Long-range ordered aluminum oxide nanotubes by nanoimprint-assisted aluminum film surface engineering

Author(s):  
Kunbae Noh ◽  
Chulmin Choi ◽  
Jin-Yeol Kim ◽  
Young Oh ◽  
Karla S. Brammer ◽  
...  
RSC Advances ◽  
2016 ◽  
Vol 6 (72) ◽  
pp. 67992-67996 ◽  
Author(s):  
E. Choudhary ◽  
V. Szalai

Nanoporous anodic aluminum oxide (AAO) membranes are being used for an increasing number of applications.


Author(s):  
Hiromasa Teshima ◽  
Kohei Kojima ◽  
Yang Ju

There is an urgent need in surface mount technology (SMT) for a nontoxic, reusable and low temperature bonding technique which can afford good mechanical support as well as electrical contact. Meanwhile in the nanotechnology, many excellent and unique structure-related properties such as the high mechanical strength, the high conductivity and the adhesion ability of gecko feet have been studied. Our lab proposes a new patterned structure of Au nanowire array named nanowire surface fastener (NSF), which cold bonding for surface mount technology can be realized at room temperature. Then various methods have been developed to fabricate nanowire, such as arc discharge, catalytic CVD growth and template synthesis, and so on. Among these methods, the template method has been widely used for preparing one-dimensional nanostructures such as metals, semiconductors, polymers, and other materials by electrochemical, electroless deposition or sol-gel technique. Especially anodic aluminum oxide template assisted way has attached considerable attention due to its unique structure properties, such as controllable pore diameter, extremely narrow pore size distribution with high densities, high aspect ratios, and ideally cylindrical pore shape. The well arranged porous anodic aluminum oxide membrane is fabricated from aluminum film by two steps zM oxalic acid electrolytes. The anodic aluminum oxide membrane was investigated for features such as pore size, interpore distance, and thickness by 40 V. It is important for fabrication of porous anodic aluminum oxide template to find out elimination of the barrier layer of oxide and the pore extending rate by 0.5 M phosphoric acid. Morphologies of surface of aluminum film between anodization process and the anodic aluminum oxide barrier layer was researched by using atomic force microscope and scanning electron microscope. Results showed that the anodic aluminum oxide having the same diameter of the pore and the well arranged pore array without branching channel was obtained. The diameter of the pore before the pore extending treatment is 42 nm and the diameter of the pore after the pore extending treatment for 30 minutes is 86 nm. It was found that the diameter of the pore increased per 15 nm by the pore extending treatment for 10 minutes. We fabricated the through-hole anodic aluminum oxide template and made Cu nanowire by the template of our own making. By using Cu nanowire, we try to produce nanowire surface fastener and evaluate its properties.


2014 ◽  
Vol 953-954 ◽  
pp. 1282-1285 ◽  
Author(s):  
Jing Zhe Wang ◽  
Chun Hua Xu ◽  
Wei Cao ◽  
Yan He

In this paper, porous anodic aluminum oxide (AAO) membrane was prepared with highly pure aluminum film in 0.3M oxalic acid under dc voltage of 40V at about 8°C by two-step anodization. The morphology of the specimens processed in different stages of two-step anodization was observed with a scanning electron microscope (SEM). The electrochemical behavior of the anodized aluminum after different stages of two-step anodization was studied by electrochemical impedance spectroscopy (EIS). Different equivalent circuits were established to fit EIS experiment data, based on morphologies and structures of AAO during processing. The electrical elements in the equivalent circuits were used to explain experimental parameters.


2018 ◽  
Vol 49 (7) ◽  
pp. 1145-1154 ◽  
Author(s):  
Viktor I. Fabelinsky ◽  
Dimitrii N. Kozlov ◽  
Sergey N. Orlov ◽  
Yury N. Polivanov ◽  
Ivan A. Shcherbakov ◽  
...  

1973 ◽  
Vol 12 (4) ◽  
pp. 518-522 ◽  
Author(s):  
Tomomitsu Satake ◽  
Kazuo Yokoyama ◽  
Shuichi Shirakawa ◽  
Kozo Sawaguchi

2000 ◽  
Vol 634 ◽  
Author(s):  
Jacqueline Vollmann ◽  
Dieter Profunser ◽  
Jürg Dual

ABSTRACTThe precise measurement of thicknesses, mechanical properties, and film-substrate bonding qualities of sub-micron metallic films, multi-layers, and microstructures in a nondestructive way is of growing importance for the semiconductor industry as well as for MEMS manufacturers.Short laser pulses having durations of less than 100 fs are an ideal – not to say the only –way in order to provide sub-surface visualization in nanometer scale perpendicular to the film surface.In this investigation, an enhanced pump-probe set up is presented. A dual frequency modulation technique is implemented in order to eliminate optical and electrical cross talk between the excitational pump pulse and the measuring probe pulse.Up to the 5th acoustic echo in an aluminum film having a thickness of 50 nm on a sapphire substrate has been measured. From the time of flight and from the amplitude decay between the echoes the material properties of the film and of the substrate have been derived.Further directions of the on going research project are presented.


2014 ◽  
Vol 92 (12) ◽  
pp. 1614-1622 ◽  
Author(s):  
Saad Bin Mansoor ◽  
Bekir Sami Yilbas

Phonon transport in paired aluminum and silicon thin films is considered under laser short-pulse irradiation at the aluminum film surface. The Boltzmann equation is incorporated to formulate energy transport in the films. To include a volumetric source resembling laser irradiation in the aluminum film, the Boltzmann equation is modified. Thermal boundary resistance is located at the interface of the film pair. An equivalent equilibrium temperature is introduced to assess the thermal resistance of the film during the laser heating process. The phonon temperature obtained from solution of the Boltzmann equation is compared with the findings of the two-temperature model. It is found that phonon temperature obtained from the solution of the Boltzmann equation is lower than that corresponding to the two-temperature model, which is particularly true in the surface region of the aluminum film. Phonon temperature increases gradually while, early on, the electron temperature rises and decays sharply in the surface region of the aluminum film.


NANO ◽  
2010 ◽  
Vol 05 (02) ◽  
pp. 89-95 ◽  
Author(s):  
JIN-YEOL KIM ◽  
KUNBAE NOH ◽  
CHULMIN CHOI ◽  
KARLA S. BRAMMER ◽  
MARIANA LOYA ◽  
...  

We have shown in this paper that the self-ordered pore structure of anodic aluminum oxide (AAO) can be utilized as a basis to conveniently form large-area Al2O3 nanowire arrays on a glass surface. An aluminum oxide nanowire array has been produced by aluminum film deposition on glass followed by anodization, then simple chemical etching. The glass surface as prepared is highly superhydrophobic, with a contact angle as high as 169°. The thinness (~ 340 nm) and vertical alignment of the aluminum oxide nanowires with empty spaces in-between essentially contribute to maintaining the optical transparency of the glass substrate. Interestingly, substantially suppressed UV transmission in the ~ 300–400 nm spectrum region was observed with the presence of the Al2O3 nanowires on the glass substrate. Such a durable surface ceramic nanowire structure can be useful for producing superhydrophobic, self-cleaning glasses with a variety of potential applications such as UV protecting glass windows for high rise buildings with reduced consumption of water and cleaning chemicals for positive environmental effects.


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