressible gases, as mechanical agents, and to their power of producing cold by the rapidity of their evaporation.