The crystal structure, luminescence and nitrobenzene-sensing properties of a two-dimensional MnIIcoordination polymer based on 2,6-bis(imidazol-1-yl)pyridine
2015 ◽
Vol 71
(6)
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pp. 435-439
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Keyword(s):
Ft Ir
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A two-dimensional MnIIcoordination polymer (CP), poly[bis[μ2-2,6-bis(imidazol-1-yl)pyridine-κ2N3:N3′]bis(thiocyanato-κN)manganese] [Mn(NCS)2(C11H9N5)2]n, (I), has been obtained by the self-assembly reaction of Mn(ClO4)2·6H2O, NH4SCN and bent 2,6-bis(imidazol-1-yl)pyridine (2,6-bip). CP (I) was characterized by FT–IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. The crystal structure features a unique two-dimensional (4,4) network with one-dimensional channels. The luminescence and nitrobenzene-sensing properties were explored in a DMF suspension, revealing that CP (I) shows a strong luminescence emission and is highly sensitive for nitrobenzene detection.
Keyword(s):
2021 ◽
Vol 77
(9)
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2016 ◽
Vol 11
(2)
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pp. 3498-3512
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Keyword(s):