scholarly journals Analysis of the Thermodynamic Potential of Supercritical Carbon Dioxide Cycles: A Systematic Approach

2017 ◽  
Author(s):  
Francesco Crespi ◽  
Giacomo Gavagnin ◽  
David Sánchez ◽  
Gonzalo S. Martínez
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Pressure Ratio ◽  
Operating Conditions ◽  
Inlet Temperature ◽  
Specific Work ◽  
Turbine Inlet Temperature ◽  
Fair Comparison ◽  
Modelling Assumptions ◽  
Supercritical Carbon

Since the renewed interest in supercritical carbon dioxide cycles, a large number of cycle layouts have been proposed in literature. These analyses, which are essentially theoretical, consider different operating conditions and modelling assumptions and thus the results are not comparable. There are also works that aim to provide a fair comparison between different cycles in order to assess which one is most efficient. These analyses are very interesting but, usually, combine thermodynamic and technical restrictions thus making it difficult to draw solid and general conclusions with regards to which the cycle of choice in the future should be . With this background, the present work provides a systematic thermodynamic analysis of twelve supercritical carbon dioxide cycles under similar working conditions, with and without technical restriction in terms of pressure and/or temperature. This yields very interesting conclusions regarding which the most interesting cycles are amongst those proposed in literature. Also, useful recommendations are extracted from the parametric analysis with respect to the directions that must be followed when searching for more efficient cycles. The analysis is based on efficiency and specific work diagrams with respect to pressure ratio and turbine inlet temperature in order to enhance their applicability to plant designs driven by fuel economy and/or footprint.

scholarly journals Analysis of the Thermodynamic Potential of Supercritical Carbon Dioxide Cycles: A Systematic Approach

2017 ◽  
Vol 140 (5) ◽  
Author(s):  
Francesco Crespi ◽  
Giacomo Gavagnin ◽  
David Sánchez ◽  
Gonzalo S. Martínez
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Systematic Approach ◽  
Pressure Ratio ◽  
Operating Conditions ◽  
Inlet Temperature ◽  
Specific Work ◽  
Turbine Inlet Temperature ◽  
Fair Comparison ◽  
Supercritical Carbon

After the renewed interest in supercritical carbon dioxide cycles, a large number of cycle layouts have been proposed in literature. These works, which are essentially theoretical, consider different operating conditions and modeling assumptions, and thus, the results are not comparable. There are also works that aim to provide a fair comparison between different cycles in order to assess which one is most efficient. These analyses are very interesting but, usually, they combine thermodynamic and technical restrictions, which make it difficult to draw solid and general conclusions with regard to which the cycle of choice in the future should be. With this background, the present work provides a systematic thermodynamic analysis of 12 supercritical carbon dioxide cycles under similar working conditions, with and without technical restriction in terms of pressure and/or temperature. This yields very interesting conclusions regarding the most interesting cycles in the literature. Also, useful recommendations are extracted from the parametric analysis with respect to the directions that must be followed when searching for more efficient cycles. The analysis is based on efficiency and specific work diagrams with respect to pressure ratio and turbine inlet temperature in order to enhance its applicability to plant designs driven by fuel economy and/or footprint.

Testing of a New Turbocompressor for Supercritical Carbon Dioxide Closed Brayton Cycles

2018 ◽  
Author(s):  
Jim Pasch ◽  
David Stapp
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Maximum Pressure ◽  
Inlet Temperature ◽  
Brayton Cycle ◽  
Turbine Inlet Temperature ◽  
Development Platform ◽  
Cycle System ◽  
Turbine Inlet ◽  
Supercritical Carbon

Sandia National Laboratories (SNL) has recently purchased a supercritical carbon dioxide (sCO2) turbocompressor that operates at 118,000 rpm, 750 °C turbine inlet temperature, and 42.9 MPa compressor discharge pressure, and is sized to pressurize the flow for a 1 MWe closed Brayton cycle. The turbocompressor is a line replaceable unit designed by Peregrine Turbine Technologies (PTT) located in Wiscasset, Maine, as part of their closed Brayton electric power genset rated at 1 MWe. Both this machine and a 6MW variant are intended for commercial applications burning a variety of aircombustible fuels including biomass materials. Sandia purchased this turbocompressor as the first phase of a program to construct a 1 MWe commercially viable sCO2 recompression closed Brayton-cycle system. During this phase, the development platform resident at the SNL Brayton Lab was reconfigured to support testing of the PTT turbocompressor to moderate, or idle, conditions. The testing infrastructure at the Brayton Lab limited maximum pressure to 13.8 MPa. This pressure limitation consequently limited turbocompressor operations to a speed of 52,000 rpm and a turbine inlet temperature of 150 °C. While these conditions are far removed from the machine design point, they are sufficient to demonstrate a range of important features. Numerous testing objectives were identified and researched, most notably: the development of a reliable cycle bootstrapping process for a motorless turbocompressor; the demonstration of consistent start, steady state, and shutdown performance and operations; performance demonstration of the numerous internal seals and bearings designs that are new to this environment; demonstration of controllability via turbine back pressuring and turbine inlet temperature; and turbomachinery performance map validation. This paper presents the design and development of the testing platform, the PTT turbocompressor and progress achieved on each of the objectives.

CFD Simulation of a Supercritical Carbon Dioxide Radial-Inflow Turbine, Comparing the Results of Using Real Gas Equation of Estate and Real Gas Property File

2016 ◽  
Vol 846 ◽  
pp. 85-90 ◽  
Author(s):  
Mostafa Odabaee ◽  
Emilie Sauret ◽  
Kamel Hooman
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Cfd Simulation ◽  
Pressure Ratio ◽  
Computational Cost ◽  
Real Gas ◽  
Table Method ◽  
Radial Inflow Turbine ◽  
Solar Resource ◽  
Supercritical Carbon

The present study explores CFD analysis of a supercritical carbon dioxide (SCO2) radial-inflow turbine generating 100kW from a concentrated solar resource of 560oC with a pressure ratio of 2.2. Two methods of real gas property estimations including real gas equation of estate and real gas property (RGP) file - generating a required table from NIST REFPROP - were used. Comparing the numerical results and time consumption of both methods, it was shown that equation of states could insert a significant error in thermodynamic property prediction. Implementing the RGP table method indicated a very good agreement with NIST REFPROP while it had slightly more computational cost compared to the RGP table method.

Extraction and Identification of Vitamin E from Pithecellobium Jiringan Seeds Using Supercritical Carbon Dioxide

2015 ◽  
Vol 74 (7) ◽  
Author(s):  
Mohd Azizi Che Yunus ◽  
Salman Zhari ◽  
Saharudin Haron ◽  
Nur Husnina Arsad ◽  
Zuhaili Idham ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Vitamin E ◽  
Supercritical Carbon Dioxide ◽  
Potential Method ◽  
Operating Conditions ◽  
Oil Yield ◽  
Flight Mass Spectrometry ◽  
Carbon Dioxide Extraction ◽  
Natural Herb ◽  
Supercritical Carbon

Pithecellobium Jiringan (P. Jiringan) is traditionally known as natural herb consists of several medicinal compounds (vitamin E). Supercritical carbon dioxide extraction (SC-CO2) has been proven as potential method to extract interest compound from herbs. By altering pressure and temperature, the specific compound can be extracted. In this study, the SC-CO2 operating conditions are pressure (20.68 MPa to 55.16 MPa) and temperature (40°C to 80°C) in one hour extraction regime was used to extract vitamin E from P. jiringan. The quantification of vitamin E was analysed with Gas Chromatography Time of Flight Mass Spectrometry (GC-TOF-MS). The responses are overall oil yield and vitamin E yield. The overall oil yield was obtained at the highest condition of 55.16 MPa and 80°C with asymptotic yield of 8.06%. In contrast, the highest amount of vitamin E obtained is 0.0458mg/g sample (80.14 ppm) at the lowest extraction condition of 20.68 MPa and 40ᵒC.

Microcellular Polymeric Foams (MPFs) Generated Continuously in Supercritical Carbon Dioxide

2000 ◽  
Vol 629 ◽  
Author(s):  
Srinivas Siripurapu ◽  
Yvon J. Gay ◽  
Joseph R. Royer ◽  
Joseph M. DeSimone ◽  
Saad A. Khan ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Vinylidene Fluoride ◽  
Amorphous Polymer ◽  
Extrusion Process ◽  
Operating Conditions ◽  
Polymeric Foams ◽  
Poly Vinylidene Fluoride ◽  
Cell Densities ◽  
Supercritical Carbon

ABSTRACTMicrocellular polymeric foams (MPFs) hold tremendous promise for engineering applications as substitutes to their solid analogs in light of reduced manufacturing/materials costs and improved properties. We present a two-part study addressing the generation of such materials in the presence of supercritical carbon dioxide (scCO2). The first part describes the production of polystyrene MPFs in a continuous extrusion process, as well as the effect of operating conditions such as temperature and CO2 concentration on foam morphology. The second part discusses microcellular foaming of poly (vinylidene fluoride) (PVDF), a semicrystalline polymer, via blending with the amorphous polymer poly (methyl methacrylate) PMMA. Foams of pure PVDF possess ill-defined morphologies, whereas those of PVDF-PMMA blends show an improvement with cell sizes on the order of 10 mm or less and cell densities in excess of 109 cells/cm3.

The Role of Turbomachinery Performance in the Optimization of Supercritical Carbon Dioxide Power Systems

2019 ◽  
Author(s):  
Alessandro Romei ◽  
Paolo Gaetani ◽  
Andrea Giostri ◽  
Giacomo Persico
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Power Systems ◽  
Pressure Ratio ◽  
Plant Size ◽  
Cycle Performance ◽  
Small Contribution ◽  
Compression Process ◽  
Multiple Cycle ◽  
Supercritical Carbon

Abstract The successful penetration of supercritical carbon dioxide (sCO2) power systems in the energy market largely depends on the achievable turbomachinery performance. The present study illustrates a systematic framework where both the compressor and the turbine are designed via validated (within ±2% pts against experiments) mean-line tools and the related impact on cycle performance estimates is quantitatively and qualitatively assessed. A significant effort is devoted to the analysis of centrifugal compressor performance operating close to the critical point, where sharp thermodynamic property variations may make critical the compression process. The analysis is performed for different compressor sizes and pressure ratios, showing a comparatively small contribution of compressor-intake fluid conditions to the machine efficiency, which may achieve technological competitive values (82 ÷ 85%) for representative full-scale sizes. Two polynomial correlations for both turbomachinery efficiencies are devised as a function of proper similarity parameters accounting for machine sizes and loadings. Such correlations can be easily embedded in power cycle optimizations, which are usually carried out assuming constant-turbomachinery efficiency, thus ignoring the effects of plant size and cycle operating parameters. Efficiency correlations are finally exploited to perform several optimizations of a recompressed sCO2 cycle, by varying multiple cycle parameters (i.e. maximum and minimum temperature, pressure ratio and net power output). The results highlight that the replacement of constant-efficiency assumption with the proposed correlations leads to more accurate performance predictions (i.e. cycle efficiency can differ by more than 4% pts), showing in particular that an optimal pressure ratio exists in the range 2 ÷ 5 for all the investigated configurations.

Visualization of Supercritical Carbon Dioxide Flow Through a Converging-Diverging Nozzle

2019 ◽  
Author(s):  
Chang Hyeon Lim ◽  
Gokul Pathikonda ◽  
Sandeep Pidaparti ◽  
Devesh Ranjan
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Critical Point ◽  
High Speed ◽  
Operating Conditions ◽  
Higher Plant ◽  
Two Phase ◽  
Pressure Profiles ◽  
Flow Through ◽  
Supercritical Carbon

Abstract Supercritical carbon dioxide (sCO2) power cycles have the potential to offer a higher plant efficiency than the traditional Rankine superheated/supercritical steam cycle or Helium Brayton cycles. The most attractive characteristic of sCO2 is that the fluid density is high near the critical point, allowing compressors to consume less power than conventional gas Brayton cycles and maintain a smaller turbomachinery size. Despite these advantages, there still exist unsolved challenges in design and operation of sCO2 compressors near the critical point. Drastic changes in fluid properties near the critical point and the high compressibility of the fluid pose several challenges. Operating a sCO2 compressor near the critical point has potential to produce two phase flow, which can be detrimental to turbomachinery performance. To mimic the expanding regions of compressor blades, flow through a converging-diverging nozzle is investigated. Pressure profiles along the nozzle are recorded and presented for operating conditions near the critical point. Using high speed shadowgraph images, onset and growth of condensation is captured along the nozzle. Pressure profiles were calculated using a one-dimensional homogeneous equilibrium model and compared with experimental data.

scholarly journals Performance Analysis of the Supercritical Carbon Dioxide Re-compression Brayton Cycle

2020 ◽  
Vol 10 (3) ◽  
pp. 1129 ◽  
Author(s):  
Mohammad Saad Salim ◽  
Muhammad Saeed ◽  
Man-Hoe Kim
Keyword(s):  
Carbon Dioxide ◽  
Performance Analysis ◽  
Supercritical Carbon Dioxide ◽  
Mass Fraction ◽  
Inlet Temperature ◽  
Brayton Cycle ◽  
Exergy Destruction ◽  
Turbine Inlet Temperature ◽  
Turbine Inlet ◽  
Compressor Inlet

This paper presents performance analysis results on supercritical carbon dioxide ( s C O 2 ) re-compression Brayton cycle. Monthly exergy destruction analysis was conducted to find the effects of different ambient and water temperatures on the performance of the system. The results reveal that the gas cooler is the major source of exergy destruction in the system. The total exergy destruction has the lowest value of 390.1   kW when the compressor inlet temperature is near the critical point (at 35 °C) and the compressor outlet pressure is comparatively low ( 24   MPa ). The optimum mass fraction (x) and efficiency of the cycle increase with turbine inlet temperature. The highest efficiency of 49% is obtained at the mass fraction of x = 0.74 and turbine inlet temperature of 700 °C. For predicting the cost of the system, the total heat transfer area coefficient ( U A T o t a l ) and size parameter (SP) are used. The U A T o t a l value has the maximum for the split mass fraction of 0.74 corresponding to the maximum value of thermal efficiency. The SP value for the turbine is 0.212 dm at the turbine inlet temperature of 700 °C and it increases with increasing turbine inlet temperature. However the SP values of the main compressor and re-compressor increase with increasing compressor inlet temperature.

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