scholarly journals Synchrotron X-ray scattering and reflectivity studies of the structure of low dielectric constant SiOCH thin films prepared from bistrimethylsilylmethane by chemical vapor deposition

2006 ◽  
Vol 40 (s1) ◽  
pp. s614-s619 ◽  
Author(s):  
Kyuyoung Heo ◽  
Kyoung Suk Oh ◽  
Jinhwan Yoon ◽  
Kyeong Sik Jin ◽  
Sangwoo Jin ◽  
...  
1994 ◽  
Vol 343 ◽  
Author(s):  
Justin F. Gaynor ◽  
Seshu B. Desu

ABSTRACTPolyxylylene thin films grown by the chemical vapor deposition (CVD) process have long been utilized to achieve uniform, pinhole-free conformal coatings. They have recently been cited as possible low dielectric constant films for intermetal layers in high-speed ICs. Homopolymer films are highly crystalline and have a glass transition temperature around room temperature. We have demonstrated that room temperature copolymerization with previously untested comonomers can be achieved during the CVD process. Copolymerizing chloro-p-xylylene with perfluorooctyl methacrylate results in the dielectric constant at optical frequencies being lowered from 2.68 to 2.19. Copolymerizing p-xylylene with vinylbiphenyl resulted in films which increase the temperature at which oxidative scission occurs from 320 to 450C. Copolymerizing p-xylylene with 9-vinylanthracene resulted in a brittle, yellow film.


2008 ◽  
Vol 53 (9(5)) ◽  
pp. 2512-2517
Author(s):  
AnSoo Jung ◽  
ChangYoung Kim ◽  
R. Navamathavan ◽  
Jong-Kwan Woo ◽  
Kwang-Man Lee ◽  
...  

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