Laminar Flame Speed Measurements of H2/CO/CO2 Mixtures Up to 15 atm and 600 K Preheat Temperature

2008 ◽  
Author(s):  
J. Natarajan ◽  
Y. Kochar ◽  
T. Lieuwen ◽  
J. Seitzman
Keyword(s):  
Temperature Dependence ◽  
Atmospheric Pressure ◽  
Radiation Effects ◽  
Laminar Flame ◽  
Elevated Pressure ◽  
Flame Speed ◽  
Preheat Temperature ◽  
Numerical Predictions ◽  
Kinetic Mechanisms ◽  
Fuel Mixtures

Laminar flame speeds of lean H2/CO/CO2 (syngas) fuel mixtures have been measured for a range of H2 levels (20–90% of the fuel) at pressures and reactant preheat temperatures relevant to gas turbine combustors (up to 15 atm and 600 K). A conical flame stabilized on a contoured nozzle is used for the flame speed measurement, which is based on the reaction zone area calculated from chemiluminescence imaging of the flame. A O2:He mixture (1:9 by volume) is used as the oxidizer, rather than standard air, in order to suppress the hydrodynamic and thermo-diffusive instabilities that become prominent at elevated pressure conditions for lean H2/CO fuel mixtures. All the measurements are compared with numerical predictions based on two leading kinetic mechanisms: the H2/CO mechanism of Davis et al. and the C1 mechanism of Li et al. The results generally agree with the findings of an earlier study at atmospheric pressure: 1) for low H2 content (<40%) fuels, the model predictions are in good agreement with measurements at both 300 K and 600 K preheat temperature; but 2) the models tend to over predict the temperature dependence of the flame speed for medium (∼40–60%) and high (> 60%) H2 content fuels, especially at very lean conditions. The elevated pressure (∼15 atm) results, however, reveal that the effect is less pronounced than at atmospheric pressure. The exaggerated temperature dependence of the current models may be due to errors in the temperature dependence used for so-called “low temperature” reactions that become more important as the preheat temperature is increased. The radiation effects associated with CO2 addition to the fuel (up to 40%) is found to be less important for medium and high H2 content syngas fuels at elevated pressure and preheat temperature.

Laminar Flame Speeds and Strain Sensitivities of Mixtures of H2 With CO, CO2and N2 at Elevated Temperatures

2007 ◽  
Author(s):  
J. Natarajan ◽  
T. Lieuwen ◽  
J. Seitzman
Keyword(s):  
Radiation Effects ◽  
Equivalence Ratio ◽  
Elevated Temperatures ◽  
Laminar Flame ◽  
Flame Speed ◽  
Bunsen Flame ◽  
Clear Trend ◽  
Numerical Predictions ◽  
Fuel Mixtures ◽  
Lean Conditions

Laminar flame speed and strain sensitivities have been measured for mixtures of H2/CO/CO2/N2/O2 with a wall stagnation flame technique at high preheat temperature (700 K) and lean conditions. The measurements are compared with numerical predictions based on two reaction mechanisms: GRI Mech 3.0 and a H2/CO mechanism (Davis et al.). For H2:CO 50:50 fuel mixtures, both models tend to over predict the temperature dependence of the flame speed especially at very lean conditions, which confirms the trend found in an earlier study employing a Bunsen flame technique. The predicted strain sensitivities are in good agreement with the measurements. For 50:50 H2:CO fuel mixtures diluted with 40% CO2, the amount of over prediction by the models is about the same as in the undiluted case, which suggests that radiation effects associated with CO2 addition are not important for this mixture at highly preheated lean condition. For low H2 content (5 to 20%) H2/CO fuel mixtures at 5 atm and fuel lean condition, the predicted unstrained flame speeds are in excellent agreement with the measurements, but the models fail to predicted the strain sensitivity as the amount of H2 increases to 20%. Results are also presented for pure H2 with N2 diluted air (O2:N2 1:9) over a range of equivalence ratios. At lean conditions, the models over predict the measured flame speed by as much as 30%, and the amount of over prediction decreases as the equivalence ratio increases to stoichiometric and rich condition. The measured strain sensitivities are three times higher than the model predictions at lean conditions. More importantly, the predicted strain sensitivities do not change with equivalence ratio for both models, while the measurements reveal a clear trend (decreasing and then increasing) as the fuel-air ratio changes from lean to rich.

Laminar Flame Speeds and Strain Sensitivities of Mixtures of H2∕O2∕N2 at Elevated Preheat Temperatures

2008 ◽  
Vol 130 (6) ◽  
Author(s):  
J. Natarajan ◽  
T. Lieuwen ◽  
J. Seitzman
Keyword(s):  
Kinetic Model ◽  
Temperature Dependence ◽  
Reasonable Agreement ◽  
Room Temperature ◽  
Laminar Flame ◽  
Flame Speed ◽  
Numerical Predictions ◽  
Hydrogen Flame ◽  
Measured Strain ◽  
Lean Conditions

Laminar flame speeds and strain sensitivities of mixtures of H2 and air or air highly diluted with N2 (O2:N2 1:9) have been measured for a range of equivalence ratios at high preheat conditions (∼700K) using a nozzle generated, 1D, laminar, wall stagnation flame. The measurements are compared with numerical predictions based on three detailed kinetic models (GRIMECH 3.0, a H2∕CO mechanism from Davis et al. (2004, “An Optimized Kinetic Model of H2∕CO Combustion,” Proc. Combust. Inst., 30, pp. 1283–1292) and a H2 mechanism from Li et al. (2004, “An Updated Comprehensive Kinetic Model of Hydrogen Combustion,” Int. J. Chem. Kinet., 36, pp. 566–575)). Sensitivity of the measurements to uncertainties in boundary conditions, e.g., wall temperature and nozzle velocity profile (plug or potential), is investigated through detailed numerical simulations and shown to be small. The flame speeds and strain sensitivities predicted by the models for preheated reactants are in reasonable agreement with the measurements for mixtures of H2 and standard air at very lean conditions. For H2 and N2 diluted air, however, all three mechanisms significantly overpredict the measurements, and the overprediction increases for leaner mixtures. In contrast, the models underpredict flame speeds for room temperature mixtures of H2 with both standard and N2 diluted air, based on comparisons with measurements in literature. Thus, we find that the temperature dependence of the hydrogen flame speed as predicted by all the models is greater than the actual temperature dependence (for both standard and diluted air). Finally, the models are found to underpredict the measured strain sensitivity of the flame speed for H2 burning in N2 diluted air, especially away from stoichiometric conditions.

Laminar Flame Speeds of Synthetic Gas Fuel Mixtures

2005 ◽  
Author(s):  
J. Natarajan ◽  
S. Nandula ◽  
T. Lieuwen ◽  
J. Seitzman
Keyword(s):  
Temperature Dependence ◽  
Reaction Mechanisms ◽  
Laminar Flame ◽  
Measured Temperature ◽  
Preheat Temperature ◽  
Significant Difference ◽  
Synthetic Gas ◽  
Co2 Levels ◽  
Gas Fuel ◽  
Fuel Mixtures

Laminar flame speeds of H2/CO/CO2 mixtures have been measured over a range of fuel compositions, lean equivalence ratios, and reactant preheat temperature (up to 700 K). The measurements are compared to numerical flame speed predictions based on two reaction mechanisms: GRI Mech 3.0 and a H2/CO mechanism. For undiluted and nonpreheated mixtures, the current results agree with previous data and the numerical calculations over most of the range tested. The measured flame speeds increase as the H2 content of the fuel rises and for higher equivalence ratios. The most significant difference between the measurements and models is for high CO content fuel with the H2/CO mechanism, and the high H2 content fuel at the leanest conditions with the GRI mechanism. For CO2 diluted fuels, measured flame speeds decrease as predicted. However, agreement between the measurements and predictions worsens with increasing CO2 dilution. Deviations as large as 40% are observed at lean equivalence ratios and 20% CO2 levels. For reactant preheat temperatures below ∼400K, the measured flame speeds generally match the calculated flame speeds within 10%. At higher preheat temperatures, however, the discrepancy between the measurements and the calculations increases, reaching levels of ∼30% at 700 K. The measured temperature dependence is closer to the predictions from GRI Mech 3.0 than from the H2/CO mechanism.

Evaluation of Kinetic Mechanisms for Direct Fired Supercritical Oxy-Combustion of Natural Gas

2016 ◽  
Author(s):  
Shane Coogan ◽  
Xiang Gao ◽  
Aaron McClung ◽  
Wenting Sun
Keyword(s):  
Carbon Dioxide ◽  
Natural Gas ◽  
San Diego ◽  
Laminar Flame ◽  
Flame Speed ◽  
Laminar Flame Speed ◽  
Validation Data ◽  
Data Set ◽  
Reduced Mechanism ◽  
Kinetic Mechanisms

Existing kinetic mechanisms for natural gas combustion are not validated under supercritical oxy-fuel conditions because of the lack of experimental validation data. Our studies show that different mechanisms have different predictions under supercritical oxy-fuel conditions. Therefore, preliminary designers may experience difficulties when selecting a mechanism for a numerical model. This paper evaluates the performance of existing chemical kinetic mechanisms and produces a reduced mechanism for preliminary designers based on the results of the evaluation. Specifically, the mechanisms considered were GRI-Mech 3.0, USC-II, San Diego 204-10-04, NUIG-I, and NUIG-III. The set of mechanisms was modeled in Cantera and compared against the literature data closest to the application range. The high pressure data set included autoignition delay time in nitrogen and argon diluents up to 85 atm and laminar flame speed in helium diluent up to 60 atm. The high carbon dioxide data set included laminar flame speed with 70% carbon dioxide diluent and the carbon monoxide species profile in an isothermal reactor with up to 95% carbon dioxide diluent. All mechanisms performed adequately against at least one dataset. Among the evaluated mechanisms, USC-II has the best overall performance and is preferred over the other mechanisms for use in the preliminary design of supercritical oxy-combustors. This is a significant distinction; USC-II predicts slower kinetics than GRI-Mech 3.0 and San Diego 2014 at the combustor conditions expected in a recompression cycle. Finally, the global pathway selection method was used to reduce the USC-II model from 111 species, 784 reactions to a 27 species, 150 reactions mechanism. Performance of the reduced mechanism was verified against USC-II over the range relevant for high inlet temperature supercritical oxy-combustion.

scholarly journals Experimental and Numerical Investigation on the Laminar Flame Speed of CH4/O2 Mixtures Diluted With CO2 and H2O

2010 ◽  
Author(s):  
A. N. Mazas ◽  
D. A. Lacoste ◽  
T. Schuller
Keyword(s):  
Laminar Flame ◽  
Burning Velocity ◽  
Molar Fraction ◽  
Fuel Combustion ◽  
Flame Speed ◽  
Operating Conditions ◽  
Inlet Temperature ◽  
Laminar Flame Speed ◽  
Numerical Predictions ◽  
Linear Decrease

The effects of CO2 and H2O addition on premixed oxy-fuel combustion are investigated with experiments and numerical simulations on the laminar flame speed of CH4/O2/CO2/H2O(v) and CH4/O2/N2/H2O(v) mixtures, at atmospheric pressure and for a reactants inlet temperature Tu = 373 K. Experiments are conducted with steady laminar conical premixed flames over a range of operating conditions representative of oxy-fuel combustion with flue gas recirculation. The relative O2-to-CO2 and O2-to-N2 ratios, respectively defined as O2/(O2+CO2) (mol.) and O2/(O2+N2) (mol.), are varied from 0.21 to 1.0. The equivalence ratio of the mixtures ranges from 0.5 to 1.5, and the steam molar fraction in the reactive mixture is varied from 0 to 0.45. Laminar flame speeds are measured with the flame area method using a Schlieren apparatus. Experiments are completed by simulations with the PREMIX code using the detailed kinetic mechanism GRI-mech. 3.0. Numerical predictions are found in good agreement with experimental data for all cases explored. It is also shown that the laminar flame speed of CH4/O2/N2 mixtures diluted with steam H2O(v) features a quasi-linear decrease when increasing the diluent molar fraction, even at high dilution rates. Effects of N2 replacement by CO2 in wet reactive mixtures are then investigated. A similar quasi-linear decrease of the flame speed is observed for CH4/O2/CO2 H2O-diluted flames. For a similar flame speed in dry conditions, results show a larger reduction of the burning velocity for CH4/O2/N2/H2O mixtures than for CH4/O2/CO2/H2O mixtures, when the steam molar fraction is increased. Finally, it is observed that the laminar flame speed of weakly (CO2, H2O)-diluted CH4/O2 mixtures is underestimated by the GRI-mech 3.0 predictions.

scholarly journals Selected combustion parameters of biogas at elevated pressure–temperature conditions

2012 ◽  
Vol 148 (1) ◽  
pp. 40-47
Author(s):  
Stanisław SZWAJA ◽  
Wojciech TUTAK ◽  
Karol GRAB-ROGALIŃSKI ◽  
Arkadiusz JAMROZIK ◽  
Arkadiusz KOCISZEWSKI
Keyword(s):  
Carbon Dioxide ◽  
Ignition Delay ◽  
Combustion Temperature ◽  
Laminar Flame ◽  
Engine Performance ◽  
Elevated Pressure ◽  
Flame Speed ◽  
Methane Content ◽  
Laminar Flame Speed ◽  
Adiabatic Combustion Temperature

Results from tests conducted in several RTD centers lead to conclusion that biogas as a potential fuel for the internal combustion (IC) spark ignited (SI) engine features with its satisfactory combustion predisposition causing smooth engine run without accidental misfiring or knock events. This good predisposition is obtained due to carbon dioxide (CO2) content in the biogas. On the other hand, carbon dioxide as incombustible gas contribute to decrease in the brake power of the biogas fueled engine. To analyze mutual CO2 and CH4 content on biogas burning the combustion parameters as follows: adiabatic combustion temperature, laminar flame speed and ignition delay of biogas with various methane content were determined and presented in the paper. Additionally, these parameters for pure methane were also included in order to make comparison between each other. As computed, ignition delay, which has is strongly correlated with knock resistance, can change several times with temperature increase, but does not change remarkably with increase in methane content. Adiabatic combustion temperature does not also ought to influence on engine performance or increase in engine cooling and exhaust losses due to its insignificant changes. The largest change was observed in laminar flame speed, that can influence on development of the first premixed combustion phase.

Flame Speed and Vapor Pressure of Biojet Fuel Blends

2013 ◽  
Author(s):  
Jeffrey D. Munzar ◽  
Bradley M. Denman ◽  
Rodrigo Jiménez ◽  
Ahmed Zia ◽  
Jeffrey M. Bergthorson
Keyword(s):  
Vapor Pressure ◽  
Alternative Fuels ◽  
Laminar Flame ◽  
Flame Speed ◽  
Aviation Fuel ◽  
Laminar Flame Speed ◽  
Camelina Oil ◽  
Combustion Properties ◽  
Initial Comparison ◽  
Fuel Mixtures

An understanding of the fundamental combustion properties of alternative fuels is essential for their adoption as replacements for non-renewable sources. In this study, three different biojet fuel mixtures are directly compared to conventional Jet A-1 on the basis of laminar flame speed and vapor pressure. The biofuel is derived from camelina oil and hydrotreated to ensure consistent elemental composition with conventional aviation fuel, yielding a bioderived synthetic paraffinic kerosene (Bio-SPK). Two considered blends are biofuel and Jet A-1 mixtures, while the third is a 90% Bio-SPK mixture with 10% aromatic additives. Premixed flame speed measurements are conducted at an unburned temperature of 400K and atmospheric pressure using a jet-wall stagnation flame apparatus. Since the laminar flame speed cannot be studied experimentally, a strained (or reference) flame speed is used as the basis for the initial comparison. Only by using an appropriate surrogate fuel were the reference flame speed measurements extrapolated to zero flame strain, accomplished using a direct comparison of simulations to experiments. This method has been previously shown to yield results consistent with non-linear extrapolations. Vapor pressure measurements of the biojet blends are also made from 25 to 200°C using an isoteniscope. Finally, the biojet blends are compared to the Jet A-1 benchmark on the basis of laminar flame speed at different equivalence ratios, as well as on the basis of vapor pressure over a wide temperature range, and the suitability of a binary laminar flame speed surrogate for these biojet fuels is discussed.

Investigation of Hydrogen Enriched Methane Flame in a Dry Low Emission Industrial Prototype Burner at Atmospheric Pressure Conditions

2017 ◽  
Author(s):  
Arman Ahamed Subash ◽  
Robert Collin ◽  
Marcus Aldén ◽  
Atanu Kundu ◽  
Jens Klingmann
Keyword(s):  
Atmospheric Pressure ◽  
Laminar Flame ◽  
Burning Velocity ◽  
Flame Stabilization ◽  
Oh Radicals ◽  
Burner Exit ◽  
Low Emission ◽  
Planar Laser ◽  
Pilot Fuel ◽  
Fuel Mixtures

Experiments were performed on a prototype 4th generation DLE (dry low emission) burner under atmospheric pressure conditions to investigate the effects of hydrogen (H2) enrichment on methane (CH4) flames. The burner assembly was designed to have three concentrically arranged premixed sections: an outer Main section, an intermediate section (Pilot) and a central pilot body termed the RPL (Rich-Pilot-Lean) section. The Planar laser-induced fluorescence (PLIF) of OH radicals together with flame chemiluminescence imaging were employed for studying the local flame characteristics so as to be able to investigate the turbulence-flame interactions and the location of the reaction zone at the burner exit. Flames were investigated for three different fuel mixtures having hydrogen (H2)/methane (CH4) in vol. % concentration of 0/100, 25/75 and 50/50. The results show that the characteristics of the flames are clearly affected by the addition of hydrogen and the effects are expected due to the faster reaction rate, higher diffusivity and higher laminar burning velocity of H2. Enriching the flame with H2 at a constant global phi (ϕ) is found to shorten the total extension of the flame due to the higher laminar flame speed. The OH signal distribution becomes thicker and more pronounced due to the higher production of OH radicals, and the flame stabilization zone that is produced after the burner throat, moves further downstream. At a constant global ϕ in altering the RPL and the Pilot ϕ, similar changes for both 0/100 and 25/75 (in vol. %) of the H2/CH4 fuel mixtures can be observed. At a rich RPL ϕ, the secondary RPL flame contributes to the main flame and to determining the flame stabilization position. The flame stabilization zone located after the burner throat moves further downstream with an increase in the RPL ϕ. When the PFR (Pilot fuel ratio) increases, the extension of the flame shortens and the flame stabilization zone moves upstream. Combustion emissions were also determined so as to observe the effects of the H2 enrichment on the NOX level.

scholarly journals Experimental Study on the Effect of Nano Additives γAl2O3 and Equivalence Ratio to Bunsen Flame Characteristic of Biodiesel from Nyamplung (Calophyllum Inophyllum)

2021 ◽  
Vol 4 (2) ◽  
pp. 51-61
Author(s):  
Setyo Pambudi ◽  
Nasrul Ilminnafik ◽  
Salahuddin Junus ◽  
Muh Nurkoyim Kustanto
Keyword(s):  
Atmospheric Pressure ◽  
Catalytic Effect ◽  
Laminar Flame ◽  
Flame Speed ◽  
Laminar Flame Speed ◽  
Flammability Limit ◽  
Bunsen Flame ◽  
Calophyllum Inophyllum ◽  
Equivalent Ratio ◽  
Nano Additives

Nano γAl2O3 has been one of the nanometal oxides that has improved the characteristics of biodiesel. The effect of γAl2O3 nanoparticles addition on premixed flame combustion is investigated with an experiment on the laminar flame speed of Calophyllum inophyllum methyl ester 30% and 70% petrodiesel mixtures, at atmospheric pressure and preheated temperature T = 473K. The γAl2O3 nanoparticles added to CIME30 biodiesel were 0ppm, 100ppm, 200ppm, and 300ppm. Experiments were carried out on a bunsen burner. The equivalent ratio of the mixture between ϕ = 0.67 to 1.17. Experiments revealed that the addition of nanoparticles to CIME30 biodiesel expands the flammability limit and increases the laminar flame speed. CIME30 without nanoparticles, flame stable between ϕ = 0,76 -1,17. CIME30 with nanoparticles, flame stable between ϕ = 0,67 -1,17. Combustion of CIME30 required a lot of air. The highest laminar flame speed occurred at the equivalent ratio ϕ = 0.83. The highest laminar flame speed of CIME30 0, 100, 200, and 300 ppm were 30.77, 34.50, 35.90, 38.45 cm/s respectively. The higher the nano γAl2O3 concentration the higher the laminar flame speed. This occurs due to the catalytic effect of γAl2O3 on biodiesel and its mixtures.

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