Combustion and Emission Characteristics of a Diesel Engine Working With Diesel/Jojoba Biodiesel/Higher Alcohol Blends

2020 ◽  
Author(s):  
Ahmed I. EL-Seesy ◽  
Mohamed Nour ◽  
Tiemin Xuan ◽  
Zhixia He ◽  
Hamdy Hassan
Keyword(s):  
High Viscosity ◽  
Higher Alcohols ◽  
Engine Emissions ◽  
Nox Formation ◽  
Higher Alcohol ◽  
Mechanical Dispersion ◽  
Combustion Duration ◽  
Ci Engine ◽  
Biodiesel Blend ◽  
Ci Engines

Abstract The main concerns of utilizing jojoba biodiesel in CI engines is that it has a high viscosity and high NOx formation. Therefore, this article purposes in endeavoring to improve the combustion and emission parameters of a CI engine working with diesel/jojoba biodiesel blend and higher alcohols under various engine loads. The higher alcohols typically are n-butanol, n-heptanol, and n-octanol, which are combined with 50% diesel, 40% of jojoba biodiesel at a volume portion of 10%, and they are designated as DJB, DJH, and DJO respectively. The jojoba biodiesel is manufactured via a transesterification process with facilitating mechanical dispersion. The findings display that there is a drop in pmax and HRR for DJB, DJH, and DJO blends compared to pure diesel fuel, whereas the combustion duration and ignition delay are extended. The brake specific fuel consumption is enlarged. Concerning engine emissions, the NOx formation is reduced while the CO, UHC, and soot emissions are increased for DJB, DJH, and DJO mixtures. It can be deduced that combining high fractions of jojoba biodiesel with C4, C7, and C8 alcohols have the feasible to accomplish low NOx formation in the interim having high thermal efficiency level.

A biometric study of higher alcohol production in Saccharomyces cerevisiae

1990 ◽  
Vol 36 (1) ◽  
pp. 61-64 ◽  
Author(s):  
Paolo Giudici ◽  
Patrizia Romano ◽  
Carlo Zambonelli
Keyword(s):  
Saccharomyces Cerevisiae ◽  
Key Words ◽  
Isoamyl Alcohol ◽  
Higher Alcohols ◽  
Methionine Biosynthesis ◽  
Higher Alcohol ◽  
Strain Characteristic ◽  
Alcohol Production ◽  
Flocculation Ability ◽  
Individual Strain

A hundred strains of Saccharomyces cerevisiae were examined for the ability to produce higher alcohols. In the strains tested the production of higher alcohols was found to be an individual strain characteristic and, as such, was statistically significant. The characteristics of the strains used (flocculation ability, foaming ability, killer character, and non-H2S production) were found to be uncorrelated to isobutanol and isoamyl alcohol production, whereas the production of high levels of n-propanol was found to be related to inability to produce H2S. This, in turn, suggests a link to methionine biosynthesis. Key words: Saccharomyces cerevisiae, higher alcohols, biometry, H2S production.

scholarly journals Use of diesel and emulsified diesel in CI engine: A comparative analysis of engine characteristics

2021 ◽  
Vol 104 (2) ◽  
pp. 003685042110209
Author(s):  
Zain Ul Hassan ◽  
Muhammad Usman ◽  
Muhammad Asim ◽  
Ali Hussain Kazim ◽  
Muhammad Farooq ◽  
...  
Keyword(s):  
Comparative Analysis ◽  
Alternative Fuels ◽  
Fossil Fuels ◽  
Negative Impact ◽  
Water Injection ◽  
Load Range ◽  
Performance And Emission ◽  
Injection Methods ◽  
Ci Engine ◽  
Ci Engines

Despite a number of efforts to evaluate the utility of water-diesel emulsions (WED) in CI engine to improve its performance and reduce its emissions in search of alternative fuels to combat the higher prices and depleting resources of fossil fuels, no consistent results are available. Additionally, the noise emissions in the case of WED are not thoroughly discussed which motivated this research to analyze the performance and emission characteristics of WED. Brake thermal efficiency (BTE) and brake specific fuel consumption (BSFC) were calculated at 1600 rpm within 15%–75% of the load range. Similarly, the contents of NOx, CO, and HC, and level of noise and smoke were measured varying the percentage of water from 2% to 10% gradually for all values of loads. BTE in the case of water emulsified diesel was decreased gradually as the percentage of water increased accompanied by a gradual increase in BSFC. Thus, WED10 showed a maximum 13.08% lower value of BTE while BSFC was increased by 32.28%. However, NOx emissions (21.8%) and smoke (48%) were also reduced significantly in the case of WED10 along with an increase in the emissions of HC and CO and noise. The comparative analysis showed that the emulsified diesel can significantly reduce the emission of NOx and smoke, but it has a negative impact on the performance characteristics and HC, CO, and noise emissions which can be mitigated by trying more fuels variations such as biodiesel and using different water injection methods to decrease dependency on fossil fuels and improve the environmental impacts of CI engines.

scholarly journals iTRAQ-based proteomic analysis reveals the molecule mechanism of reducing higher alcohols in Chinese rice wine by nitrogen compensation

2021 ◽  
Vol 71 (1) ◽  
Author(s):  
Guidong Huang ◽  
Hong Ren ◽  
Ali Wang ◽  
Xinran Wan ◽  
Ziying Wu ◽  
...  
Keyword(s):  
Molecular Mechanism ◽  
Carbon Metabolism ◽  
Proteomic Analysis ◽  
Metabolic Flux ◽  
Quantitative Polymerase Chain Reaction ◽  
Higher Alcohols ◽  
Rice Wine ◽  
Chinese Rice Wine ◽  
Higher Alcohol ◽  
Amino Acid Synthesis

Abstract Purpose Higher alcohol is a by-product of the fermentation of wine, and its content is one of the most important parameters that affect and are used to appraise the final quality of Chinese rice wine. Ammonium compensation is an efficient and convenient method to reduce the content of higher alcohols, but the molecule mechanism is poorly understood. Therefore, an iTRAQ-based proteomic analysis was designed to reveal the proteomic changes of Saccharomyces cerevisiae to elucidate the molecular mechanism of ammonium compensation in reducing the content of higher alcohols. Methods The iTRAQ proteomic analysis method was used to analyze a blank group and an experimental group with an exogenous addition of 200 mg/L (NH4)2HPO4 during inoculation. The extracted intracellular proteins were processed by liquid chromatography-mass spectrometry and identified using bioinformatics tools. Real-time quantitative polymerase chain reaction was used to verify the gene expression of differentially expressed proteins. Results About 4062 proteins, including 123 upregulated and 88 downregulated proteins, were identified by iTRAQ-based proteomic analysis. GO and KEGG analysis uncovered that significant proteins were concentrated during carbohydrate metabolism, such as carbon metabolism, glyoxylate, and dicarboxylate metabolism, pyruvate metabolism, and the nitrogen metabolism, such as amino acid synthesis and catabolism pathway. In accordance with the trend of differential protein regulation in the central carbon metabolism pathway and the analysis of carbon metabolic flux, a possible regulatory model was proposed and verified, in which ammonium compensation facilitated glucose consumption, regulated metabolic flow direction into tricarboxylic acid, and further led to a decrease in higher alcohols. The results of RT-qPCR confirmed the authenticity of the proteomic analysis results at the level of gene. Conclusion Ammonium assimilation promoted by ammonium compensation regulated the intracellular carbon metabolism of S. cerevisiae and affected the distribution of metabolic flux. The carbon flow that should have gone to the synthesis pathway of higher alcohols was reversed to the TCA cycle, thereby decreasing the content of higher alcohols. These findings may contribute to an improved understanding of the molecular mechanism for the decrease in higher alcohol content through ammonium compensation.

scholarly journals Influence of blends of diesel and renewable fuels on CI engine emissions over transient engine conditions.

2018 ◽  
Author(s):  
Adriaan Smuts Van Niekerk ◽  
Benjamin Drew ◽  
Neil Larsen ◽  
Peter Kay
Keyword(s):  
Fuel Consumption ◽  
Co2 Emissions ◽  
Nox Emissions ◽  
Compression Ignition ◽  
Engine Emissions ◽  
Drive Cycle ◽  
Fuel Blend ◽  
High Oxygen Content ◽  
Fuel Blends ◽  
Ci Engine

To reduce the amount of carbon dioxide released from transportation the EU has implemented legislation to mandate the renewable content of petrol and diesel fuels. However, due to the complexity of the combustion process the addition of renewable content, such as biodiesel and ethanol, can have a detrimental effect on other engine emissions. In particular the engine load can have a significant impact on the emissions. Most research that have studied this issue are based on steady state tests, that are unrealistic of real world driving and will not capture the difference between full and part loads. This study aims to address this by investigating the effect of renewable fuel blends of diesel, biodiesel and ethanol on the emissions of a compression ignition engine tested over the World Harmonised Light Vehicle Test Procedure (WLTP). Diesel, biodiesel and ethanol were blended to form binary and ternary blends, the ratios were determined by Design of Experiments (DoE). The total amount of emissions for CO, CO2 and NOx as well as the fuel consumption, were measured from a 2.4 liter compression ignition (CI) engine running over the WLTP drive cycle. The results depicted that percentages smaller than 10 % of ethanol in the fuel blend can reduce CO emissions, CO2 emissions as well as NOx emissions, but increases fuel consumption with increasing percentage of ethanol in the fuel blend. Blends with biodiesel resulted in minor increases in CO emissions due to the engine being operated in the low and medium load regions over the WLTP. CO2 emissions as well as NOx emissions increased as a result of the high oxygen content in biodiesel which promoted better combustion. Fuel consumption increased for blends with biodiesel as a result from biodiesel's lower heating value. All the statistical models describing the engine responses were significant and this demonstrated that a mixture DoE is suitable to quantify the effect of fuel blends on an engine's emissions response. An optimised ternary blend of B2E9 was found to be suitable as a 'drop in' fuel that will reduce harmful emissions of CO emissions by approximately 34 %, NOx emissions by 10 % and CO2 emissions by 21 % for transient engine operating scenarios such as the WLTP drive cycle.

scholarly journals Performance and emission characteristics of dual fuel engine using biodiesels

2021 ◽  
Vol 850 (1) ◽  
pp. 012005
Author(s):  
Nikhil Muthu Kumar ◽  
Harsh Bhavsar ◽  
G Sakthivel ◽  
Mohammed Musthafa Feroskhan ◽  
K Karunamurthy
Keyword(s):  
Fish Oil ◽  
New Technologies ◽  
Dual Fuel ◽  
Emission Characteristics ◽  
Performance And Emission ◽  
Fuel Blends ◽  
Mahua Oil ◽  
Secondary Fuel ◽  
Ci Engine ◽  
Ci Engines

Abstract The introduction of the strict emissions norms is diverting the research for the development of new technologies which leads to the reduction of engine exhaust emissions. The usage of biodiesel in CI engine can enhance air quality index and protects the environment. Biodiesel can do an increment in the life of CI engines because it is clean-burning and a stable fuel when compared to diesel. Moreover, biogas has the potential to decrease both nitrogen oxides and smoke emissions simultaneously. Operating the engine in dual-fuel mode can provide lower emissions and a proper substitute for diesel. In this research, a modified CI Engine with single cylinder is used. Biogas is used as primary fuel and diesel, Mahua oil-diesel blend and Fish oil-diesel blend are used as secondary fuel. The effect of various secondary fuel blends on performance and emission characteristics in dual fuel engine are compared. In light of the performance and emission qualities it is reasoned that, utilization of the dual fuel mode in engine signifies the durability and lessens the harmful emissions from the engine with the exception of hydrocarbon and CO emissions. The excessive viscosity of fish oil and mahua oil prompts inconvenience in siphoning and spray attributes. The incompetent mixing of raw fish oil and raw mahua oil with diesel and biogas including air leads to incomplete combustion.

scholarly journals On the role of higher alcohols in the characterization of cachaça

2020 ◽  
Vol 9 (10) ◽  
pp. e8299109135
Author(s):  
Amazile Biagioni Maia ◽  
Lorena Simão Marinho ◽  
David Lee Nelson
Keyword(s):  
Isoamyl Alcohol ◽  
Raw Material ◽  
Alcoholic Beverages ◽  
Higher Alcohols ◽  
Isobutyl Alcohol ◽  
Higher Alcohol ◽  
Three Samples ◽  
Typical Range

There is a growing interest in chemical markers for the identification and certification of cachaça as a cane spirit produced in Brazil. It is known that the higher alcohols that are usually analyzed (propyl alcohol, Isobutyl alcohol and isoamyl alcohol) occur in all alcoholic beverages (fermented and distilled), but the relative proportions can vary markedly according to the peculiarities of the raw material and the production process. In this work, the contents of higher alcohols in 300 samples of alembic cachaça were compared, 220 from the state of Minas Gerais and 80 from other states, as well as three samples of industrial cachaça and 14 samples of whiskeys of various brands. The typical range of total higher alcohols in cachaça was 180-360 mg/100 mL ethanol. Cachaça containing higher alcohol concentrations greater than 360 mg/100 mL ethanol do not comply with Brazilian legislation. However, cachaças with higher alcohols concentrations below 180 mg/100 mL ethanol, as was found in one of the industrial cachaças, signify adulteration, for example, by mixing with fuel alcohol. The C4/C5 ratio varied less than the C3/C5 ratio, being consistently within the range of 0.20-0.50. In the whiskeys analyzed, the concentrations of higher alcohols were in the range of 160 and 270 mg/100 mL. Therefore, this parameter would not assist in differentiating between cachaça and whiskey. But the C4/C5 ratio was consistently different, being always greater than 0.50 for the whiskeys. Thus, the routine analysis of higher alcohols provides useful information both for tracking possible fraud and for assessments related to the identity or origin of cachaça.

scholarly journals Effect of some vitamins and micronutrient deficiencies on the production of higher alcohols by Saccharomyces cerevisiae

1993 ◽  
Vol 50 (3) ◽  
pp. 484-489 ◽  
Author(s):  
L.E. Gutierrez
Keyword(s):  
Saccharomyces Cerevisiae ◽  
Alcoholic Fermentation ◽  
Isoamyl Alcohol ◽  
Higher Alcohols ◽  
Micronutrient Deficiencies ◽  
Isobutyl Alcohol ◽  
Yeast Saccharomyces Cerevisiae ◽  
Higher Alcohol ◽  
Alcohol Production ◽  
Acid Deficiency

A study was carried out in order to determine the effect of vitamins (biotin, thiamine, pantotheniic acid and pyridoxal) and micronutrient (zinc, boron, manganese and iron) deficiencies on higher alcohol production during alcoholic fermentation with the industrially used yeast Saccharomyces cerevisiae M-300-A. Zinc deficiency induced a reduction on the levels of isobutyl and isoamyl alcohols. An increase on isobutyl alcohol (fivefold) and a reduction of isoamyl alcohol (two fold) and n-propyl alcohol (three fold) contents resulted from pantotheiiic acid deficiency, whereas pyridoxal deficiency caused an increase on the levels of isobutyl and isoamyl alcohols. Biotin was not essential for the growth of this strain.

Optimization of injection timing and anti-oxidants for multiple responses of CI engine fuelled with algae biodiesel blend

Fuel ◽  
2021 ◽  
Vol 287 ◽  
pp. 119438
Author(s):  
Saravanan Subramani ◽  
Krishnamoorthy Natarajan ◽  
G. Lakshmi Narayana Rao
Keyword(s):  
Injection Timing ◽  
Multiple Responses ◽  
Algae Biodiesel ◽  
Ci Engine ◽  
Biodiesel Blend
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