Characterization of Groundwater Zones and Salinity Assessment in Aquifers of the Campo District, South Cameroon Using the GIS, AHP and PCA Approach.

In the Campo region, groundwater is critical for human consumption and social activity. Groundwater potential is influenced by a region's geological, geophysical, and hydrogeological factors. The major goals of this research are to determine which regions are ideal for productive groundwater drilling and to assess the source of salinity in the study area's coastal aquifers. The groundwater potential map was created using Geographic Information Systems (GIS) and the Hierarchical Analysis Process (AHP). The process of groundwater mineralization was studied using principal component analysis (PCA). Six variables were taken into account, and weights were assigned to them based on their impact on groundwater recharge. In a GIS environment, spatial integration and a combination of theme layers were conducted. Campo's groundwater potential map was divided into four zones: low 14.4% (389.6 km²), moderate 53.3% (1484.5 km²), high 28.3% (783.3 km²), and extremely high 4.1% (110.9 km²). The results of the PCA reveal a mechanism of water-rock interaction, as a result of geological alteration and a salinization process caused by the intrusion of seawater and human activity The source of salinity in groundwater is manmade (agricultural and residential activities) rather than seawater intrusion. Seawater infiltration is not greatly aided by the low lineament density found near the beaches.

Application of Geoelectrical Survey and Time-Lapse Resistivity with Groundwater Data in Delineating a Groundwater Potential Map: A Case Study from Phuket Island, Thailand

Phuket is well-known around the world as a popular tourist destination. Tourism-related population growth depends more on groundwater as the only available source of potable water in Phuket. The proper precautions must be taken to reduce the risk of spending large sums of money in sinking abortive boreholes, and a groundwater potential map would enhance the success rate of future groundwater exploration and exploitation in the study area. Geoelectrical surveys were carried out in this study to collect electrical properties of the subsurface, and the Dar-Zarrouk parameters (DZP) were calculated using the geoelectrical data. The first thematic groundwater potential map was constructed using the interpretation of DZP, while the second thematic groundwater potential map was created using the basis maps of the depth-of-basement and aquifer thickness parameters. Finally, two thematic maps based on geographic information system (GIS) environments were overlaid on a groundwater potential map of Phuket. However, in order to provide a reliable assessment of groundwater potential, time-lapse electrical resistivity imaging was used to confirm the area of the high-potential zone indicated on the map. The map created by this study is aimed to act as a reference for future groundwater exploration and exploitation, preventing water supplies from becoming unsustainable through botched borehole drilling for groundwater production.

Neurophysiological Characterization of Posteromedial Hypothalamus in Anaesthetized Patients

Deep brain stimulation (DBS) requires a precise localization, which is especially difficult at the hypothalamus, because it is usually performed in anesthetized patients. We aimed to characterize the neurophysiological properties posteromedial hypothalamus (PMH), identified by the best neurophysiological response to electrical stimulation. We obtained microelectrode recordings from four patients with intractable aggressivity operated under general anesthesia. We pooled data from 1.5 mm at PMH, 1.5 mm upper (uPMH) and 1.5 mm lower (lPMH). We analyzed 178 units, characterized by the mean action potential (mAP). Only 11% were negative. We identified the next types of units: P1N1 (30.9%), N1P1N2 (29.8%), P1P2N1 (16.3%), N1P1 and N1N2P1 (6.2%) and P1N1P2 (5.0%). Besides, atypical action potentials (amAP) were recorded in 11.8%. PMH was highly different in cell composition from uPMH and lPMH, exhibiting also a higher percentage of amAP. Different kinds of cells shared similar features for the three hypothalamic regions. Although features for discharge pattern did not show region specificity, the probability mass function of inter-spike interval were different for all the three regions. Comparison of the same kind of mAP with thalamic neurons previously published demonstrate that most of cells are different for derivatives, amplitude and/or duration of repolarization and depolarization phases and also for the first phase, demonstrating a highly specificity for both brain centers. Therefore, the different properties described for PMH can be used to positively refine targeting, even under general anesthesia. Besides, we describe by first time the presence of atypical extracellular action potentials.

Semiempirical Quantum Chemical and Ab Intio Study of Co(Ii), Ni(Ii),Cu(Ii) and Zn(Ii) Complexes with the Azo Dye Derived from 4-Amino Antipyrine and 2,4-Dihydroxy Acetopheone

Semi-empirical quantum chemical calculation was made to study the nucleophilicity of the ligand and to study the mode of bonding between the ligand and the metal ions. The natural atomic charge at different atomic sites of the ligand has been calculated along with the electrostatic potential map to predict the reactive sites for electrophilic and nucleophilic attack. The theoretical spectral data such as IR, NMR and electronic have been calculated and compared with the experimentally generated data.

Roboustness of Hydrogen Bonding in the Construction of Supramolecular Architechures in Protonated Perchlorate Salts

Five new multicomponent salts of perchloric acid with a series of substituted anilines and N-heterocyclic amines namely Diphenylaminium perchlorate (DPAPC) (1), 2, 5-dichloroanilinium perchlorate (25DAP) hydrate (2), 4-Methylanilinium perchlorate (4MAPC) (3), 4-diamino-6-methyl-1, 3, 5-triazin-1-ium hydrogen perchlorate (24DAMTHP) (4) and 8-hydroxyquinolinium hydrogen perchlorate (8HQP) (5) were prepared and structurally characterized. The entire complexes were subjected to FTIR and elemental analysis. A vast family of intermolecular contacts N-H…O, O-H…O, N-H…N and C-H…O were observed, which are key ingredient in the generation of privileged supramolecular self-assemblies appeared as one-dimensional chain, two-dimensional ladder and helix. Cambridge structural Database (CSD) analysis of 52 hits revealed the perchloric acid display higher propensity of ladder architectures. Molecular stability of the complexes were studied by quantum chemical calculations using DFT/B3LYP method with 6-31G(d,p) basis set. Further their relative charge distributions were identified using molecular electrostatic potential map. The use of Hirshfeld surfaces in combination with fingerprint plots was visualized in order to study the closer contacts within the molecule. The relative contribution of whole percentage of interactions associated is highlighted.

GIS-Based Groundwater Potential Assessment in Varied Topographic Areas of Mianyang City, Southwestern China, Using AHP

Mianyang City is located in the varied topographic areas of Sichuan Province in southwestern China and is characterized by a complex geological background. This area is prone to disasters and its varied topography is inconvenient for emergency water storage and supply. Groundwater is essential for alleviating the demand for water and post-disaster emergency water supply in this area. This study applied AHP to integrate remote sensing, geological and hydrological data into GIS for the assessment of groundwater potential, providing a plan for the rational exploitation of groundwater and post-disaster emergency water supply in the area. Nine factors, including the spring calibration related to groundwater, were integrated by AHP after multicollinear checks. As a result, the geology-controlled groundwater potential map was classified into five levels with equal intervals. All the results were validated using borehole data, indicating the following: the areas with yield rates of , 1–20 , and 20–400 accounted for 2.66%, 36.1%, and 39.62%, respectively, whereas the areas with yield rates of 400–4000 and accounted for only 20.88% and 0.75% of the overall area. The flexibility of this quick and efficient method enables its application in other regions with a similar geological background.

Potential Map of Community Welfare Based on Strong and Flexible Statistics Modelling in the Framework of Poverty

Purpose: This study aims to map the level of family welfare in the Wajak District. Methods: This study uses a survey method with a mixed-method approach. The data used in this study is secondary data regarding HDI (Human Development Index), ISSI (Infrastructure Service Satisfaction Index), and EQI (Environmental Quality Index). The population in this study was all villages in Wajak District, which amounted to 13 villages. Then with the sampling technique using simple random sampling, the village selected as the sample for analysis is Bringin Village. The data analysis used in this study includes biplot, cluster, and IPA analysis. Findings: The result of this study is that the level of welfare of the community in Bringin Village is said to be quite prosperous, this can be seen from the results of mapping the variables of religiosity, entrepreneurship, and service quality showing that cluster 1 is quite prosperous with 39 members, while in cluster 2, which is less prosperous, there are 11 members. Originality: The outputs obtained for the Wajak Rural community include a mapping related to the level of family welfare and its distribution in various areas in the Wajak District area.

Identification of groundwater recharge potential zones in a study region of South Kerala

Groundwater is considered as a precious natural resource which serves as the main source of agriculture and domestic purposes. Kerala state is blessed with around 3000mm rainfall annually because of two prominent monsoon. But the available water is insufficient to meet the demand of people. Increase in population and water demand cause threat to overall water balance. Ground water resource must be managed well to overcome these problems. Ground water recharging is a major requirement for sustainable utilization of water resources. It also becomes highly relevant to assess the water recharge zones and to preserve water quality. This study proposes identification of suitable water recharge sites in Karamana river basin, Thiruvananthapuram, Kerala. Karamana river supplies majority of drinking water in Thiruvananthapuram district. Since its quality is deteriorating day by day, appropriate locations for recharging groundwater is identified using GIS technique. Various thematic maps like soil, slope, drainage, geomorphology and land utilization that affect the groundwater recharge is integrated and weighted overlay analysis is adopted to find the groundwater recharge potential map. Weights are assigned using Analytical Hierarchy Process (AHP) by constructing a pairwise comparison matrix. The result depicts the groundwater recharge potential zones which is divided into very high, high, moderate, low and very low potential areas.