Evolution of a bicontinuous structure in peritectic melting: The simplest form of dealloying

2019 ◽  
Vol 3 (11) ◽  
Author(s):  
Wen-Kai Hu ◽  
Jun-Chao Shao ◽  
Shao-Gang Wang ◽  
Hai-Jun Jin
Nanoscale ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 4678-4684
Author(s):  
Yan Cheng ◽  
Yonghui Zheng ◽  
Zhitang Song

A 3D nano-bicontinuous structure consisting of a reversible Sb2Te3 phase and amorphous Si phase is visualized. The amorphous Si frame is stable and the Sb2Te3 nano areas switch between the a- and f-structure.


2006 ◽  
Vol 118 ◽  
pp. 651-654
Author(s):  
Young Soon Kwon ◽  
Pyuck Pa Choi ◽  
Ji Soon Kim ◽  
Dae Hwan Kwon ◽  
K.B. Gerasimov

The particle size effect on the peritectic melting of FeSn2 particles in FeSn-FeSn2 nanocomposites was studied using differential scanning calorimetry and X-ray diffraction. FeSn-10 wt.% FeSn2 compounds, mechanically milled for 30 min and slowly heated in a differential scanning calorimeter, showed incongruent melting at 680 K. Although FeSn2 grains grew from 10 to 40 nm upon heating before peritectic melting set in, the melting temperature was more than 100 K lower than the equilibrium value. A small latent heat during peritectic melting and a large amount of interfacial energy of FeSn-FeSn2 nanocomposites are held responsible for this large particle size effect. Grain growth is hardly possible in the case of rapid local heating during mechanical milling. Therefore, a decrease in the peritectic melting temperature is even expected to be substantially larger.


Langmuir ◽  
2012 ◽  
Vol 28 (21) ◽  
pp. 8197-8204 ◽  
Author(s):  
Marcel Mühlmann ◽  
Annemarie Magerl ◽  
Werner A. Goedel

2020 ◽  
Author(s):  
Manuel Pimenta Silva ◽  
Peter Ulmer ◽  
Othmar Müntener

<p>In the southern part of the Adamello Batholith (43-33 Ma; Schaltegger et al., 2019) in Northern Italy (Re di Castello superunit), we identified a multi-generational dyke suite with “exotic” chemical compositions intruding quartz-dioritic units surrounding a gabbroic complex. These dykes are characterised by SiO<sub>2</sub> contents between 43 and 46 wt.%, high Al<sub>2</sub>O<sub>3</sub> (20-21 wt.%), and low MgO and Ni (below 6.5 wt.% and 40 μg/g, respectively), displaying a nepheline-normative character. Furthermore, they exhibit positive Sr and Ba anomalies. These chemical features exclude a possible primitive character or derivation from a typical calc-alkaline liquid line of descent, as identified for the Adamello Massif (Ulmer et al, 2018). The primocrystic cargo of these dikes (clinopyroxene, anorthitic plagioclase, and low-Si, high-Na pargasitic amphibole) displays striking similarities with cumulate crystals of the contiguous Blumone amphibole gabbroic cumulate, inferring mechanical interaction of these exotic liquids with and/or derivation from the cumulate complex. Amphibole-plagioclase equilibration temperatures of the dikes (875 to 775ºC) are consistent with thermal equilibration with the surrounding quartz-dioritic mush. Sharp contacts and dyke fragmentation are also observed and are thermally congruent with the ductile-brittle transition of a quartz-dioritic to tonalitic mush (Marxer & Ulmer, 2019).</p><p>Simple mass balance calculations modelling of the peritectic melting of pargasitic amphibole and high-An plagioclase (major mineral phases of the contiguous amphibole gabbroic cumulates) with simultaneous crystallisation of low-Al clinopyroxene reveal that melt compositions similar to these dykes can be achieved with amphibole-plagioclase proportions ranging between 65:35 and 50:50. To verify if peritectic cumulate remelting represents a possible generation mechanism of these dykes we performed<span>  </span>experiments at 0.2 GPa.</p><p>Established phase equilibria of these dyke compositions reveal a lack of near-liquidus olivine, which is a rare phase in gabbroic complex. This is consistent with preliminary experimental results on cumulate melting, where olivine is also absent at high temperatures (> 1075ºC). These observations further disprove the petrogenesis of these liquids via a calc-alkaline liquid line of descent, where mafic magmas would be early saturated in olivine at low pressure further supporting their generation by local remelting of amphibole-plagioclase dominated mafic cumulates.Geochemical as well as experimental results both strongly point towards the petrogenesis of these nepheline-normative, high-Al, low-Mg picrobasalts by low pressure peritectic melting of a pargasite-anorthite cumulate assemblage in an active magmatic system.</p><p> </p><p>Marxer, F. & Ulmer, P. <em>Contrib Mineral Petr.</em> <strong>174(10)</strong>, 84 (2019).</p><p>Schaltegger, U. <em>et al. J Petrol. </em><strong>60(4)</strong>, 701-722 (2019).</p><p>Ulmer, P. <em>et al. J. Petrol.</em> <strong>59(1)</strong>, 11-58 (2018).</p>


2014 ◽  
Vol 50 (62) ◽  
pp. 8480-8483 ◽  
Author(s):  
Zhenhua Ju ◽  
Junpo He

Responsive nanospheres with an internal bicontinuous structure and shape changing ability through phase inversion were obtained through hierarchical self-assembly of a dendritic block terpolymer in selective solvents.


2014 ◽  
Vol 804 ◽  
pp. 187-190 ◽  
Author(s):  
Kuo Zhang ◽  
Hong Yan Xia ◽  
Bo Wang ◽  
Zhong Qi Shi ◽  
Xiang Zhao Zhang ◽  
...  

A three dimensional (3D) SiC/Cu-Si composite with bicontinuous structure was fabricated by spontaneous infiltration method, using porous recrystallized SiC ceramic with porosity of 37% as 3D network reinforcement and Cu alloy (Cu-18Si) as matrix. The phase composition, microstructure, and thermo-physical properties of the as-prepared 3D-SiC/Cu-Si composite were investigated. The experimental results showed that the Cu-18Si alloy could fully penetrate into the porous SiC ceramic at 1600 °C for 2 h spontaneously. SiC and Cu15Si4 phases were identified in the as-prepared composites. The interfacial bond between SiC and Cu-Si alloy was tightly and no severe interfacial reaction was observed. The thermal conductivity and coefficient of thermal expansion of the as-prepared 3D-SiC/Cu-Si composite were changed from 89.8 to 55 W·m-1·K-1 and 7.512 to 9.64×10-6 °C-1 with the temperature increased from room temperature to 500 °C, respectively.


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