Surface evolution and bonding properties of electroplated Au/Sn/Au

Author(s):  
K. Wang ◽  
K. Aasmundtveit ◽  
H. Jakobsen
2020 ◽  
Vol 12 (17) ◽  
pp. 2809
Author(s):  
Meirman Syzdykbayev ◽  
Bobak Karimi ◽  
Hassan A. Karimi

Detection of terrain features (ridges, spurs, cliffs, and peaks) is a basic research topic in digital elevation model (DEM) analysis and is essential for learning about factors that influence terrain surfaces, such as geologic structures and geomorphologic processes. Detection of terrain features based on general geomorphometry is challenging and has a high degree of uncertainty, mostly due to a variety of controlling factors on surface evolution in different regions. Currently, there are different computational techniques for obtaining detailed information about terrain features using DEM analysis. One of the most common techniques is numerically identifying or classifying terrain elements where regional topologies of the land surface are constructed by using DEMs or by combining derivatives of DEM. The main drawbacks of these techniques are that they cannot differentiate between ridges, spurs, and cliffs, or result in a high degree of false positives when detecting spur lines. In this paper, we propose a new method for automatically detecting terrain features such as ridges, spurs, cliffs, and peaks, using shaded relief by controlling altitude and azimuth of illumination sources on both smooth and rough surfaces. In our proposed method, we use edge detection filters based on azimuth angle on shaded relief to identify specific terrain features. Results show that the proposed method performs similar to or in some cases better (when detecting spurs than current terrain features detection methods, such as geomorphon, curvature, and probabilistic methods.


Author(s):  
Attila Kovács ◽  
Zoltán Varga

AbstractThe feasibility of an additional ligand coordination at the 11th coordination site of actinium, lanthanum, and lutetium ions in 10-fold coordinated macropa complexes has been studied by means of density functional theory calculations. The study covered the two main macropa conformers, Δ(δλδ)(δλδ) and Δ(λδλ)(λδλ), favoured by larger (Ac3+, La3+) and smaller (Lu3+) ions, respectively. At the molecular level, the coordination of H2O is the most favourable to the largest Ac3+ while only slightly less to La3+. Protonation of the picoline arms enhances the coordination by shifting the metal ion closer to the open site of the ligand. The choice of macropa conformer has only a slight influence on the strength and bonding properties of the H2O coordination. Aqueous solution environment decreases considerably the energy gain of H2O coordination at the 11th coordination site.


2021 ◽  
Vol 103 (3) ◽  
Author(s):  
A. D. N. James ◽  
E. I. Harris-Lee ◽  
A. Hampel ◽  
M. Aichhorn ◽  
S. B. Dugdale

2021 ◽  
Author(s):  
Nikolaos Tsoureas ◽  
Akseli Mansikkamäki ◽  
Richard Layfield
Keyword(s):  

A series of hybrid uranocenes consisting of uranium(IV) sandwiched between cyclobutadienyl (Cb) and cyclo-octatetraenyl (COT) ligands has been synthesized, structurally characterized and studied computationally. The dimetallic species [(η4-Cb'''')(η8-COT)U(μ:η2:η8-COT)U(THF)(η4-Cb'''')] (1) forms...


Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 393
Author(s):  
Jiantao Zhou ◽  
Xu Han ◽  
Hui Li ◽  
Sheng Liu ◽  
Shengnan Shen ◽  
...  

Laser polishing is a widely used technology to improve the surface quality of the products. However, the investigation on the physical mechanism is still lacking. In this paper, the established numerical transient model reveals the rough surface evolution mechanism during laser polishing. Mass transfer driven by Marangoni force, surface tension and gravity appears in the laser-induced molten pool so that the polished surface topography tends to be smoother. The AlSi10Mg samples fabricated by laser-based powder bed fusion were polished at different laser hatching spaces, passes and directions to gain insight into the variation of the surface morphologies, roughness and microhardness in this paper. The experimental results show that after laser polishing, the surface roughness of Ra and Sa of the upper surface can be reduced from 12.5 μm to 3.7 μm and from to 29.3 μm to 8.4 μm, respectively, due to sufficient wetting in the molten pool. The microhardness of the upper surface can be elevated from 112.3 HV to 176.9 HV under the combined influence of the grain refinement, elements distribution change and surface defects elimination. Better surface quality can be gained by decreasing the hatching space, increasing polishing pass or choosing apposite laser direction.


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