The influence of Ni on the microstructure and corrosion resistance of high-strength low alloy steel in the Cl-containing environment

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Dan Wang ◽  
Qingdong Zhong ◽  
Jian Yang ◽  
Shujian Zhang

Purpose This paper aims to search the optimum content of Ni on the microstructure, phase and electrochemical behavior of high-strength low alloy (HSLA) steel in the 3.5 wt.% NaCl solution. Design/methodology/approach The microstructure and corrosion resistance of Ni-containing HSLA steel in the simulated marine environment was studied by optical microscopy, scanning electron microscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and electrochemical techniques. Findings The sample containing 3.55 wt.% of nickel exhibited a finer grain size of 10 μm and a lower icorr of 2.169 µA cm−2. The XRD patterns showed that the Fe-Cr-Ni solid solution, FeC and Cr3C2 were observed in samples when Ni was added. Besides, the 3.55 wt.% of nickel addition enhanced the charge transfer resistance of the low alloy steel which suggested the sample possessed excellent inhibition of electrochemical reaction and corrosion resistance. The XPS spectrum suggested that nickel was beneficial to improve the corrosion resistance of steel by forming protective oxides, and the ratio of Fe2+/Fe3+ in protective oxides was increased. Practical implications Finding the comprehensive performance of HSLA steel which can be applied to unmanned surface vehicles in marine operations. Originality/value This study has a guiding significance for optimizing the composition of HSLA steel in a Cl- containing environment.

Alloy Digest ◽  
1957 ◽  
Vol 6 (1) ◽  

Abstract KAISALOY is a high-strength low-alloy steel combining excellent formability and good weldability with desirable corrosion resistance. It is intended primarily for weight reduction. Kaisaloy is furnished in three grades. This datasheet provides information on composition, hardness, and tensile properties as well as fracture toughness. It also includes information on corrosion resistance as well as forming, machining, and joining. Filing Code: SA-53. Producer or source: Kaiser Steel Corporation.


2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
El-Sayed M. Sherif ◽  
Adel Taha Abbas ◽  
D. Gopi ◽  
A. M. El-Shamy

The corrosion and corrosion inhibition of high strength low alloy (HSLA) steel after 10 min and 60 min immersion in 2.0 M H2SO4solution by 3-amino-1,2,4-triazole (ATA) were reported. Several electrochemical techniques along with scanning electron microscopy (SEM) and energy dispersive X-ray (EDS) were employed. Electrochemical impedance spectroscopy indicated that the increase of immersion time from 10 min to 60 min significantly decreased both the solution and polarization resistance for the steel in the sulfuric acid solution. The increase of immersion time increased the anodic, cathodic, and corrosion currents, while it decreased the polarization resistance as indicated by the potentiodynamic polarization measurements. The addition of 1.0 mM ATA remarkably decreased the corrosion of the steel and this effect was found to increase with increasing its concentration to 5.0 mM. SEM and EDS investigations confirmed that the inhibition of the HSLA steel in the 2.0 M H2SO4solutions is achieved via the adsorption of the ATA molecules onto the steel protecting its surface from being dissolved easily.


Alloy Digest ◽  
1953 ◽  
Vol 2 (11) ◽  

Abstract JALTEN is a high-strength low-alloy steel that is readily welded and easily fabricated. It offers an opportunity to incorporate many weight-saving features in design of new products. It is produced in three grades, namely, JALTEN, #1, JALTEN #2, JALTEN #3. This datasheet provides information on composition and tensile properties. It also includes information on corrosion resistance as well as forming, machining, and joining. Filing Code: SA-12. Producer or source: Jones & Laughlin Steel Corporation.


Alloy Digest ◽  
1962 ◽  
Vol 11 (1) ◽  

Abstract Armco High Strength No. 2 is a high-strength low-alloy steel designed to give excellent corrosion resistance coupled with superior mechanical properties. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: SA-123. Producer or source: Armco Inc., Eastern Steel Division.


2015 ◽  
Vol 67 (2) ◽  
pp. 166-171 ◽  
Author(s):  
B. S. Yilbas ◽  
Ihsan-ul-Haq Toor ◽  
Jahanzaib Malik ◽  
F. Patel

Purpose – The purpose of the present study is to report the results of the laser treatment of high-strength low-alloy (HSLA) steel surface and corrosion response of the treated surface that was carried out. Metallurgical and morphological changes in the laser-treated layer are also examined. Laser treatment of the alloy surface improves the surface properties; however, development of high thermal stress field in the treated layer can exceed the yielding limit of the alloy lowers, particularly, the corrosion resistance of the resulting surface. Design/methodology/approach – Pre-prepared workpiece surfaces are laser-treated and electrochemically tested in an electrolytic solution. Corrosion rate of the resulting surface is analyzed and pit sites are examined. Findings – It is found that the presence of nitride compounds and fine grains acts like as a self-protective layer at the laser-treated surface while lowering the corrosion resistance. Consequently, laser gas-assisted treatment provides a positive effect on the corrosion properties of the treated surface through lowering the corrosion current. The pits are shallow and do not form a regular pattern at the workpiece surface. The secondary pitting is prevented by the protective layer formed at the laser-treated surface. Research limitations/implications – The study can be extended to include laser treatment including the hard particles, such as carbides, at the surface. However, this extension is left to another study. Practical implications – Laser treatment can be used for protection of surfaces from wear and corrosive environments. The findings of this study give insight into the improvement of the surface characteristics for this purpose. It serves to industry for the practical solution of the surface protection from corrosive environments. Social implications – The researchers and scientists working in the area get the benefit from the outcome of this work. Originality/value – It is an original work and gives insight into the enhancement of the corrosion resistance of HSLA steel after the laser treatment process.


2016 ◽  
Vol 45 (3) ◽  
pp. 191-198 ◽  
Author(s):  
Yuanfeng Jia ◽  
Nana Ren ◽  
Huadong Yue ◽  
Jianru Deng ◽  
Yali Liu

Purpose The paper developed a novel gallic acid-based rust conversion emulsion (RCE) that is applied in the treatment of rusted steels. The purpose of this paper is to investigate the methods for the synthesis of RCE and study the mechanism of rust conversion. Design/methodology/approach Conversion emulsion was prepared using styrene, acrylate and self-developed gallic acid (GA)-based rust converter (GRC) via seed emulsion polymerisation. The polymerisable GRC was synthesised by the ring-opening reaction of glycidyl methacrylate with natural GA. The effects of the GRC dosage and its feeding modes on the RCE synthesis were analysed. The corrosion resistance, surface morphology, composition and mechanism of rust conversion coatings were studied using electrochemical tests, scanning electron microscopy, Raman spectroscopy and X-ray photoelectron spectroscopy (XPS), respectively. Findings The results showed that conversion coating on rusted steels treated with RCE, with various dosages of GRC (weight per cent), synthesised using seed emulsion polymerisation, exhibited the best adhesion and corrosion resistance. Raman spectroscopy revealed that RCE converted the original multiphase rust into stable crystalline phases of α-Fe2O3 and Fe3O4. According to XPS and energy dispersive X-ray analysis, the phenolic hydroxyl groups of RCE were proposed to chelate with Fe ions to form macromolecular ferrum compounds. Research limitations/implications The pre-rusted steels demonstrated a better corrosion resistance than rust-free steels after treatment with RCE. Practical implications The paper developed a novel GA-based RCE with high efficiency and environment-friendly method. Originality/value This work is expected to replace the conventional rust conversion paints and cause a significant impact on extending the service life of rusted steels.


2021 ◽  
Vol 9 (3) ◽  
pp. 299-310 ◽  
Author(s):  
Saadat Ali Rizvi ◽  
Rajnish Singh ◽  
Saurabh Kumar Gupta

The basic aim of this study was to find a relationship between heat input and mechanical properties of high strength low alloy steel (HSLA) welded joints and also elaborate its effect on microstructure. The combined effect of welding current, voltage and speed i.e. Heat Input on mechanical properties of High Strength Low Alloy Steel (ASTM A242 type-II) weldments have been studied in the present work. HSLA steel work pieces were welded by Gas metal arc welding (GMAW) process under varying welding current, arc voltage, and welding speed. Total nine samples were prepared at different heat input level i.e. 1.872 kJ/mm, 1.9333 kJ/mm, 2.0114 kJ/mm, 2.1 kJ/mm, 2.1956 kJ/mm, 2.296 kJ/mm, 2.4 kJ/mm, 2.5067 kJ/mm and 2.6154 kJ/mm It was observed that as heat input increases the ultimate tensile strength and microhardness of weldment decreased while impact strength increased and it was also observed that on increasing the heat input grain size of microstructure tends to coarsening it is only due to decreasing in cooling rate.


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