Autoignition of Hydrogen / Natural Gas / Nitrogen Fuel Mixtures at Reheat Combustor Operating Conditions

2012 ◽  
Author(s):  
Julia Fleck ◽  
Peter Griebel ◽  
Manfred Aigner ◽  
Adam M. Steinberg
Keyword(s):  
Natural Gas ◽  
High Speed ◽  
Volume Fraction ◽  
Fluid Dynamic ◽  
Flame Stabilization ◽  
Operating Conditions ◽  
Mixing Zone ◽  
Fuel Injector ◽  
Jet Penetration ◽  
Penetration Depths

Previous autoignition studies at conditions relevant to reheat combustor operation have indicated that the presence of relatively small amounts of natural gas (NG) in H2/N2 fuel significantly changes the autoignition behavior. The present study further elucidates the influence of NG on autoignition, kernel propagation, and subsequent flame stabilization at conditions that are relevant for the practical operation of gas turbine reheat combustors (p = 15 bar, Tinlet > 1000 K, hot flue gas, appropriate residence times). The experimental investigation was carried out in a generic, optically accessible reheat combustor. Autoignition events in the mixing zone were recorded by a high-speed camera at frame rates of up to 30,000 fps. This paper describes the autoignition behavior as the H2 volume fraction is increased (decreasing NG) in a H2/NG/N2 fuel mixture for two different jet penetration depths. Additionally, the subsequent flame stabilization phenomena and the structure of the stabilized flame are discussed. The results reveal that autoignition kernels occurred even for the lowest H2 fuel fraction, but they did not initiate a stable flame in the mixing zone. Increasing the H2 volume fraction decreased the distance between the initial position of the autoignition kernels and the fuel injector, finally leading to flame stabilization. The occurrence of autoignition kernels at lower H2 volume fractions (H2/(H2+NG) < 85%) was not found to be significantly influenced by the fluid dynamic and mixing field differences related to the different jet penetration depths. In contrast, autoignition leading to flame stabilization was found to depend on jet penetration; flame stabilization occurred at lower H2 fractions for the higher jet penetration depth (H2/(H2+NG) ≈ 89 compared to H2/(H2+NG) ≈ 95 vol. %).

scholarly journals The Influence of Carrier Air Preheating on Autoignition of Inline-Injected Hydrogen–Nitrogen Mixtures in Vitiated Air of High Temperature

2017 ◽  
Vol 140 (3) ◽  
Author(s):  
Christoph A. Schmalhofer ◽  
Peter Griebel ◽  
Manfred Aigner
Keyword(s):  
Hydrogen Content ◽  
Gas Turbines ◽  
High Speed ◽  
Flame Stabilization ◽  
Operating Conditions ◽  
Promoting Effect ◽  
Experimental Conditions ◽  
Lean Premixed Combustion ◽  
Image Velocimetry ◽  
Fuel Mixtures

The use of highly reactive hydrogen-rich fuels in lean premixed combustion systems strongly affects the operability of stationary gas turbines (GT) resulting in higher autoignition and flashback risks. The present study investigates the autoignition behavior and ignition kernel evolution of hydrogen–nitrogen fuel mixtures in an inline co-flow injector configuration at relevant reheat combustor operating conditions. High-speed luminosity and particle image velocimetry (PIV) measurements in an optically accessible reheat combustor are employed. Autoignition and flame stabilization limits strongly depend on temperatures of vitiated air and carrier preheating. Higher hydrogen content significantly promotes the formation and development of different types of autoignition kernels: More autoignition kernels evolve with higher hydrogen content showing the promoting effect of equivalence ratio on local ignition events. Autoignition kernels develop downstream a certain distance from the injector, indicating the influence of ignition delay on kernel development. The development of autoignition kernels is linked to the shear layer development derived from global experimental conditions.

Ultra-Low Emission Hydrogen/Syngas Combustion With a 1.3 MW Injector Using a Micro-Mixing Lean-Premix System

2011 ◽  
Author(s):  
Brian Hollon ◽  
Erlendur Steinthorsson ◽  
Adel Mansour ◽  
Vincent McDonell ◽  
Howard Lee
Keyword(s):  
Carbon Dioxide ◽  
Natural Gas ◽  
Flame Temperature ◽  
Fuel Mixture ◽  
Full Scale ◽  
Operating Conditions ◽  
Nox Emissions ◽  
Fuel Injector ◽  
Nitrogen Dilution ◽  
Fuel Mixtures

This paper discusses the development and testing of a full-scale micro-mixing lean-premix injector for hydrogen and syngas fuels that demonstrated ultra-low emissions and stable operation without flashback for high-hydrogen fuels at representative full-scale operating conditions. The injector was fabricated using Macrolamination technology, which is a process by which injectors are manufactured from bonded layers. The injector utilizes sixteen micro-mixing cups for effective and rapid mixing of fuel and air in a compact package. The full scale injector is rated at 1.3 MWth when operating on natural gas at 12.4 bar (180 psi) combustor pressure. The injector operated without flash back on fuel mixtures ranging from 100% natural gas to 100% hydrogen and emissions were shown to be insensitive to operating pressure. Ultra-low NOx emissions of 3 ppm were achieved at a flame temperature of 1750 K (2690 °F) using a fuel mixture containing 50% hydrogen and 50% natural gas by volume with 40% nitrogen dilution added to the fuel stream. NOx emissions of 1.5 ppm were demonstrated at a flame temperature over 1680 K (2564 °F) using the same fuel mixture with only 10% nitrogen dilution, and NOx emissions of 3.5 ppm were demonstrated at a flame temperature of 1730 K (2650 °F) with only 10% carbon dioxide dilution. Finally, using 100% hydrogen with 30% carbon dioxide dilution, 3.6 ppm NOx emissions were demonstrated at a flame temperature over 1600 K (2420 °F). Superior operability was achieved with the injector operating at temperatures below 1470 K (2186 °F) on a fuel mixture containing 87% hydrogen and 13% natural gas. The tests validated the micro-mixing fuel injector technology and the injectors show great promise for use in future gas turbine engines operating on hydrogen, syngas or other fuel mixtures of various compositions.

Experimental Assessment of the Emissions Benefits of a Ceramic Gas Turbine Combustor

1996 ◽  
Author(s):  
K. O. Smith ◽  
A. Fahme
Keyword(s):  
Natural Gas ◽  
Gas Turbine ◽  
Flow Distribution ◽  
Operating Conditions ◽  
Nox Emissions ◽  
Fuel Injector ◽  
Gas Turbine Combustor ◽  
Experimental Assessment ◽  
Industrial Gas Turbine ◽  
Combustor Liner

Three subscale, cylindrical combustors were rig tested on natural gas at typical industrial gas turbine operating conditions. The intent of the testing was to determine the effect of combustor liner cooling on NOx and CO emissions. In order of decreasing liner cooling, a metal louvre-cooled combustor, a metal effusion-cooled combustor, and a backside-cooled ceramic (CFCC) combustor were evaluated. The three combustors were tested using the same lean-premixed fuel injector. Testing showed that reduced liner cooling produced lower CO emissions as reaction quenching near the liner wall was reduced. A reduction in CO emissions allows a reoptimization of the combustor air flow distribution to yield lower NOx emissions.

Lean-Burn Characteristics of a Heavy-Duty Diesel Engine Retrofitted to Natural Gas Spark Ignition

2018 ◽  
Author(s):  
Jinlong Liu ◽  
Cosmin E. Dumitrescu
Keyword(s):  
Natural Gas ◽  
Combustion Chamber ◽  
Spark Ignition ◽  
Operating Conditions ◽  
Combustion Stability ◽  
Fuel Injector ◽  
Heavy Duty ◽  
Lean Burn ◽  
Spark Timing ◽  
Heavy Duty Diesel

Increased utilization of natural-gas (NG) in the transportation sector can decrease the use of petroleum-based fuels and reduce greenhouse-gas emissions. Heavy-duty diesel engines retrofitted to NG spark ignition (SI) can achieve higher efficiencies and low NOx, CO, and HC emissions when operated under lean-burn conditions. To investigate the SI lean-burn combustion phenomena in a bowl-in-piston combustion chamber, a conventional heavy-duty direct-injection CI engine was converted to SI operation by replacing the fuel injector with a spark plug and by fumigating NG in the intake manifold. Steady-state engine experiments and numerical simulations were performed at several operating conditions that changed spark timing, engine speed, and mixture equivalence ratio. Results suggested a two-zone NG combustion inside the diesel-like combustion chamber. More frequent and significant late burn (including double-peak heat release rate) was observed for advanced spark timing. This was due to the chamber geometry affecting the local flame speed, which resulted in a faster and thicker flame in the bowl but a slower and thinner flame in the squish volume. Good combustion stability (COVIMEP < 3 %), moderate rate of pressure rise, and lack of knocking showed promise for heavy-duty CI engines converted to NG SI operation.

Lean-Burn Characteristics of a Heavy-Duty Diesel Engine Retrofitted to Natural-Gas Spark Ignition

2019 ◽  
Vol 141 (7) ◽  
Author(s):  
Jinlong Liu ◽  
Cosmin Emil Dumitrescu
Keyword(s):  
Natural Gas ◽  
Combustion Chamber ◽  
Spark Ignition ◽  
Operating Conditions ◽  
Combustion Stability ◽  
Fuel Injector ◽  
Heavy Duty ◽  
Lean Burn ◽  
Heavy Duty Diesel ◽  
Ci Engines

Increased utilization of natural gas (NG) in the transportation sector can decrease the use of petroleum-based fuels and reduced greenhouse gas emissions. Heavy-duty diesel engines retrofitted to NG spark ignition (SI) can achieve higher efficiencies and low NOX, CO, and hydrocarbon (HC) emissions when operated under lean-burn conditions. To investigate the SI lean-burn combustion phenomena in a bowl-in-piston combustion chamber, a conventional heavy-duty direct-injection CI engine was converted to SI operation by replacing the fuel injector with a spark plug and by fumigating NG in the intake manifold. Steady-state engine experiments and numerical simulations were performed at several operating conditions that changed spark timing (ST), engine speed, and mixture equivalence ratio. Results suggested a two-zone NG combustion inside the diesel-like combustion chamber. More frequent and significant late-burn (including double-peak heat release rate) was observed for advanced ST. This was due to the chamber geometry affecting the local flame speed, which resulted in a faster and thicker flame in the bowl but a slower and thinner flame in the squish volume. Good combustion stability (COVIMEP < 3%), moderate rate of pressure-rise, and lack of knocking showed promise for heavy-duty CI engines converted to NG SI operation.

On the influence of wall distance and geometry for high-pressure n-dodecane spray flames in a constant-volume chamber

2019 ◽  
Vol 21 (2) ◽  
pp. 406-417 ◽  
Author(s):  
Noud Maes ◽  
Mark Hooglugt ◽  
Nico Dam ◽  
Bart Somers ◽  
Gilles Hardy
Keyword(s):  
Heat Release ◽  
High Speed ◽  
Constant Volume ◽  
Operating Conditions ◽  
Orifice Diameter ◽  
Fuel Injector ◽  
Flat Wall ◽  
Wall Distance ◽  
Wall Interaction ◽  
End Wall

To isolate the effect of flame–wall interaction from representative operating conditions of an internal combustion engine, experiments were performed in a constant-volume pre-burn vessel. Three different wall geometries were studied at distances of 32.8, 38.2, and 46.2 mm from a single-hole 0.09-mm orifice diameter fuel injector. A flat wall provides a simplified case of flame–wall interaction. To mimic the division of a jet into two regions by the piston bowl rim in an engine, a two-dimensional confined wall is used. A third, axisymmetric confined wall geometry allows a second simplified comparison to numerical simulations in a Reynolds-averaged Navier–Stokes framework. As a limiting situation for a free jet, the distance from the injector orifice to the end wall of the chamber is 95 mm. Thermocouples installed in the end wall provided insights into local heat losses for reference cases without a wall insert. The test conditions were according to the Engine Combustion Network Spray A guidelines with an ambient temperature of 900 K and an ambient density of 22.8 kg/m3 with 15% O2. Flame structures were studied using high-speed OH* chemiluminescence with integrated single-shot OH PLIF and combined with pressure-based apparent heat release data to infer combustion progress and spray behavior. Soot was studied in a qualitative manner using high-speed natural luminosity imaging with integrated high-speed laser-induced incandescence. Overall, increased mixing upon interaction with the surfaces is observed to increase early heat release rate and to significantly reduce soot, with the nearest wall distance showing most effect. The flat wall gives rise to the most significant effects in all cases.

Measurement of Smoke Particle Size and Distribution Within a Gas Turbine Combustor

2005 ◽  
Vol 127 (2) ◽  
pp. 286-294 ◽  
Author(s):  
K. D. Brundish ◽  
M. N. Miller ◽  
C. W. Wilson ◽  
M. Jefferies ◽  
M. Hilton ◽  
...  
Keyword(s):  
Particle Size ◽  
Gas Turbine ◽  
Fluid Dynamic ◽  
Combustion Process ◽  
Analytical Techniques ◽  
Number Concentration ◽  
Operating Conditions ◽  
Fuel Injector ◽  
Gas Turbine Combustor ◽  
Smoke Particle

The objective of the work described in this paper was to identify a method of making measurements of the smoke particle size distribution within the sector of a gas turbine combustor, using a scanning mobility particle sizing (SMPS) analyzer. As well as gaining a better understanding of the combustion process, the principal reasons for gathering these data was so that they could be used as validation for computational fluid dynamic and chemical kinetic models. Smoke mass and gaseous emission measurements were also made simultaneously. A “water cooled,” gas sampling probe was utilized to perform the measurements at realistic operating conditions within a generic gas turbine combustor sector. Such measurements had not been previously performed and consequently initial work was undertaken to gain confidence in the experimental configuration. During this investigation, a limited amount of data were acquired from three axial planes within the combustor. The total number of test points measured were 45. Plots of the data are presented in two-dimensional contour format at specific axial locations in addition to axial plots to show trends from the primary zone to the exit of the combustor. Contour plots of smoke particle size show that regions of high smoke number concentration once formed in zones close to the fuel injector persist in a similar spatial location further downstream. Axial trends indicate that the average smoke particle size and number concentration diminishes as a function of distance from the fuel injector. From a technical perspective, the analytical techniques used proved to be robust. As expected, making measurements close to the fuel injector proved to be difficult. This was because the quantity of smoke in the region was greater than 1000mg/m3. It was found necessary to dilute the sample prior to the determination of the particle number concentration using SMPS. The issues associated with SMPS dilution are discussed.

Investigation of Flame Stabilization in a High-Pressure Multi-Jet Combustor by Laser Measurement Techniques

2014 ◽  
Author(s):  
Oliver Lammel ◽  
Tim Rödiger ◽  
Michael Stöhr ◽  
Holger Ax ◽  
Peter Kutne ◽  
...  
Keyword(s):  
High Pressure ◽  
Natural Gas ◽  
Combustion Chamber ◽  
Gas Turbine ◽  
Recirculation Zone ◽  
Flame Stabilization ◽  
Operating Conditions ◽  
Pollutant Emissions ◽  
Single Shot ◽  
Optical Access

In this contribution, comprehensive optical and laser based measurements in a generic multi-jet combustor at gas turbine relevant conditions are presented. The flame position and shape, flow field, temperatures and species concentrations of turbulent premixed natural gas and hydrogen flames were investigated in a high-pressure test rig with optical access. The needs of modern highly efficient gas turbine combustion systems, i.e., fuel flexibility, load flexibility with increased part load capability, and high turbine inlet temperatures, have to be addressed by novel or improved burner concepts. One promising design is the enhanced FLOX® burner, which can achieve low pollutant emissions in a very wide range of operating conditions. In principle, this kind of gas turbine combustor consists of several nozzles without swirl, which discharge axial high momentum jets through orifices arranged on a circle. The geometry provides a pronounced inner recirculation zone in the combustion chamber. Flame stabilization takes place in a shear layer around the jet flow, where fresh gas is mixed with hot exhaust gas. Flashback resistance is obtained through the absence of low velocity zones, which favors this concept for multi-fuel applications, e.g. fuels with medium to high hydrogen content. The understanding of flame stabilization mechanisms of jet flames for different fuels is the key to identify and control the main parameters in the design process of combustors based on an enhanced FLOX® burner concept. Both experimental analysis and numerical simulations can contribute and complement each other in this task. They need a detailed and relevant data base, with well-known boundary conditions. For this purpose, a high-pressure burner assembly was designed with a generic 3-nozzle combustor in a rectangular combustion chamber with optical access. The nozzles are linearly arranged in z direction to allow for jet-jet interaction of the middle jet. This line is off-centered in y direction to develop a distinct recirculation zone. This arrangement approximates a sector of a full FLOX® gas turbine burner. The experiments were conducted at a pressure of 8 bar with preheated and premixed natural gas/air and hydrogen/air flows and jet velocities of 120 m/s. For the visualization of the flame, OH* chemiluminescence imaging was performed. 1D laser Raman scattering was applied and evaluated on an average and single shot basis in order to simultaneously and quantitatively determine the major species concentrations, the mixture fraction and the temperature. Flow velocities were measured using particle image velocimetry at different section planes through the combustion chamber.

Influence of Injection Parameters and Operating Conditions on Ignition and Combustion in Dual-Fuel Engines

2017 ◽  
Author(s):  
Marcus Grochowina ◽  
Michael Schiffner ◽  
Simon Tartsch ◽  
Thomas Sattelmayer
Keyword(s):  
Natural Gas ◽  
High Speed ◽  
Measurement Techniques ◽  
Injection Pressure ◽  
Operating Conditions ◽  
Liquid Fuels ◽  
Dual Fuel ◽  
Injection Parameters ◽  
Pilot Fuel ◽  
Ignition And Combustion

Dual-Fuel (DF) engines offer great fuel flexibility since they can either run on gaseous or liquid fuels. In the case of Diesel pilot ignited DF-engines the main source of energy is provided by gaseous fuel, whereas the Diesel fuel acts only as an ignition source. Therefore, a proper autoignition of the pilot fuel is of utmost importance for combustion in DF-engines. However, autoignition of the pilot fuel suffers from lower compression temperatures of Miller or Atkinson valve timings. These valve timings are applied to increase efficiency and lower nitrogen oxide engine emissions. In order to improve the ignition, it is necessary to understand which parameters influence the ignition in DF-engines. For this purpose, experiments were conducted and the influence of parameters such as injection pressure, pilot fuel quantity, compression temperature and air-fuel equivalence ratio of the homogenous natural gas-air mixture were investigated. The experiments were performed on a periodically chargeable combustion cell using optical high-speed recordings and thermodynamic measurement techniques for pressure and temperature. The study reveals that the quality of the Diesel pilot ignition in terms of short ignition delay and a high number of ignited sprays significantly depends on the injection parameters and operating conditions. In most cases, the pilot fuel suffers from too high dilution due to its small quantity and long ignition delays. This results in a small number of ignited sprays and consequently leads to longer combustion durations. Furthermore, the experiments confirm that the natural gas of the background mixture influences the autoignition of the Diesel pilot oil.

Dynamics and Stability Limits of Syngas Combustion in a Swirl-Stabilized Combustor

2008 ◽  
Author(s):  
Raymond L. Speth ◽  
H. Murat Altay ◽  
Duane E. Hudgins ◽  
Ahmed F. Ghoniem
Keyword(s):  
High Speed ◽  
Equivalence Ratio ◽  
Fluid Dynamic ◽  
Flame Structure ◽  
Low Frequency ◽  
Operating Conditions ◽  
Video Data ◽  
Combustion Dynamics ◽  
Lean Blowout ◽  
Operating Modes

The combustion dynamics, stability bands and flame structure of syngas flames under different operating conditions are investigated in an atmospheric pressure swirl-stabilized combustor. Pressure measurements and high-speed video data are used to distinguish several operating modes. Increasing the equivalence ratio makes the flame more compact, and in general increases the overall sound pressure level. Very close to the lean blowout limit, a long stable flame anchored to the inner recirculation zone is observed. At higher equivalence ratios, a low frequency, low amplitude pulsing mode associated with the fluid dynamic instabilities of axial swirling flows is present. Further increasing the equivalence ratio produces unstable flames oscillating at frequencies coupled with the acoustic eigenmodes. Additionally, a second unstable mode, coupled with a lower eigen-mode of the system, is observed for flames with CO concentration higher than 50%. As the amount of hydrogen in the fuel is increased, the lean flammability limit is extended and transitions between operating regimes move to lower equivalence ratios.

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