Second letter on the electrolysis of secondary compounds, addressed to Michael Faraday, Esq., D. C. L., F. R. S., &c. By J. Frederic Daniell. Esq., For. Sec. R. S., Professor of Chemistry in King's College, London
The author, in this letter, prosecutes the inquiry he had commenced in the former one, into the mode in which the chemical elements group themselves together to constitute radicles , or proximate principles. He considers his experiments as establishing the principle that, considered as electrolytes, the inorganic oxy-acid salts must be regarded as compounds of metals, or of that extraordinary compound of nitrogen and four equivalents of hydrogen to which Berzelius has given the name of ammonium , and compound anions, chlorine, iodine, &c., of the Haloide salts; and as showing that this evidence goes far to establish experimentally the hypothesis originally brought forward by Davy, of the general analogy in the constitution of all salts, whether derived from oxy-acids or hydro-acids. Some remarks are made on the subject of nomenclature, and the rest of the paper is occupied with the details of the experiments, all bearing on the important subject which he has undertaken to investigate.