The Puzzle of Drastic Reduction of Point Source Emissions and Continuing High Deposition of Mercury in Florida

Author(s):  
N. J. Themelis

This report shows that the combined emissions of mercury from major point sources of mercury in Florida decreased from about 4.8 short tons in 1994 to 1.3 tons in recent years. A similar reduction of mercury emissions was reported by Florida DEP for south Florida where the Everglades Park is located: Point sources of emissions decreased from a high of 3.4 short tons (3,100 kg) of mercury in 1991 to 0.22 tons (204 kg) in 2000. The Florida DEP study of the Everglades also showed that the mercury concentrations in largemouth bass and in great egret nestlings decreased by a factor of six between 1991 and 2000. On the other hand, our analysis of 330 sets of weekly mercury deposition data, obtained by the Everglades station of the national Mercury Deposition Network (MDN) showed that the annual average deposition in the Everglades did not change significantly from December 1995 to January 2004. Two other interesting findings were that 73% of the total mercury deposition during those eight years occurred in the high precipitation season, between May and October; and that 40% of the weekly samples taken during this eight-year period represented only 3.8 % of the recorded total deposition of mercury. This paper examines the reasons why the substantial decrease of local and regional point sources of mercury emission has not affected substantially the local deposition rates. A likely answer is that climatic conditions in Florida, associated mainly with the warmer months and higher rates of precipitation and evaporation, have a large effect on a) re-emission of previously deposited mercury and b) co-precipitation of global mercury from the atmosphere. This may also explain why Florida, where the present annual rate of mercury emissions from coal-fired power plants (in kilograms per square kilometer) is one fifth that of Pennsylvania, has mercury deposition rates that are twice those reported by MDN for Pennsylvania.

2010 ◽  
Vol 10 (2) ◽  
pp. 4719-4752 ◽  
Author(s):  
N. Pirrone ◽  
S. Cinnirella ◽  
X. Feng ◽  
R. B. Finkelman ◽  
H. R. Friedli ◽  
...  

Abstract. This paper provides an up-to-date assessment of global mercury emissions from anthropogenic and natural sources. On an annual basis, natural sources account for 5207 Mg of mercury released to the global atmosphere, including the contribution from re-emission processes, which are emissions of previously deposited mercury originating from anthropogenic and natural sources, and primary emissions from natural reservoirs. Anthropogenic sources, which include a large number of industrial point sources, are estimated to account for 2320 Mg of mercury emitted annually. The major contributions are from fossil-fuel fired power plants (810 Mg yr−1), artisanal small scale gold mining (400 Mg yr−1), non-ferrous metals manufacturing (310 Mg yr−1), cement production (236 Mg yr−1), waste disposal (187 Mg yr−1) and caustic soda production (163 Mg yr−1). Therefore, our current estimate of global mercury emissions suggests that the overall contribution from natural sources (primary emissions+re-emissions) and anthropogenic sources is nearly 7527 Mg per year, the uncertainty associated with these estimates are related to the typology of emission sources and source regions.


2010 ◽  
Vol 10 (13) ◽  
pp. 5951-5964 ◽  
Author(s):  
N. Pirrone ◽  
S. Cinnirella ◽  
X. Feng ◽  
R. B. Finkelman ◽  
H. R. Friedli ◽  
...  

Abstract. This paper provides an up-to-date assessment of global mercury emissions from anthropogenic and natural sources. On an annual basis, natural sources account for 5207 Mg of mercury released to the global atmosphere, including the contribution from re-emission processes, which are emissions of previously deposited mercury originating from anthropogenic and natural sources, and primary emissions from natural reservoirs. Anthropogenic sources, which include a large number of industrial point sources, are estimated to account for 2320 Mg of mercury emitted annually. The major contributions are from fossil-fuel fired power plants (810 Mg yr−1), artisanal small scale gold mining (400 Mg yr−1), non-ferrous metals manufacturing (310 Mg yr−1), cement production (236 Mg yr−1), waste disposal (187 Mg yr−1) and caustic soda production (163 Mg yr−1). Therefore, our current estimate of global mercury emissions suggests that the overall contribution from natural sources (primary emissions + re-emissions) and anthropogenic sources is nearly 7527 Mg per year, the uncertainty associated with these estimates are related to the typology of emission sources and source regions.


Atmosphere ◽  
2021 ◽  
Vol 12 (7) ◽  
pp. 811
Author(s):  
Yaqin Hu ◽  
Yusheng Shi

The concentration of atmospheric carbon dioxide (CO2) has increased rapidly worldwide, aggravating the global greenhouse effect, and coal-fired power plants are one of the biggest contributors of greenhouse gas emissions in China. However, efficient methods that can quantify CO2 emissions from individual coal-fired power plants with high accuracy are needed. In this study, we estimated the CO2 emissions of large-scale coal-fired power plants using Orbiting Carbon Observatory-2 (OCO-2) satellite data based on remote sensing inversions and bottom-up methods. First, we mapped the distribution of coal-fired power plants, displaying the total installed capacity, and identified two appropriate targets, the Waigaoqiao and Qinbei power plants in Shanghai and Henan, respectively. Then, an improved Gaussian plume model method was applied for CO2 emission estimations, with input parameters including the geographic coordinates of point sources, wind vectors from the atmospheric reanalysis of the global climate, and OCO-2 observations. The application of the Gaussian model was improved by using wind data with higher temporal and spatial resolutions, employing the physically based unit conversion method, and interpolating OCO-2 observations into different resolutions. Consequently, CO2 emissions were estimated to be 23.06 ± 2.82 (95% CI) Mt/yr using the Gaussian model and 16.28 Mt/yr using the bottom-up method for the Waigaoqiao Power Plant, and 14.58 ± 3.37 (95% CI) and 14.08 Mt/yr for the Qinbei Power Plant, respectively. These estimates were compared with three standard databases for validation: the Carbon Monitoring for Action database, the China coal-fired Power Plant Emissions Database, and the Carbon Brief database. The comparison found that previous emission inventories spanning different time frames might have overestimated the CO2 emissions of one of two Chinese power plants on the two days that the measurements were made. Our study contributes to quantifying CO2 emissions from point sources and helps in advancing satellite-based monitoring techniques of emission sources in the future; this helps in reducing errors due to human intervention in bottom-up statistical methods.


2021 ◽  
Vol 13 (7) ◽  
pp. 3933
Author(s):  
Solomon E. Uhunamure ◽  
Karabo Shale

South Africa is been faced with erratic power supply, resulting in persistent load shedding due to ageing in most of its coal-fired power plants. Associated with generating electricity from fossil fuel are environmental consequences such as greenhouse emissions and climate change. On the other hand, the country is endowed with abundant renewable energy resources that can potentially ameliorate its energy needs. This article explores the viability of renewable energy using the strengths, weaknesses, opportunities and threats (SWOT) analysis approach on the key renewable potential in the country. The result indicates that geographic position, political and economic stability and policy implementation are some of the strengths. However, Government bureaucratic processes, level of awareness and high investment cost are some of the weaknesses. Several opportunities favour switching to renewable energy, and these include regional integration, global awareness on climate change and the continuous electricity demand. Some threats hindering the renewable energy sector in the country include land ownership, corruption and erratic climatic conditions. Some policy implications are suggested based on the findings of the study.


Geophysics ◽  
1997 ◽  
Vol 62 (5) ◽  
pp. 1369-1378 ◽  
Author(s):  
Georg F. Schwarz ◽  
Ladislaus Rybach ◽  
Emile E. Klingelé

Airborne radiometric surveys are finding increasingly wider applications in environmental mapping and monitoring. They are the most efficient tool to delimit surface contamination and to locate lost radioactive sources. To secure radiometric capability in survey and emergency situations, a new sensitive airborne system has been built that includes an airborne spectrometer with 256 channels and a sodium iodide detector with a total volume of 16.8 liters. A rack mounted PC with memory cards is used for data acquisition, with a GPS satellite navigation system for positioning. The system was calibrated with point sources using a mathematical correction to take into account the effects of gamma‐ray scattering in the ground and in the atmosphere. The calibration was complemented by high precision ground gamma spectrometry and laboratory measurements on rock samples. In Switzerland, two major research programs make use of the capabilities of airborne radiometric measurements. The first one concerns nuclear power plant monitoring. The five Swiss nuclear installations (four power plants and one research facility) and the surrounding regions of each site are surveyed annually. The project goal is to monitor the dose‐rate distribution and to provide a documented baseline database. The measurements show that all sites (with the exception of the Gösgen power plant) can be identified clearly on the maps. No artificial radioactivity that could not be explained by the Chernobyl release or earlier nuclear weapons tests was detected outside of the fenced sites of the nuclear installations. The second program aims at a better evaluation of the natural radiation level in Switzerland. The survey focused on the crystalline rocks of the Central Massifs of the Swiss Alps because of their relatively high natural radioactivity and lithological variability.


2010 ◽  
Vol 7 (6) ◽  
pp. 537 ◽  
Author(s):  
Anne L. Soerensen ◽  
Henrik Skov ◽  
Matthew S. Johnson ◽  
Marianne Glasius

Environmental context Mercury is a neurotoxin that bioaccumulates in the aquatic food web. Atmospheric emissions from urban areas close to the coast could cause increased local mercury deposition to the ocean. Our study adds important new data to the current limited knowledge on atmospheric mercury emissions and dynamics in coastal urban areas. Abstract Approximately 50% of primary atmospheric mercury emissions are anthropogenic, resulting from e.g. emission hotspots in urban areas. Emissions from urban areas close to the coast are of interest because they could increase deposition loads to nearby coastal waters as well as contribute to long range transport of mercury. We present results from measurements of gaseous elemental mercury (GEM) and reactive gaseous mercury (RGM) in 15 coastal cities and their surrounding marine boundary layer (MBL). An increase of 15–90% in GEM concentration in coastal urban areas was observed compared with the remote MBL. Strong RGM enhancements were only found in two cities. In urban areas with statistically significant GEM/CO enhancement ratios, slopes between 0.0020 and 0.0087 ng m–3 ppb–1 were observed, which is consistent with other observations of anthropogenic enhancement. The emission ratios were used to estimate GEM emissions from the areas. A closer examination of data from Sydney (Australia), the coast of Chile, and Valparaiso region (Chile) in the southern hemisphere, is presented.


2009 ◽  
Vol 76 (3) ◽  
pp. 724-732 ◽  
Author(s):  
Amir M. Abdelzaher ◽  
Mary E. Wright ◽  
Cristina Ortega ◽  
Helena M. Solo-Gabriele ◽  
Gary Miller ◽  
...  

ABSTRACT Swimming in ocean water, including ocean water at beaches not impacted by known point sources of pollution, is an increasing health concern. This study was an initial evaluation of the presence of indicator microbes and pathogens and the association among the indicator microbes, pathogens, and environmental conditions at a subtropical, recreational marine beach in south Florida impacted by non-point sources of pollution. Twelve water and eight sand samples were collected during four sampling events at high or low tide under elevated or reduced solar insolation conditions. The analyses performed included analyses of fecal indicator bacteria (FIB) (fecal coliforms, Escherichia coli, enterococci, and Clostridium perfringens), human-associated microbial source tracking (MST) markers (human polyomaviruses [HPyVs] and Enterococcus faecium esp gene), and pathogens (Vibrio vulnificus, Staphylococcus aureus, enterovirus, norovirus, hepatitis A virus, Cryptosporidium spp., and Giardia spp.). The enterococcus concentrations in water and sand determined by quantitative PCR were greater than the concentrations determined by membrane filtration measurement. The FIB concentrations in water were below the recreational water quality standards for three of the four sampling events, when pathogens and MST markers were also generally undetectable. The FIB levels exceeded regulatory guidelines during one event, and this was accompanied by detection of HPyVs and pathogens, including detection of the autochthonous bacterium V. vulnificus in sand and water, detection of the allochthonous protozoans Giardia spp. in water, and detection of Cryptosporidium spp. in sand samples. The elevated microbial levels were detected at high tide and under low-solar-insolation conditions. Additional sampling should be conducted to further explore the relationships between tidal and solar insolation conditions and between indicator microbes and pathogens in subtropical recreational marine waters impacted by non-point source pollution.


2021 ◽  
Vol 848 (1) ◽  
pp. 012109
Author(s):  
I V Kovalev ◽  
N V Zenutkin ◽  
A A Voroshilova ◽  
N A Testoyedov ◽  
E N Golovenkin ◽  
...  

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