Combination of Silica Gel and Surfactin Promoting Methane Hydrate Formation

2020 ◽  
pp. 1-31
Author(s):  
Amit Arora ◽  
Swaranjit Singh cameotra ◽  
Chandrajit Balomajumder ◽  
Rajnish Kumar ◽  
Anil Kumar Singh ◽  
...  

Abstract Recently gas hydrates based technologies have been exploited for few novel applications such as Storage and transpiration of natural gas, gas mixtures separation, CO2 capture ,seawater desalination etc. Most of these applications are currently facing a challenge of low rate of gas hydrate formation. Chemical additives like surfactants can play a role of a good kinetic promoter for gas hydrate formation. The present study reports application of biosurfactant for enhancing gas hydrate formation. Biosurfactant was produced by Bacillus subtilis strain A21. These types of microbes show their presence in the real gas hydrate sites also. The surfactin was characterized using many sophisticated technique conforming the formation of surfactin. It was used in presence of fixed bed media of silica gel and it was observed that surfactin in the presence of silica gel has increased the consumption of moles of methane as well as reduced the induction time also as well as the conversion was also increase up to 27.9 % for 390 minutes for 1000 ppm surfactin hence indicating it to be a clean and novel promoter of methane hydrate formation in combination with silica gel which can replace its synthetic counter parts which are having environmental concerns.

RSC Advances ◽  
2017 ◽  
Vol 7 (62) ◽  
pp. 39109-39117 ◽  
Author(s):  
Florian Rauh ◽  
Jens Pfeiffer ◽  
Boris Mizaikoff

Studies on the role of surfactants at a molecular level during gas hydrate formation via in situ fiberoptic infrared spectroscopy.


2019 ◽  
Vol 7 (38) ◽  
pp. 21634-21661 ◽  
Author(s):  
Yan He ◽  
Meng-Ting Sun ◽  
Chen Chen ◽  
Guo-Dong Zhang ◽  
Kun Chao ◽  
...  

Surfactant-promoted methane hydrate formation during the past 2–3 decades has been reviewed, aiming toward achieving a comprehensive evaluation on the current research status and effective guidance on the research prospects.


Fuel ◽  
2016 ◽  
Vol 185 ◽  
pp. 517-523 ◽  
Author(s):  
Ngoc N. Nguyen ◽  
Anh V. Nguyen ◽  
Khoi T. Nguyen ◽  
Llew Rintoul ◽  
Liem X. Dang

2015 ◽  
Vol 55 (29) ◽  
pp. 7973-7980 ◽  
Author(s):  
Dong-Liang Zhong ◽  
Zheng Li ◽  
Yi-Yu Lu ◽  
Jia-Le Wang ◽  
Jin Yan ◽  
...  

Author(s):  
Remi-Erempagamo T. Meindinyo ◽  
Runar Bøe ◽  
Thor Martin Svartås ◽  
Silje Bru

Gas hydrates are the foremost flow assurance issue in deep water operations. Since heat transfer is a limiting factor in gas hydrate formation processes, a better understanding of its relation to hydrate formation is important. This work presents findings from experimental study of the effect of gas hydrate content on heat transfer through a cylindrical wall. The experiments were carried out at temperature conditions similar to those encountered in flowlines in deep water conditions. Experiments were conducted on methane hydrate, Tetrahydrofuran hydrate, and ethylene oxide hydrate respectively in stirred cylindrical high pressure autoclave cells. Methane hydrate was formed at 90 bars (pressure), and 8°C, followed by a cooling/heating cycle in the range of 8°C → 4°C → 8°C. Tetrahydrofuran (THF) and ethylene oxide (EO) hydrates were formed at atmospheric pressure and system temperature of 1°C in contact with atmospheric air. This was followed by a heating/cooling cycle within the range of 1°C → 4°C → 1°C, since the hydrate equilibrium temperature of THF hydrate is 4.98°C in contact with air at atmospheric pressure. The experimental conditions of the latter hydrate formers were more controlled, given that both THF and EO are miscible with water. We found in all cases a general trend of decreasing heat transfer coefficient of the cell content with increasing concentration of hydrate in the cell, indicating that hydrate formation creates a heat transfer barrier. The hydrate equilibrium temperature seemed to change with a change in the stoichiometric concentration of THF and EO. While the methane hydrate cooling/heating cycles were performed under quiescent conditions, the effect of stirring was investigated for the latter hydrate formers.


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