Primordial, thermal, and shock features of ordinary chondrites: Emulating bulk X‐ray diffraction using in‐plane rotation of polished thin sections

2019 ◽  
Vol 54 (4) ◽  
pp. 919-937 ◽  
Author(s):  
Naoya Imae ◽  
Makoto Kimura ◽  
Akira Yamaguchi ◽  
Hideyasu Kojima
Author(s):  
T. J. Beveridge

The Bacillus subtilis cell wall provides a protective sacculus about the vital constituents of the bacterium and consists of a collection of anionic hetero- and homopolymers which are mainly polysaccharidic. We recently demonstrated that unfixed walls were able to trap and retain substantial amounts of metal when suspended in aqueous metal salt solutions. These walls were briefly mixed with low concentration metal solutions (5mM for 10 min at 22°C), were well washed with deionized distilled water, and the quantity of metal uptake (atomic absorption and X-ray fluorescence), the type of staining response (electron scattering profile of thin-sections), and the crystallinity of the deposition product (X-ray diffraction of embedded specimens) determined.Since most biological material possesses little electron scattering ability electron microscopists have been forced to depend on heavy metal impregnation of the specimen before obtaining thin-section data. Our experience with these walls suggested that they may provide a suitable model system with which to study the sites of reaction for this metal deposition.


1966 ◽  
Vol 36 (276) ◽  
pp. 1029-1060 ◽  
Author(s):  
G. J. H. McCall

SummaryThe petrography of the Mount Padbury meteorite, previously briefly recorded, is described in some detail. Both the metalliferous host material of the mesosiderite and the varied range of silicate-rich, virtually metal-free enclaves (including both familiar achondrite material and unfamiliar achondrite material) are described. Eucrite, brecciated eucrite, and a peculiar ‘shocked’ form of eucrite (resembling some terrestrial flaser-gabbros) are the calcium-rich achondrite types represented; hypersthene achondrite (including typical diogenite material and unfamiliar material) and olivine achondrite (granular aggregates of olivine not entirely similar to the unique chassignite and single crystals up to 4 in. in length) are the calcium-poor achondrite types represented. The eucrite displays more or less uniform mineralogy, but the mineral constituents are present in varying proportions, and there is a wide range of textural variations recognized. The silicate grain fragments enclosed in the metallic reticulation to form the mesosiderite host material are, significantly, entirely of minerals seen within the achondrite enclaves—plagioclase, hypersthene, pigeonite, olivine, and tridymite.These results include microscopic analysis of thin sections and polished sections, X-ray diffraction studies, optical determination of refractive indices using mineral grain mounts, and chemical analyses.The wider implications of this new and unique meteorite find are briefly considered.


2019 ◽  
Vol 116 (36) ◽  
pp. 17963-17969 ◽  
Author(s):  
Katsuya Araki ◽  
Naoto Yagi ◽  
Koki Aoyama ◽  
Chi-Jing Choong ◽  
Hideki Hayakawa ◽  
...  

Many neurodegenerative diseases are characterized by the accumulation of abnormal protein aggregates in the brain. In Parkinson’s disease (PD), α-synuclein (α-syn) forms such aggregates called Lewy bodies (LBs). Recently, it has been reported that aggregates of α-syn with a cross-β structure are capable of propagating within the brain in a prionlike manner. However, the presence of cross-β sheet-rich aggregates in LBs has not been experimentally demonstrated so far. Here, we examined LBs in thin sections of autopsy brains of patients with PD using microbeam X-ray diffraction (XRD) and found that some of them gave a diffraction pattern typical of a cross-β structure. This result confirms that LBs in the brain of PD patients contain amyloid fibrils with a cross-β structure and supports the validity of in vitro propagation experiments using artificially formed amyloid fibrils of α-syn. Notably, our finding supports the concept that PD is a type of amyloidosis, a disease featuring the accumulation of amyloid fibrils of α-syn.


MRS Bulletin ◽  
2004 ◽  
Vol 29 (3) ◽  
pp. 177-181 ◽  
Author(s):  
Ian K. Robinson ◽  
Jianwei Miao

AbstractX-rays have been widely used in the structural analysis of materials because of their significant penetration ability, at least on the length scale of the granularity of most materials. This allows, in principle, for fully three-dimensional characterization of the bulk properties of a material. One of the main advantages of x-ray diffraction over electron microscopy is that destructive sample preparation to create thin sections is often avoidable. A major disadvantage of x-ray diffraction with respect to electron microscopy is its inability to produce real-space images of the materials under investigation—there are simply no suitable lenses available. There has been significant progress in x-ray microscopy associated with the development of lenses, usually based on zone plates, Kirkpatrick–Baez mirrors, or compound refractive lenses. These technologies are far behind the development of electron optics, particularly for the large magnification ratios needed to attain high resolution. In this article, the authors report progress toward the development of an alternative general approach to imaging, the direct inversion of diffraction patterns by computation methods. By avoiding the use of an objective lens altogether, the technique is free from aberrations that limit the resolution, and it can be highly efficient with respect to radiation damage of the samples. It can take full advantage of the three-dimensional capability that comes from the x-ray penetration. The inversion step employs computational methods based on oversampling to obtain a general solution of the diffraction phase problem.


2013 ◽  
Vol 48 (3) ◽  
pp. 457-473 ◽  
Author(s):  
Pablo Munayco ◽  
Jimmy Munayco ◽  
Roberto R. de Avillez ◽  
Millarca Valenzuela ◽  
Pierre Rochette ◽  
...  

2017 ◽  
Vol 32 (3) ◽  
pp. 267-274
Author(s):  
Nil Yapici ◽  
Ferhat Gezer ◽  
Nusret Nurlu ◽  
Seref Turhan ◽  
Yuksel Ufuktepe

In the study, radiological, geochemical, and mineralogical characterization of natural stone samples used for covering or ornamental purposes collected from different quarries in Turkey was done using gamma spectrometric technique with high-purity germanium detector, X-ray fluorescence spectroscopic technique, X-ray diffraction technique and thin sections. The mean activity concentrations of 226Ra, 232Th, and 40K were measured in natural stone samples as 28.9, 30.8, and 355.0 Bqkg-1, respectively. The assessment of radiological hazards from utilization of stone samples as covering or ornamental material in building sector was made by estimating activity concentration index, absorbed gamma dose rate and annual effective dose rate. The examined natural stone samples were composed of calcite, dolomite, quartz, orthoclase, albite, biotite, hornblende, oligoclase, olivine and talc.


2021 ◽  
Vol 58 (3) ◽  
pp. 249-304
Author(s):  
Mark Longman ◽  
Virginia Gent ◽  
James Hagadorn

We integrate new and previous stratigraphic and petrographic data for the mid-Turonian Codell Sandstone to interpret its provenance, depositional characteristics, and environments. Our focus is on sedimentologic, X-ray diffraction, and X-ray fluorescence analyses of cores and thin sections spread throughout the Denver Basin, augmented by interpretation and correlation of well logs, isopach maps, outcrops, and provenance data. Although we treat the Codell as a single mappable unit, it actually consists of two geographically disjunct sandstone packages separated by a southwest-northeast-trending gap, the NoCoZo, short for No Codell Zone. The Codell is everywhere capped by a significant unconformity and across much of the northern Denver Basin rests unconformably on the underlying shales of the Carlile Shale. In the southern Denver Basin, the Codell commonly contains two parasequences, each of which becomes less muddy upward. Biostratigraphic and geochonologic data suggest that the unit represents deposition over a relatively brief time, spanning ~0.4 Ma from ~91.7 to ~91.3 Ma. The Codell is predominantly a thin (<50 ft) sheet-like package of pervasively bioturbated coarse siltstone and very fine-grained sandstone dominated by quartz and chert grains 50 to 100 μm in diameter. The unit is more phosphatic than the underlying members of the Carlile Shale, and its grain size coarsens to medium-grained in the northern part of the basin. An unusual aspect of the Codell across our study area is the generally excellent grain sorting despite the presence of an intermixed clay matrix. This duality of well sorted grains in a detrital clay matrix is due to the bioturbation that dominates the unit. Such burrowing created a textural inversion that obscures most of the unit’s primary sedimentary structures, except for thin intervals dominated by interlaminated silty shale and very fine sandstone. A relatively widespread and unburrowed example of this bedded facies is preserved in a thin (<10 ft) interval that extends across most of the northern Denver Basin where it is informally called the middle Codell bedded to laminated lithofacies. Sparse beds with hummocky or swaley cross-stratified and ripple cross-laminated fine-grained sandstone are present locally in this bedded facies. We hypothesize that Codell sediments were derived from a major deltaic source extending into the Western Interior Seaway from northwestern Wyoming, and that the Codell was deposited and reworked southward on the relatively flat floor of the Seaway by waxing and waning shelf currents as well as storms and waves. Codell sediments were spread across an area of more than 100,000 mi2 in this epeiric shelf system that spans eastern Colorado, southeastern Wyoming, western Kansas, parts of Nebraska and beyond.


Clay Minerals ◽  
1982 ◽  
Vol 17 (2) ◽  
pp. 259-262 ◽  
Author(s):  
A. Meunier ◽  
B. Velde

Precise identification of clay minerals found in granular rocks has always posed a great problem to the clay petrographer. Even if it is possible to locate the position of authigenic clay mineral formation in a thin section, subsequent identification of this same material by X-ray diffractometry is usually very difficult. Attempts have been made using selected-area radiation of thin sections (Pawluck & Dumanski, 1973; Wicks & Zussman, 1975; Wilson & Clark, 1978) but the area analysed remains relatively large, i.e. of the order of several mm2. The other solution is micro-picking of material from a thin section and subsequent identification by Debye-Scherrer camera methods (Wallace, 1955; Rickwood, 1977). This method, however, does not allow preferred orientation, and thus precise identification, of many clay species. The ideal method is to combine micro-picking from thin sections from areas of several hundreds of square microns with an oriented sample preparation, which can then be treated in the traditional way (glycolation, heating, etc.) for characterization by X-ray diffractometry.


1978 ◽  
Vol 42 (324) ◽  
pp. 499-503 ◽  
Author(s):  
R. H. Verschure

SummarySeveral types of microscope-mounted drills have been described in literature to obtain pure mineral material from thin sections or polished sections (e.g. Granigg, 1915; Moritz, 1929; Haycock, 1931; Russanow, 1937; Machairas, 1967), but all of them appear to be of limited mechanical stability and reliability. This paper describes an improved drill to extract under the microscope minute quantities of pure material from thin or polished sections. The drilling is performed in a liquid (silicon-oil) to minimize loss of the drilled-out mineral powder. With the help of a micromanipulator the liquid, together with the borings, is drawn up into a microcapillary tube (less than 30 µm in diameter) made of Lindemann glass. For identification of the mineral powder the microcapillary is mounted in a Debye-Scherrer X-ray diffraction camera.


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