scholarly journals The NOx and N2O Emission Characteristics of an HCCI Engine Operated With n-Heptane

2011 ◽  
Vol 134 (1) ◽  
Author(s):  
Hailin Li ◽  
W. Stuart Neill ◽  
Hongsheng Guo ◽  
Wally Chippior
Keyword(s):  
N2o Emission ◽  
Combustion Efficiency ◽  
Operating Conditions ◽  
N2o Emissions ◽  
Emission Characteristics ◽  
Nox Emissions ◽  
Oxides Of Nitrogen ◽  
Incomplete Combustion ◽  
Hcci Combustion ◽  
Wide Range

This paper presents the oxides of nitrogen (NOx) and nitrous oxide (N2O) emission characteristics of a Cooperative Fuel Research (CFR) engine modified to operate in homogeneous charge compression ignition (HCCI) combustion mode. N-heptane was used as the fuel in this research. Several parameters were varied, including intake air temperature and pressure, air/fuel ratio (AFR), compression ratio (CR), and exhaust gas recirculation (EGR) rate, to alter the HCCI combustion phasing from an overly advanced condition where knocking occurred to an overly retarded condition where incomplete combustion occurred with excessive emissions of unburned hydrocarbons (UHC) and carbon monoxide (CO). NOx emissions below 5 ppm were obtained over a fairly wide range of operating conditions, except when knocking or incomplete combustion occurred. The NOx emissions were relatively constant when the combustion phasing was within the acceptable range. NOx emissions increased substantially when the HCCI combustion phasing was retarded beyond the optimal phasing even though lower combustion temperatures were expected. The increased N2O and UHC emissions observed with retarded combustion phasing may contribute to this unexpected increase in NOx emissions. N2O emissions were generally less than 0.5 ppm; however, they increased substantially with excessively retarded and incomplete combustion. The highest measured N2O emissions were 1.7 ppm, which occurred when the combustion efficiency was approximately 70%.

The NOx and N2O Emission Characteristics of an HCCI Engine Operated With N-Heptane

2007 ◽  
Author(s):  
Hailin Li ◽  
W. Stuart Neill ◽  
Hongsheng Guo ◽  
Wally Chippior
Keyword(s):  
N2o Emission ◽  
Combustion Efficiency ◽  
N2o Emissions ◽  
Emission Characteristics ◽  
Nox Emissions ◽  
Fuel Injector ◽  
Incomplete Combustion ◽  
Hcci Combustion ◽  
Wide Range ◽  
Combustion Phase

This paper presents the NOx and N2O emission characteristics of a Cooperative Fuel Research (CFR) engine modified to operate in Homogeneous Charge Compression Ignition (HCCI) combustion mode using an air-assist port fuel injector. The single-cylinder engine was fuelled with n-heptane for these experiments. The parameters examined include intake air temperature and pressure, air/fuel ratio, compression ratio, and exhaust gas recirculation (EGR) rate. The parameters were varied in order to change the combustion phasing from advanced (knocking) to retarded (incomplete combustion) conditions. NOx emissions were less than 5 ppm for a fairly wide range of combustion phases, except when knocking or incomplete combustion occurred, and were largely unaffected by the parameter varied when the combustion phase was within the acceptable range. It was also found that NOx emissions increased significantly when retarded and incomplete combustion was observed even though lower combustion temperatures were expected. The increased N2O and unburned hydrocarbon (THC) emissions usually observed with retarded combustion phasing, as well as the deteriorated combustion efficiency, may contribute to this unexpected increase in NOx emissions. It was also shown that N2O emissions were extremely low (less than 0.5 ppm) except when incomplete combustion was observed.

Effects of Cycle Operating Conditions on Combustor Performance

1997 ◽  
Vol 119 (1) ◽  
pp. 45-49 ◽  
Author(s):  
N. T. Davis ◽  
V. G. McDonell ◽  
G. S. Samuelsen
Keyword(s):  
Cost Function ◽  
Duty Cycle ◽  
Load Condition ◽  
Combustion Efficiency ◽  
Operating Conditions ◽  
Nox Emissions ◽  
Variable Geometry ◽  
Oxides Of Nitrogen ◽  
Mixing Processes ◽  
The Cost

To mitigate the environmental impact of next-generation gas turbine combustors, the emission performance at each condition throughout the load duty cycle must be optimized. Achieving this with a single combustor geometry may not be possible. Rather, the mixing processes and airflow splits must likely be modified as a function of load in order to (1) abate the emission of oxides of nitrogen, (2) maintain combustion efficiency, and (3) preclude lean blow-out over the entire duty cycle. The present study employs a model combustor to evaluate combustor performance as a function of load and explore the application of variable geometry to optimize performance at each condition. A parametric variation of flow splits is conducted at each load condition by independently adjusting the primary jet area and swirler choke area. The resultant impact on combustor performance is measured and quantified in terms of a cost function. The cost function is defined to increase with improving combustor performance (e.g., improving combustion efficiency and/or declining NOx emissions). Cycle operating conditions are found to alter the response mappings of efficiency and NOx. As a result, the optimal configuration of the combustor changes as the load is varied over the duty cycle. The results provide guidance on the application of active control.

Effects of Cycle Operating Conditions on Combustor Performance

1995 ◽  
Author(s):  
N. T. Davis ◽  
V. G. McDonell ◽  
G. S. Samuelsen
Keyword(s):  
Cost Function ◽  
Duty Cycle ◽  
Load Condition ◽  
Combustion Efficiency ◽  
Operating Conditions ◽  
Nox Emissions ◽  
Variable Geometry ◽  
Oxides Of Nitrogen ◽  
Mixing Processes ◽  
The Cost

To mitigate the environmental impact of next generation gas turbine combustors, the emission performance at each condition throughout the load duty cycle must be optimized. Achieving this with a single combustor geometry may not be possible. Rather, the mixing processes and air flow splits must likely be modified as a function of load in order to (1) abate the emission of oxides of nitrogen, (2) maintain combustion efficiency, and (3) preclude lean blow out over the entire duty cycle. The present study employs a model combustor to evaluate combustor performance as a function of load and explore the application of variable geometry to optimize performance at each condition. A parametric variation of flow splits is conducted at each load condition by independently adjusting the primary jet area and swirler choke area. The resultant impact on combustor performance is measured and quantified in terms of a cost function. The cost function is defined to increase with improving combustor performance (e.g., improving combustion efficiency and/or declining NOx emissions). Cycle operating conditions are found to alter the response mappings of efficiency and NOx. As a result, the optimal configuration of the combustor changes as the load is varied over the duty cycle. The results provide guidance on the application of active control.

The effect of air/fuel ratio on the CO and NOx emissions for a twin-spark motorcycle gasoline engine under wide range of operating conditions

Energy ◽  
2019 ◽  
Vol 169 ◽  
pp. 1202-1213 ◽  
Author(s):  
Banglin Deng ◽  
Qing Li ◽  
Yangyang Chen ◽  
Meng Li ◽  
Aodong Liu ◽  
...  
Keyword(s):  
Gasoline Engine ◽  
Operating Conditions ◽  
Nox Emissions ◽  
Fuel Ratio ◽  
Wide Range

Combustion Characteristics of Small Size Gas Turbine Combustor Fueled by Biomass Gas Employing Flameless Combustion

2007 ◽  
Author(s):  
Masato Hiramatsu ◽  
Yoshifumi Nakashima ◽  
Sadamasa Adachi ◽  
Yudai Yamasaki ◽  
Shigehiko Kaneko
Keyword(s):  
Gas Turbine ◽  
Combustion Efficiency ◽  
Combustion Characteristics ◽  
Operating Conditions ◽  
Nox Emissions ◽  
Gas Turbine Combustor ◽  
Flameless Combustion ◽  
Engine Exhaust ◽  
Micro Gas Turbine

One approach to achieving 99% combustion efficiency (C.E.) and 10 ppmV or lower NOx (at 15%O2) in a micro gas turbine (MGT) combustor fueled by biomass gas at a variety of operating conditions is with the use of flameless combustion (FLC). This paper compares experimentally obtained results and CHEMKIN analysis conducted for the developed combustor. As a result, increase the number of stage of FLC combustion enlarges the MGT operation range with low-NOx emissions and high-C.E. The composition of fuel has a small effect on the characteristics of ignition in FLC. In addition, NOx in the engine exhaust is reduced by higher levels of CO2 in the fuel.

Ambient Condition Effects on NOx and CO Emissions From Process Heaters

2008 ◽  
Author(s):  
Wesley R. Bussman ◽  
Charles E. Baukal
Keyword(s):  
Atmospheric Pressure ◽  
Ambient Air ◽  
Operating Conditions ◽  
Nox Emissions ◽  
Ambient Conditions ◽  
Fuel Gas ◽  
Natural Draft ◽  
Actual Operating ◽  
Wide Range ◽  
Pollution Emissions

Because process heaters are typically located outside, their operation is subject to the weather. Heaters are typically tuned at a given set of conditions; however, the actual operating conditions may vary dramatically from season to season and sometimes even within a given day. Wind, ambient air temperature, ambient air humidity, and atmospheric pressure can all significantly impact the O2 level, which impacts both the thermal efficiency and the pollution emissions from a process heater. Unfortunately, most natural draft process burners are manually controlled on an infrequent basis. This paper shows how changing ambient conditions can considerably impact both CO and NOx emissions if proper adjustments are not made as the ambient conditions change. Data will be presented for a wide range of operating conditions to show how much the CO and NOx emissions can be affected by changes in the ambient conditions for fuel gas fired natural draft process heaters, which are the most common type used in the hydrocarbon and petrochemical industries. Some type of automated burner control, which is virtually non-existent today in this application, is recommended to adjust for the variations in ambient conditions.

The Oxides of Nitrogen: Their Relation to Tropospheric Ozone

2015 ◽  
Author(s):  
Jack G. Calvert ◽  
John J. Orlando ◽  
William R. Stockwell ◽  
Timothy J. Wallington
Keyword(s):  
Tropospheric Ozone ◽  
Anthropogenic Activity ◽  
N2o Emissions ◽  
Nox Emissions ◽  
Oxides Of Nitrogen ◽  
Assessment Report ◽  
Natural Emissions ◽  
Gas Phase Oxidation ◽  
Odd Nitrogen

Reactive (or “odd”) nitrogen is emitted into the atmosphere in a variety of forms, with the most important being NOx (NO and NO2), ammonia (NH3), and nitrous oxide (N2O). Emissions of these species into the atmosphere have been summarized, for example, by the IPCC Fourth Assessment Report (the AR4; IPCC, 2007). Some discussion of NOx emissions and trends has also been presented in Chapter I. Emissions of NOx are mainly the result of anthropogenic activity associated with fossil fuel combustion and industrial activity. For the 1990s, the AR4 estimates total anthropogenic NOx emissions of 33.4 TgN yr−1, with natural emissions (mostly from soil and lightning) accounting for an additional 8.4–13.7 TgN yr−1. Ammonia emissions are comparable in magnitude to those for NOx, with anthropogenic emissions (45.5 TgN yr−1) again exceeding natural emissions (10.6 TgN yr−1). Although the majority of the ammonia produces aerosols or is scavenged by aerosol and is subsequently lost from the atmosphere, some gas phase oxidation does occur, which can in part lead to NOx production. The N2O source strength is about 17.7 TgN yr−1, with natural sources outweighing anthropogenic ones (IPCC, 2007). However, N2O is essentially inert in the troposphere, and thus the vast majority of its photooxidation and concomitant NOx release occurs in the stratosphere. The major NOx − related reactions occurring in the Earth’s troposphere are summarized in Figure III-A-1. As just alluded to, the species NO and NO2 are jointly referred to as NOx and are often treated collectively. This is because, under daytime conditions, these two species are rapidly interconverted, with the interconversion occurring on a much shorter timescale than the loss of either species.

Application of Diethyl Ether to Reduce Smoke and NOx Emissions Simultaneously With Diesel and Biodiesel Fueled Engines

2008 ◽  
Author(s):  
Masoud Iranmanesh ◽  
J. P. Subrahmanyam ◽  
M. K. G. Babu
Keyword(s):  
Diesel Engine ◽  
Emission Characteristics ◽  
Nox Emissions ◽  
Oxides Of Nitrogen ◽  
Heating Value ◽  
Simultaneous Reduction ◽  
Performance And Emission ◽  
Oxygenated Fuel ◽  
Di Diesel Engine ◽  
Biodiesel Blend

In this investigation, tests were conducted on a single cylinder DI diesel engine fueled with neat diesel and biodiesel as baseline fuel with addition of 5 to 20% DEE on a volume basis in steps of 5 vol.% as supplementary oxygenated fuel to analyze the simultaneous reduction of smoke and oxides of nitrogen. Some physicochemical properties of test fuels such as heating value, viscosity, specific gravity and distillation profile were also determined in accordance to the ASTM standards. The results obtained from the engine tests have shown a significant reduction in NOX emissions especially for biodiesel and a little decrease in smoke of DEE blends compared with baseline fuels. A global overview of the results has shown that the 5% DEE-Diesel fuel and 15% DEE-Biodiesel blend are the optimal blend based on performance and emission characteristics.

Modeling the Effects of Variable Intake Valve Timing on Diesel HCCI Combustion at Varying Load, Speed, and Boost Pressures

2008 ◽  
Vol 130 (5) ◽  
Author(s):  
C. L. Genzale ◽  
S.-C. Kong ◽  
R. D. Reitz
Keyword(s):  
Operating Conditions ◽  
Effective Control ◽  
Intake Valve ◽  
Valve Timing ◽  
Detailed Chemical Kinetics ◽  
Hcci Combustion ◽  
Wide Range ◽  
Particulate Matter Emissions ◽  
Charge Mixture ◽  
Ignition And Combustion

Homogeneous charge compression ignition (HCCI) operated engines have the potential to provide the efficiency of a typical diesel engine, with very low NOx and particulate matter emissions. However, one of the main challenges with this type of operation in diesel engines is that it can be difficult to control the combustion phasing, especially at high loads. In diesel HCCI engines, the premixed fuel-air charge tends to ignite well before top dead center, especially as load is increased, and a method of delaying the ignition is necessary. The development of variable valve timing (VVT) technology may offer an important advantage in the ability to control diesel HCCI combustion. VVT technology can allow for late intake valve closure (IVC) times, effectively changing the compression ratio of the engine. This can decrease compression temperatures and delay ignition, thus allowing the possibility to employ HCCI operation at higher loads. Furthermore, fully flexible valve trains may offer the potential for dynamic combustion phasing control over a wide range of operating conditions. A multidimensional computational fluid dynamics model is used to evaluate combustion event phasing as both IVC times and operating conditions are varied. The use of detailed chemical kinetics, based on a reduced n-heptane mechanism, provides ignition and combustion predictions and includes low-temperature chemistry. The use of IVC delay is demonstrated to offer effective control of diesel HCCI combustion phasing over varying loads, engine speeds, and boost pressures. Additionally, as fueling levels are increased, charge mixture properties are observed to have a significant effect on combustion phasing. While increased fueling rates are generally seen to advance combustion phasing, the reduction of specific heat ratio in higher equivalence ratio mixtures can also cause noticeably slower temperature rise rates, affecting ignition timing and combustion phasing. Variable intake valve timing may offer a promising and flexible control mechanism for the phasing of diesel HCCI combustion. Over a large range of boost pressures, loads, and engine speeds, the use of delayed IVC is shown to sufficiently delay combustion in order to obtain optimal combustion phasing and increased work output, thus pointing towards the possibility of expanding the current HCCI operating range into higher load points.

NO and N2O Formation/Decomposition Characteristics During Co-Combustion of Coal With Biomass

2005 ◽  
Author(s):  
Asri Gani ◽  
Ichiro Naruse
Keyword(s):  
Coal Combustion ◽  
Co2 Emission ◽  
N2o Emission ◽  
Reaction Scheme ◽  
Volatile Matter ◽  
N2o Emissions ◽  
Emission Characteristics ◽  
Homogeneous Reaction ◽  
Fuel Cost ◽  
N2o Formation

Co-combustion technologies of coal with biomass have been applied in many practical coal combustion boilers in order to reduce CO2 emission, fuel cost and so forth. Furthermore, the biomass may be able to enhance the combustion performance and to control NOx and N2O emissions since the biomass contains high volatile matter and evolves NH3 as the main volatile N-species. This study focuses on NOx and N2O emission characteristics during co-combustion of coal with biomass. The main results obtained show that emission amount of NO and N2O during co-combustion is relatively more than that during coal combustion. At least, NO behavior can be simulated by the homogeneous reaction scheme relating to NOx even at constant temperature. However, the N2O behavior will be influenced by heterogeneous schemes due to char particles during co-combustion.

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