KOSOVO FLY ASH: UTILIZATION IN CONCRETE AS PARTIAL CEMENT SUBSTITUENT AND THE ENVIRONMENTAL IMPACT

2017 ◽  
Vol 79 (2) ◽  
Author(s):  
Mevlan Qafleshi ◽  
Misin Misini ◽  
Driton R. Kryeziu ◽  
Lulezime Aliko
Keyword(s):  
Fly Ash ◽  
Environmental Impact ◽  
Power Plants ◽  
Thermal Power ◽  
Bottom Ash ◽  
Electrical Energy ◽  
Hardened Concrete ◽  
Environmental Benefit ◽  
Cement Production ◽  
Cement Replacement

In Kosovo, except electrical energy, thermal power plants (TPP) annually produce more than 1.5 Mt of solid waste: Fly Ash (FA) and Bottom Ash (BA). Kosovo’s construction sector annually consumes around 1 Mt of cement. The environmental impact from cement production (consumption) is the emission of around 1 Mt of CO2. The focus of this study is the utilization of FA in concrete as cement replacement, which will indirectly mitigate the CO2 emissions from cement production. The properties of concrete with FA were investigated. For determining the optimum quantity of FA in concrete, four concrete mixes with different content of class C FA were tested. Density and consistence tests of FA fresh concrete, as well as tests of mechanical properties: compressive, tensile and splitting strength of FA hardened concrete specimens were performed. Concrete resistance to permeability was tested by measuring the depth of water penetration under hydrostatic pressure. The correlation between test results of concrete specimens with FA to reference concrete without FA was done. A 30% cement replacement by fly ash showed experimentally to be reasonable. The environmental benefit would be twofold: indirect decrease of 300,000 t of CO2 and removal of 125,000 m3 of industrial waste (FA).      

Experimental Study on Various Mineral Admixtures in Fibre Reinforced Concrete

2019 ◽  
pp. 309-317
Author(s):  
Kavitha E ◽  
Karthik S ◽  
Eithya B ◽  
Seenirajan M
Keyword(s):  
Fly Ash ◽  
Rice Husk ◽  
Power Plants ◽  
Rice Husk Ash ◽  
Thermal Power ◽  
Experimental Studies ◽  
Mineral Admixtures ◽  
Hardened Concrete ◽  
Polypropylene Fibres ◽  
Concrete Production

The quantity of fly ash produced from thermal power plants in India is approximately 80 million tons each year, and its percentage utilization is less than 10%. An attempt has been made to utilize these cheaper materials in concrete production. This thesis aims at investigating the characteristics of fresh concrete and various strengths of hardened concrete made with various mineral admixtures such as fly ash. GGBFS, silica fume. Rice husk ash along with polypropylene fibres in various proportions.  M20 grade concrete is considered for experimental studies with 53grade Ordinary Portland Cement blended with varying percentages of mineral admixtures. The maximum size of coarse aggregate used is 20mm.  Various mineral admixtures such as fly ash. GGBFS.Silica fume. Rice Husk Ash were added concrete in various percentages by partially replacing cement and the optimum percentage of the mineral admixtures will be found.  Based on the obtained values, the admixture with maximum mechanical strength is determined and to this polypropylene fibre is added by varying 0 to 0.5 % by weight of cement to the mix.  The test results obtained were compared and discussed with conventional concrete.

scholarly journals Technical and radiological characterisation of fly ash and bottom ash from thermal power plant

2021 ◽  
Author(s):  
Emilija Fidanchevski ◽  
Biljana Angjusheva ◽  
Vojo Jovanov ◽  
Pece Murtanovski ◽  
Ljubica Vladiceska ◽  
...  
Keyword(s):  
Fly Ash ◽  
Effective Dose ◽  
Dose Rate ◽  
Power Plants ◽  
Annual Effective Dose ◽  
Health Effect ◽  
Thermal Power ◽  
Bottom Ash ◽  
Effective Dose Rate ◽  
Annual Effective Dose Rate

AbstractHuge quantities of fly ash and bottom ash are generated from thermal power plants and it presents great concern for country, mainly due to the environmental effects. In this study, fly ashes and bottom ash were characterized from technical and radiological aspects. Health effect due to the activity of radionuclides 226Ra, 232Th and 40K was estimated via radium equivalent activity (Raeq), external hazards index (Hex), the external absorbed dose rate (D) and annual effective dose rate (EDR). The specific surface area (40.25 m2 g−1), particle density (1.88 g cm−3) and LOI (23.49%) were typical for bottom ash. Siliceous fly ash contained 32% reactive silica. The annual effective dose rate for all ashes is ≤ 0.2 mSv y−1. Both, fly ash and bottom ash present potential secondary raw materials to be used for building purposes as result of their technological and radiological assessment.

Application of Coal Bottom Ash Zeolite on Lignin and Methylene Blue Adsorption

2019 ◽  
Vol 948 ◽  
pp. 26-32
Author(s):  
Galuh Yuliani ◽  
Siska Mutiara ◽  
Agus Setiabudi
Keyword(s):  
Methylene Blue ◽  
Fly Ash ◽  
Power Plants ◽  
Thermal Power ◽  
Bottom Ash ◽  
Freundlich Isotherm ◽  
Isotherm Models ◽  
Methylene Blue Adsorption ◽  
X Ray ◽  
Coal Bottom Ash

The amount of coal combustion byproducts, such as fly ash and bottom ash, generated by coal-based thermal power plants has been increasing at an alarming rate, hence creating huge problems on their treatments and disposals. One of the promising approaches for proper utilization of these byproducts is the conversion of fly ash and bottom ash to zeolites. In this research, zeolites wereprepared from coal bottom ash (RBA) by relatively simple and cheap conversion process using NaOH at 90°C for 24h. Prior to this, the RBA was pretreated using H2SO4 for 4h. The resulted zeolite was characterized using X-ray diffraction (XRD), X-ray fluorescence (XRF), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). XRD results confirmed the formation of sodium aluminosilicate hydrate predominated upon the bottom ash and NaOH 5M ratio of 1:8. XRF results also indicated the domination of Al2O3 and SiO2 in the zeolite composition. FTIR spectra showed characteristic zeolite peaks at 900-1100, 400-500 and 550-660 cm–1forSi-O, Al-O, and Si-O-Al absorptions, respectively. The synthetic zeolite was then applied as an adsorbent for lignin and methylene blue in aqueous solutions. It was found that the Qmax for lignin and methylene blue was16.13 mg/g and 34.13 mg/g, respectively. When fitted using Langmuir and Freundlich isotherm models, the methylene blue adsorption data fitted Langmuir isotherm while those of lignin fitted Freundlich isotherm. It was concluded that the chemical interaction between zeolite and methylene blue may lead to the chemisorption mechanism to prevail.

scholarly journals Evaluating the resource recovery potential of fly ash deposits using electrical and electromagnetic methods

2020 ◽  
Author(s):  
David Caterina ◽  
Itzel Isunza Manrique ◽  
Hadrien Michel ◽  
Christin Bobe ◽  
Hugo Lucas ◽  
...  
Keyword(s):  
Fly Ash ◽  
Industrial Waste ◽  
Power Plants ◽  
Water Saturation ◽  
Inorganic Compounds ◽  
Thermal Power ◽  
Geophysical Methods ◽  
Bottom Ash ◽  
Great Influence ◽  
Recovery Potential

<p>Burning coal, or municipal solid waste, in thermal power plants and in metallurgical industries is responsible for the production of large amounts of combustion residues, which depending on their particle size and density, are usually referred to as fly or bottom ash. Nowadays, they represent one of the main types of industrial waste generated. Although their composition is strongly dependent on the material burned, they typically contain ferro-aluminosilicate minerals with potentially toxic trace elements and inorganic compounds that can cause environmental problems when stored in non-sanitary landfills. At the same time, they also represent an economically interesting secondary resource as they can be valorised by replacing aggregates/additives in cement or ceramics production. Surprisingly, despite the environmental and economic considerations for these materials, their geophysical properties remain largely unknown. A better understanding of their geophysical identity could enable using geophysical methods to, for example, improve the estimation of the volume and quality of recoverable resources from ash deposition sites. In this contribution, we show the results of geophysical investigations carried out in three of these sites located in Belgium. The main geophysical techniques involved are electrical resistivity tomography, time-domain induced polarization and frequency-domain electromagnetic induction. The deposits studied generally exhibit high electrical conductivity presumably due to the high hygroscopy of fly ash, the high chlorides content and the presence of ferro-aluminosilicate minerals, each of which enhancing electrical conduction mechanisms, although the effect of the first two is conditioned by the level of water saturation present. The presence of magnetite, or other ferri- or ferromagnetic materials, may explain the high magnetic susceptibility observed. Yet, while representing a relatively homogeneous type of waste, strong variations in geophysical properties were observed between and within different sites. This suggests a great influence of the ash production process, but also of the site-specific conditions. These first results argue for further field and laboratory experiments to validate the exploratory geophysical survey results and to identify the decisive influencing factors explaining the observed electrical and magnetic response. Improved insight in the geophysical signature of fly ash deposits will allow for more accurate interpretations of geophysical measurements, in its turn providing a more sound basis for guiding conventional sampling design and thereby contributing to a more reliable assessment of the value of these industrial waste landfills in terms of the secondary resources they can deliver.</p>

Fly Ash-Based Geopolymer: Green Material in Carbon-Constrained Society

2021 ◽  
Vol 321 ◽  
pp. 65-71
Author(s):  
Hoc Thang Nguyen ◽  
Phong Thanh Dang
Keyword(s):  
Fly Ash ◽  
Power Plants ◽  
Thermal Power ◽  
Bottom Ash ◽  
Coal Ash ◽  
Raw Material ◽  
Engineering Properties ◽  
Gravimetric Analysis ◽  
Green Materials ◽  
Alumino Silicate

Climate change is recognized as a global problem and even the industrial and construction sectors are trying to reduce the green-house gas emissions, especially on CO2 emissions. In Vietnam, the coal-fired thermal power plants are discharging millions of tons of CO2 and coal ash annually. This coal ash is comprised of about 80% of fly ash and the rest is bottom ash. This study would like to introduce one of the potential solutions in a carbon-constrained society that would not only manage the fly ash but also utilized this as raw material for green materials through geopolymerization. The geopolymer-based material has lower energy consumption, minimal CO2 emissions and lower production cost as it valorizes industrial waste. The fly ash containing high alumino-silicate resources from a coal-fired power plant in Vietnam was mixed with sodium silicate and sodium hydroxide solutions to obtain the geopolymeric pastes. The pastes were molded in 10x10x20cm molds and then cured at room temperature for 28 days. The 28-day geopolymer specimens were carried out to test for engineering properties such as compressive strength (MPa), volumetric weight (kg/m3), and water absorption (kg/m3). The microstructure analysis was also conducted for this eco-friendly materials using X ray diffraction (XRD), and Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscope (SEM), Differential Thermal Analysis - Thermal Gravimetric Analysis (DTA-TGA).

scholarly journals Effect of Biomass Fly Ash on Fresh and Hardened Properties of High Volume Fly Ash Mortars

Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 233
Author(s):  
Elisabete R. Teixeira ◽  
Aires Camões ◽  
Fernando G. Branco ◽  
José Campos Matos
Keyword(s):  
Fly Ash ◽  
Power Plants ◽  
Coal Fly Ash ◽  
Thermal Power ◽  
High Volume ◽  
Hydrated Lime ◽  
Cement Replacement ◽  
High Volume Fly Ash ◽  
Hardened State ◽  
Biomass Fly Ash

The objective of this work was to assess the use of biomass fly ash (BFA) as cement replacement material or as an alkalinity source in high volume fly ash mortar and concrete. Mortar formulations were prepared with different types of cement replacement: fly ash from thermal power plants, BFA, a blend of two pozzolans, and small amounts of BFA or/and hydrated lime (HL). Mortar formulations were tested both in the fresh and hardened state. The replacement of cement by the two fly ashes led to a decrease in the mechanical strength. The best strength values were obtained when higher HL content was introduced in mortars, however, mortars with the lower BFA content presented the best results for the majority of the tests. In general, BFA has a similar effect on cementitious mortars to coal fly ash, having good performance as cement replacement.

A Review on Utilization of Fly- Ash and Pond-Ash as a Partial Replacement of Cement in Concrete Mix Design

2018 ◽  
pp. 413-418
Author(s):  
Harshkumar Patel ◽  
Yogesh Patel
Keyword(s):  
Fly Ash ◽  
Electricity Generation ◽  
Power Plants ◽  
Renewable Energy Sources ◽  
Thermal Power ◽  
Strength Test ◽  
Partial Replacement ◽  
Pond Ash ◽  
Research Activities ◽  
Ash Disposal

Now-a-days energy planners are aiming to increase the use of renewable energy sources and nuclear to meet the electricity generation. But till now coal-based power plants are the major source of electricity generation. Disadvantages of coal-based thermal power plants is disposal problem of fly ash and pond ash. It was earlier considered as a total waste and environmental hazard thus its use was limited, but now its useful properties have been known as raw material for various application in construction field. Fly ash from the thermal plants is available in large quantities in fine and coarse form. Fine fly ash is used in construction industry in some amount and coarse fly ash is subsequently disposed over land in slurry forms. In India around 180 MT fly is produced and only around 45% of that is being utilized in different sectors. Balance fly ash is being disposed over land. It needs one acre of land for ash disposal to produce 1MW electricity from coal. Fly ash and pond ash utilization helps to reduce the consumption of natural resources. The fly ash became available in coal based thermal power station in the year 1930 in USA. For its gainful utilization, scientist started research activities and in the year 1937, R.E. Davis and his associates at university of California published research details on use of fly ash in cement concrete. This research had laid foundation for its specification, testing & usages. This study reports the potential use of pond-ash and fly-ash as cement in concrete mixes. In this present study of concrete produced using fly ash, pond ash and OPC 53 grade will be carried. An attempt will be made to investigate characteristics of OPC concrete with combined fly ash and pond ash mixed concrete for Compressive Strength test, Split Tensile Strength test, Flexural Strength test and Durability tests. This paper deals with the review of literature for fly-ash and pond-ash as partial replacement of cement in concrete.

scholarly journals Preparation of Synthetic Zeolites from Coal Fly Ash by Hydrothermal Synthesis

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1267
Author(s):  
David Längauer ◽  
Vladimír Čablík ◽  
Slavomír Hredzák ◽  
Anton Zubrik ◽  
Marek Matik ◽  
...  
Keyword(s):  
Fly Ash ◽  
Coal Combustion ◽  
Power Plants ◽  
Coal Fly Ash ◽  
Thermal Power ◽  
Product Analysis ◽  
Coal Combustion Products ◽  
X Ray ◽  
Wide Range ◽  
Silica Alumina

Large amounts of coal combustion products (as solid products of thermal power plants) with different chemical and physical properties cause serious environmental problems. Even though coal fly ash is a coal combustion product, it has a wide range of applications (e.g., in construction, metallurgy, chemical production, reclamation etc.). One of its potential uses is in zeolitization to obtain a higher added value of the product. The aim of this paper is to produce a material with sufficient textural properties used, for example, for environmental purposes (an adsorbent) and/or storage material. In practice, the coal fly ash (No. 1 and No. 2) from Czech power plants was firstly characterized in detail (X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX), particle size measurement, and textural analysis), and then it was hydrothermally treated to synthetize zeolites. Different concentrations of NaOH, LiCl, Al2O3, and aqueous glass; different temperature effects (90–120 °C); and different process lengths (6–48 h) were studied. Furthermore, most of the experiments were supplemented with a crystallization phase that was run for 16 h at 50 °C. After qualitative product analysis (SEM-EDX, XRD, and textural analytics), quantitative XRD evaluation with an internal standard was used for zeolitization process evaluation. Sodalite (SOD), phillipsite (PHI), chabazite (CHA), faujasite-Na (FAU-Na), and faujasite-Ca (FAU-Ca) were obtained as the zeolite phases. The content of these zeolite phases ranged from 2.09 to 43.79%. The best conditions for the zeolite phase formation were as follows: 4 M NaOH, 4 mL 10% LiCl, liquid/solid ratio of 30:1, silica/alumina ratio change from 2:1 to 1:1, temperature of 120 °C, process time of 24 h, and a crystallization phase for 16 h at 50 °C.

scholarly journals Assessment of Characteristics of Acid Mine Drainage Treated with Fly Ash

2021 ◽  
Vol 11 (9) ◽  
pp. 3910
Author(s):  
Saba Shirin ◽  
Aarif Jamal ◽  
Christina Emmanouil ◽  
Akhilesh Kumar Yadav
Keyword(s):  
Fly Ash ◽  
Acid Mine Drainage ◽  
Power Plants ◽  
Mine Drainage ◽  
Thermal Power ◽  
Mineralogical Characterization ◽  
Acid Mine ◽  
Before And After ◽  
Abandoned Coal Mines

Acid mine drainage (AMD) occurs naturally in abandoned coal mines, and it contains hazardous toxic elements in varying concentrations. In the present research, AMD samples collected from an abandoned mine were treated with fly ash samples from four thermal power plants in Singrauli Coalfield in the proximate area, at optimized concentrations. The AMD samples were analyzed for physicochemical parameters and metal content before and after fly ash treatment. Morphological, geochemical and mineralogical characterization of the fly ash was performed using SEM, XRF and XRD. This laboratory-scale investigation indicated that fly ash had appreciable neutralization potential, increasing AMD pH and decreasing elemental and sulfate concentrations. Therefore, fly ash may be effectively used for AMD neutralization, and its suitability for the management of coalfield AMD pits should be assessed further.

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