scholarly journals Investigation of the Use of an Inorganic Aqueous Solution in Aluminum-Made Phase-Change Heat Transfer Devices

2017 ◽  
Vol 139 (12) ◽  
Author(s):  
Qi Yao ◽  
Michael J. Stubblebine ◽  
Ivan Catton

An inorganic aqueous solution, known as IAS, has shown its compatibility with aluminum phase-change heat transfer devices. When using IAS in aluminum devices, aluminum prefers to react with the two oxidizers, permanganate and chromate, rather than water to generate a thin and compact layer of aluminum oxide, which protects the aluminum surface and prevents further reactions. In addition, an electrochemical theory of aluminum passivation is introduced, and the existence of an electrochemical cycle is demonstrated by an aluminum thermosiphon test. The electrochemistry cycle, built up by liquid back flow and tube wall, allows the oxidizers to passivate the aluminum surface inside the device without being directly in contact with it. However, failure was detected while using IAS in thermosiphons with air natural convection cooling. The importance of a continuous liquid back flow to aluminum passivation in phase-change heat transfer devices is pointed out, and a vertical thermosiphon test with natural convection cooling is used to demonstrate that a discontinuous liquid back flow is the main reason of the failures.

2017 ◽  
Vol 140 (4) ◽  
Author(s):  
Qi Yao ◽  
Jacob Supowit ◽  
Ivan Catton

A novel inorganic aqueous solution (IAS) is shown to have a better heat transfer performance than water when used as the working fluid in copper-made phase-change heat transfer devices. First, the physical properties of IAS are measured and compared to those of water. Another, a chemical analysis is performed, and the chemical reactions involved between IAS and the copper surface are listed and categorized by their contributions to the heat transfer performance. In addition, a capillary rise test is performed to show how each chemical contributes to the improvement of the surface wettability. Last, using IAS in copper-made phase-change heat transfer devices is discussed, and the main focus is how IAS improves the heat transfer performance by a smaller thermal resistance and a larger critical heat flux. The conclusion is validated by thermo-siphon tests at different inclination angles.


Author(s):  
Jacob Supowit ◽  
Sean Reilly ◽  
Ladan Amouzegar ◽  
Ivan Catton

Frozen startup of phase change heat transfer devices is a complex problem that can have a large impact on heat transfer systems. A patented novel working fluid developed at UCLA comprised of an inorganic aqueous solution (IAS) was investigated for potential effects on the freeze/thaw capabilities in phase change heat transfer devices by examining the melting process of droplets. Preliminary visual tests were conducted to gain insight into any physical processes that surface augmentation created by this fluid may have on the freezing and melting process. These tests demonstrated significant differences in liquid spreading, the melting process, and the melting rate of droplets on surfaces pre-treated with IAS. Contact angle measurements exhibited enhanced wetting properties. SEM images of frozen droplets showed that liquid freezes in the small capillary wick formed by the initial evaporation of IAS. Video of melting droplets showed a significant increase in melting rate when the surface was first treated with IAS due to superior liquid spreading.


Author(s):  
Michael Stubblebine ◽  
Sean Reilly ◽  
Qi Yao ◽  
Ivan Catton

Heat pipes are used in many applications as an effective means for transferring heat from a source to a sink. The basic heat pipe typically consists of a solid metal casing within which a working fluid is sealed inside at a given pressure. The latent heat transfer via the heat pipe’s working fluid allows it to carry a larger amount of heat energy than would normally be possible with an identically dimensioned solid metal rod. Water is often used as a working fluid due to its high heat of vaporization and suitable operating range for electronics cooling. For many applications, especially space, aluminum is desired as a casing material for its high thermal conductivity, low weight, and low cost. However, water is incompatible for use with aluminum heat pipes because it forms a non-condensable gas (NCG), hydrogen, when they contact. In this work, an inorganic aqueous solution (IAS), which has thermophysical properties similar to water, has been used as the working fluid with an aluminum alloy 5052-H2 casing. The prepared thermosiphon underwent long-term lifetime testing and the results indicate no tube failure or significant NCG formation for the duration of the 9 week study. Furthermore, the data indicate that the IAS fluid not only inhibited NCG production but also led to a reduction in heat pipe thermal resistance over time. It is believed that the chemicals in IAS react with the aluminum surface to create a compact oxide layer and electrochemical reaction which prevents hydrogen generation. A secondary, hydrophilic surface coating is also generated by the fluid on top of the first oxide (passivation) layer. This hydrophilic layer is believed to be responsible for the heat transfer enhancement which was observed during testing and the reduction in ΔT (defined as Tevap−Tcond) over time. Aluminum heat pipes used currently in practice utilize ammonia, or other non-water based working fluids, which have inferior latent heats of vaporization compared to water or an aqueous-based fluid such as IAS. The use of aluminum heat pipe casings in combination with a water-based fluid such as IAS has the potential to provide a significant increase in heat transport capability per device unit mass over traditional ammonia charged aluminum heat pipes.


Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1496
Author(s):  
Mohammad Ghalambaz ◽  
S.A.M. Mehryan ◽  
Ahmad Hajjar ◽  
Mohammad Yacoub Al Shdaifat ◽  
Obai Younis ◽  
...  

A wavy shape was used to enhance the thermal heat transfer in a shell-tube latent heat thermal energy storage (LHTES) unit. The thermal storage unit was filled with CuO–coconut oil nano-enhanced phase change material (NePCM). The enthalpy-porosity approach was employed to model the phase change heat transfer in the presence of natural convection effects in the molten NePCM. The finite element method was applied to integrate the governing equations for fluid motion and phase change heat transfer. The impact of wave amplitude and wave number of the heated tube, as well as the volume concertation of nanoparticles on the full-charging time of the LHTES unit, was addressed. The Taguchi optimization method was used to find an optimum design of the LHTES unit. The results showed that an increase in the volume fraction of nanoparticles reduces the charging time. Moreover, the waviness of the tube resists the natural convection flow circulation in the phase change domain and could increase the charging time.


Author(s):  
Qi Yao ◽  
Mike Stubblebine ◽  
Sean Reilly ◽  
Ladan Amouzegar ◽  
Ivan Catton

A novel Inorganic Aqueous Solution (IAS) is shown to have a better thermal performance than water when used as the working fluid in copper or aluminum made heat transfer devices. The effect of each chemical in the IAS and how it benefits heat transfer performance for different materials is explained. It was found that the IAS fluid reacts with copper and coats the surface with a layer of hydrophilic products during the initial boiling process. The surface roughness and wettability were increased which led to an enhanced heat transfer performance. The IAS passivates aluminum surfaces and makes water compatible for use with aluminum heat transfer devices. In addition, IAS has potential to improve the heat transfer performance by 50% lower the superheat when used with non-reactive material heat transfer devices.


1998 ◽  
Vol 120 (4) ◽  
pp. 840-857 ◽  
Author(s):  
M. P. Dyko ◽  
K. Vafai

A heightened awareness of the importance of natural convective cooling as a driving factor in design and thermal management of aircraft braking systems has emerged in recent years. As a result, increased attention is being devoted to understanding the buoyancy-driven flow and heat transfer occurring within the complex air passageways formed by the wheel and brake components, including the interaction of the internal and external flow fields. Through application of contemporary computational methods in conjunction with thorough experimentation, robust numerical simulations of these three-dimensional processes have been developed and validated. This has provided insight into the fundamental physical mechanisms underlying the flow and yielded the tools necessary for efficient optimization of the cooling process to improve overall thermal performance. In the present work, a brief overview of aircraft brake thermal considerations and formulation of the convection cooling problem are provided. This is followed by a review of studies of natural convection within closed and open-ended annuli and the closely related investigation of inboard and outboard subdomains of the braking system. Relevant studies of natural convection in open rectangular cavities are also discussed. Both experimental and numerical results obtained to date are addressed, with emphasis given to the characteristics of the flow field and the effects of changes in geometric parameters on flow and heat transfer. Findings of a concurrent numerical and experimental investigation of natural convection within the wheel and brake assembly are presented. These results provide, for the first time, a description of the three-dimensional aircraft braking system cooling flow field.


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