Effects of Particle Size Distribution on Compacted Density of Lithium Iron Phosphate 18650 Battery

Author(s):  
Lei Chen ◽  
Zhenyu Chen ◽  
Shuaishuai Liu ◽  
Biaofeng Gao ◽  
Junwei Wang

The effects of particle size distribution on compacted density of as-prepared spherical lithium iron phosphate (LFP) LFP-1 and LFP-2 materials electrode for high-performance 18650 Li-ion batteries are investigated systemically, while the selection of two commercial materials LFP-3 and LFP-4 as a comparison. The morphology study and physical characterization results show that the LFP materials are composed of numerous particles with an average size of 300–500 nm, and have well-developed interconnected pore structure and a specific surface area of 13–15 m2/g. For CR2032 coin-type cell, the specific discharge capacities of the LFP-1 and LFP-2 are about 165 mAh/g at 0.2 C. For 18650 batteries, results indicate that the LFP-3 material has the highest compacted density of 2.52 g/cm3 at a concentrated particle size distribution such as D10 = 0.56 μm, D50 = 1.46 μm, and D90 = 6.53 μm. By mixing two different particle sizes of LFP-1 and LFP-2, the compaction density can be increased significantly from 1.90 g/cm3 to 2.25 g/cm3.

Geosciences ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 55
Author(s):  
Aleksandra Gorączko ◽  
Szymon Topoliński

Particle size distribution is one of the most significant factors determining physical soil properties. Laser diffraction analysis (LDA) is an alternative method to the traditional hydrometric methods (HM) used to determine particle size distribution in soils. However, significant differences in fraction content are found in relation to the applied methods of a particle size test. Above all, measurements performed by LDA for clayey soils usually produce different results to those based on Stokes’ equation. Methodical problems, such as an appropriate method of dispersing the sample and the selection of LDA calculation theory, also play a significant role in fine soils. This paper contains the results of analyses of Neogene clays from Poland, which are characterized by differentiation with regard to the content of clay fraction particles. In this article, the validity of using laser diffraction analysis (LDA) for the identification and characterization of clayey sediments with common genesis is assessed. The possibility of finding reliable pedotransfer functions to the convert LDA results to a hydrometric analysis is discussed.


2021 ◽  
Vol 1035 ◽  
pp. 273-277
Author(s):  
Yu Qing Zhang ◽  
Lu Yan Wang ◽  
Cao Bing Li ◽  
Shan Yu Liu

Jet grading technology is an efficient process in different industries. In this research, tungsten powder with different particle size distribution was used as a raw material to produce tungsten products via isostatic pressing as well as sintering. The mechanism of jet grading and the morphology and particle size distribution of different precursors were analyzed. The results showed that jet grading technology had remarkable effect on tungsten powder classification. The appropriate grading treatment was helpful to the formation of tungsten products with high performance. After jet grading and the following process like pressing and sintering, the tungsten products with better properties were manufactured which was used fischer particle size of 3.0~3.5μm as the raw material. The obtained products’ density was 18.77g/cm3 and its hardness was 372.15HV0.3.


Author(s):  
A. G. Agwu Nnanna ◽  
Chenguang Sheng ◽  
Kimberly Conrad ◽  
Greg Crowley

One of the industrial applications of ultrafiltration membrane system is water purification and wastewater treatment. Membranes act as physical barriers by eliminating particles such as pollen, yeast, bacteria, colloids, viruses, and macromolecules from feed water. The effectiveness of the membrane to separate particles is determined by its molecular weight cut-off and feed water characteristics. Typically, pre-filtration strainers are installed upstream of an ultrafiltration membrane system to separate large particles from the flow stream. The criteria for selection of the strainer pore size is unclear and is often determined by the feed water average particle size distribution. This paper is motivated by the hydraulic loading failure of a 125 μm strainer by average feed water particle size of 1.6 μm when the volumetric flow is at or greater than 40% of the rated design flow capacity. The objective of this paper are to: a) determine if the feed particle size distribution is a sufficient parameter for selection of pre-filtration strainer, b) evaluate the effect of feed flow velocity on strainer performance, and c) enhance strainer performance using vortex generator. In this experimental study, a Single Particle Optical Sensing, Accusizer, was used to analyze particle size distribution of five water samples collected at strainer feed, strainer filtrate, and strainer backwash. All samples were analyzed using a lower detection limit of 0.5 μm. In order to capture more counts of the larger particles present in the sample, a second analysis was done for each sample at a higher detection limit, 5.09 μm for feed sample, and 2.15 μm for the rest of the samples. Particle size data based on individual detection limits were statistically combined to generate comprehensive blended results of total number and total volume. The volume was determined based on assumption that each particle is spherically shaped. The Particle Size Distribution Measurement Accuracy is ±0.035 μm. Results showed that the feed particle size diameter and volume was insufficient to determine strainer size. Particle size distribution is needed at the feed, filtrate, and backwash to evaluate the strainer particle separation efficiency. It was observed that the total particle count in the filtrate (4.4 × 106) was an order of magnitude higher than the feed (3.2 × 105). Specifically, the total count for particles with diameter less than 7.22 μm were higher in the filtrate while larger particle size ≥ 7.22 μm were more in the feed stream. It appears that the large particles in the feed breaks down into smaller particles at the strainer interface and the small particles (≤ 7.22μm) passed through the pore into the filtrate. The particle breakdown, detachment of particles in the strainer pore into the filtrate, and particle to particle interactions are enhanced by increase in flow velocity hence increasing the hydrodynamic shear that acts on attached particles. A vortex generator inserted in to the strainer reduced pore clogging and pressure drop.


REAKTOR ◽  
2014 ◽  
Vol 15 (2) ◽  
pp. 132 ◽  
Author(s):  
Nurul - Widiastuti ◽  
Farhanah Thalib ◽  
Didik Prasetyoko ◽  
Hamzah Fansuri

Abstract PARTICLE SIZE AND CRYSTAL CONFORMATION OF SYNTHESIZED ZEOLITE-A WITH TETRAPROPYLAMMONIUM HYDROXIDE (TPAOH) ADDITION. The aims of this research is to study the effect of tetrapropylammonium hydroxide (TPAOH) concentration in the synthesis of zeolite A to its physical characteristics such as crystallinity, crystal conformation and average crystal size. The zeolite A was synthesized with composition 3.165 Na2O : 1.000 Al2O3 : 1.926 SiO2 : 128 H2O : x TPAOH where x was 0; 0.0385; 0.0577; 0.0770; 0.1540 and 4.1602. The zeolite was crystalized under hydrothermal condition in a stainless steel autoclave at 100°C for 5 hours. The resulting crystal was washed with distilled water until pH 8 and then dried in an oven at 80oC for 24 hours. FT-IR and XRD analysis results show that the synthesized zeolite A at x = 4.1602 has the lowest crystallinity. It is estimated due to the mass of TPAOH was four times higger than the mass of zeolite framework components (Si and Al). SEM and PSD (Particle Size Distribution) analysis results show that TPAOH concentration affected the crystal conformation and the average size of zeolite A particles. The formation of chained crystal conformation was caused by the electrostatic interactions between TPA+ and negatively charge of zeolite framework. In addition, the particel size of the synthesized zeolite A at x = 0.1540 was 2.024 µm which was smaller than the particel size of the synthesized zeolite A without TPAOH, which was 3.534 µm. Keywords: average size of particles; crystal conformation; TPAOH; zeolite A Abstrak Penelitian ini bertujuan untuk mempelajari pengaruh konsentrasi TPAOH (Tetrapropilamonium hidroksida) dalam sintesis zeolit A terhadap sifat fisikanya yang meliputi kekristalan, konformasi kristal dan ukuran rata-rata kristal yang terbentuk. Pada penelitian   ini   zeolit A   disintesis    dengan komposisi 3,165 Na2O : 1 Al2O3 : 1,926 SiO2 :128 H2O: x TPAOH. Konsentrasi TPAOH divariasikan dengan nilai x adalah 0; 0,0385; 0,0577; 0,0770; 0,1540 dan 4,1602. Metode hidrotermal digunakan dalam penelitian ini dengan kondisi suhu  hidrotermal 100°C dan waktu kristalisasi selama 5 jam dengan pH pencucian 8. Hasil karakterisasi menggunakan FT-IR (Fourier Transform – Infrared Spectroscopy) dan XRD (X-Ray Diffraction)  menunjukkan bahwa zeolit A yang disintesis dengan x = 4,1602 memiliki kekristalan terendah. Hal ini diperkirakan terjadi karena masa TPAOH yang digunakan empat kali lebih besar daripada masa penyusun zeolit (Si dan Al). Berdasarkan hasil karakterisasi menggunakan SEM (Scanning Electron Microscopy) dan PSD (Particle Size Distribution), dapat diketahui bahwa TPAOH berpengaruh terhadap konformasi kristal dan rata-rata ukuran kristalnya.  Terbentuknya konformasi kristal seperti rantai disebabkan oleh adanya interaksi elektrostatik antara muatan positif pada TPA+ dan muatan negatif dari kerangka zeolit. Zeolit A yang disintesis dengan x = 0,1540 memiliki ukuran partikel rata-rata 2,024 µm yang lebih kecil dari daripada zeolit A tanpa TPAOH yaitu sebesar 3,534 µm. Kata kunci : ukuran partakel rata-rata; konformasi kristal; TPAOH; zeolite A 


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