scholarly journals Supplemental Material: Sustainable densification of the deep crust

Author(s):  
Benjamin Malvoisin

Materials and methods, Figures S1–S9 (fluid-inclusion mapping and point analyses of garnet and clinopyroxene with FTIR, sensitivity analyses for the two numerical models, results of the diffusion-reaction model in open system conditions, X-ray mapping of amphibole inclusions in clinopyroxene, evolution in space of the plagioclase composition), Tables S1 and S2 (chemical composition of the main minerals, and local bulk composition used for numerical modelling), and Movies S1 and S2 (results in 2-D of the model coupling reaction, fluid flow, and deformation).<br>

2020 ◽  
Author(s):  
Benjamin Malvoisin

Materials and methods, Figures S1–S9 (fluid-inclusion mapping and point analyses of garnet and clinopyroxene with FTIR, sensitivity analyses for the two numerical models, results of the diffusion-reaction model in open system conditions, X-ray mapping of amphibole inclusions in clinopyroxene, evolution in space of the plagioclase composition), Tables S1 and S2 (chemical composition of the main minerals, and local bulk composition used for numerical modelling), and Movies S1 and S2 (results in 2-D of the model coupling reaction, fluid flow, and deformation).<br>


Author(s):  
José D. Henao Casas ◽  
Fritz Kalwa ◽  
Marc Walther ◽  
Randolf Rausch

AbstractTo cope with water scarcity in drylands, stormwater is often collected in surface basins and subsequently stored in shallow aquifers via infiltration. These stormwater harvesting systems are often accompanied by high evaporation rates and hygiene problems. This is commonly a consequence of low infiltration rates, which are caused by clogging layers that form on top of the soil profile and the presence of a thick vadose zone. The present study aims to develop a conceptual solution to increase groundwater recharge rates in stormwater harvesting systems. The efficiency of vadose-zone wells and infiltration trenches is tested using analytical equations, numerical models, and sensitivity analyses. Dams built in the channel of ephemeral streams (wadis) are selected as a study case to construct the numerical simulations. The modelling demonstrated that vadose-zone wells and infiltration trenches contribute to effective bypassing of the clogging layer. By implementing these solutions, recharge begins 2250–8100% faster than via infiltration from the bed surface of the wadi reservoir. The sensitivity analysis showed that the recharge rates are especially responsive to well length and trench depth. In terms of recharge quantity, the well had the best performance; it can infiltrate up to 1642% more water than the reservoir, and between 336 and 825% more than the trench. Moreover, the well can yield the highest cumulative recharge per dollar and high recharge rates when there are limitations to the available area. The methods investigated here significantly increased recharge rates, providing practical solutions to enhance aquifer water storage in drylands.


Geosciences ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 490
Author(s):  
Maria Garcia-Rios ◽  
Philippe Gouze

The risk of CO2 leakage from damaged wellbore is identified as a critical issue for the feasibility and environmental acceptance of CO2 underground storage. For instance, Portland cement can be altered if flow of CO2-rich water occurs in hydraulic discontinuities such as cement-tubing or cement-caprock interfaces. In this case, the raw cement matrix is altered by diffusion of the solutes. This fact leads to the formation of distinctive alteration fronts indicating the dissolution of portlandite, the formation of a carbonate-rich layer and the decalcification of the calcium silicate hydrate, controlled by the interplay between the reaction kinetics, the diffusion-controlled renewing of the reactants and products, and the changes in the diffusion properties caused by the changes in porosity induced by the dissolution and precipitation mechanisms. In principle, these mass transfers can be easily simulated using diffusion-reaction numerical models. However, the large uncertainties of the parameters characterizing the reaction rates (mainly the kinetic and thermodynamic coefficients and the evolving reactive surface area) and of the porosity-dependent diffusion properties prevent making reliable predictions required for risk assessment. In this paper, we present the results of a set of experiments consisting in the alteration of a holed disk of class-G cement in contact with a CO2-rich brine at reservoir conditions (P = 12 MPa and T = 60 °C) for various durations. This new experimental protocol allows producing time-resolved data for both the spatially distributed mass transfers inside the cement body and the total mass transfers inferred from the boundary conditions mass balance. The experimental results are used to study the effect of the fluid salinity and the pCO2 on the overall reaction efficiency. Experiments at high salinity triggers more portlandite dissolution, thinner carbonate layers, and larger alteration areas than those at low salinity. These features are accompanied with different spatial distribution of the alteration layers resulting from a complex interplay between salinity-controlled dissolution and precipitation mechanisms. Conversely, the effect of the pCO2 is more intuitive: Increasing pCO2 results in increasing the overall alteration rate without modifying the relative distribution of the reaction fronts.


2006 ◽  
Vol 57 (15) ◽  
pp. 4215-4224 ◽  
Author(s):  
Q. T. Ho ◽  
B. E. Verlinden ◽  
P. Verboven ◽  
S. Vandewalle ◽  
B. M. Nicolai

Author(s):  
J Liaudat ◽  
C López ◽  
I Carol

2021 ◽  
pp. 26-26
Author(s):  
Ling Lin ◽  
Yun Qiao

Fractal modifications of Fick?s laws are discussed by taking into account the electrode?s porous structure, and a fractal derivative model for diffusion-reaction process in a thin film of an amperometric enzymatic reaction is established. Particular attention is paid to giving an intuitive grasp for its fractal variational principle and its solution procedure. Extremely fast or extremely slow diffusion process can be achieved by suitable control of the electrode?s surface morphology, a sponge-like surface leads to an extremely fast diffusion, while a lotus-leaf-like uneven surface predicts an extremely slow process. This paper sheds a bright light on an optimal design of an electrode?s surface morphology.


2021 ◽  
Author(s):  
Matteo Desiderio ◽  
Anna J. P. Gülcher ◽  
Maxim D. Ballmer

&lt;p&gt;According to geochemical and geophysical observations, Earth's lower mantle appears to be strikingly heterogeneous in composition. An accurate interpretation of these findings is critical to constrain Earth's bulk composition and long-term evolution. To this end, two main models have gained traction, each reflecting a different style of chemical heterogeneity preservation: the 'marble cake' and 'plum pudding' mantle. In the former, heterogeneity is preserved in the form of narrow streaks of recycled oceanic lithosphere, stretched and stirred throughout the mantle by convection. In the latter, domains of intrinsically strong, primordial material (enriched in the lower-mantle mineral bridgmanite) may resist convective entrainment and survive as coherent blobs in the mid mantle. Microscopic scale processes certainly affect macroscopic properties of mantle materials and thus reverberate on large-scale mantle dynamics. A cross-disciplinary effort is therefore needed to constrain present-day Earth structure, yet countless variables remain to be explored. Among previous geodynamic studies, for instance, only few have attempted to address how the viscosity and density of recycled and primordial materials affect their mutual mixing and interaction in the mantle.&lt;/p&gt;&lt;p&gt;Here, we apply the finite-volume code &lt;strong&gt;STAGYY&lt;/strong&gt; to model thermochemical convection of the mantle in a 2D spherical-annulus geometry. All models are initialized with a lower, primordial layer and an upper, pyrolitic layer (i.e., a mechanical mixture of basalt and harzburgite), as is motivated by magma-ocean solidification studies. We explore the effects of material properties on the style of mantle convection and heterogeneity preservation. These parameters include (i) the intrinsic strength of basalt (viscosity), (ii) the intrinsic density of basalt, and (iii) the intrinsic strength of the primordial material.&lt;/p&gt;&lt;p&gt;Our preliminary models predict a range of different mantle mixing styles. A 'marble cake'-like regime is observed for low-viscosity primordial material (~30 times weaker than the ambient mantle), with recycled oceanic lithosphere preserved as streaks and thermochemical piles accumulating near the core-mantle boundary. Conversely, 'plum pudding' primordial blobs are also preserved when the primordial material is relatively strong, in addition to the 'marble cake' heterogeneities mentioned above. Most notably, however, the rheology and the density anomaly of basalt affect the appearance of both recycled and primordial heterogeneities. In particular, they control the stability, size and geometry of thermochemical piles, the enhancement of basaltic streaks in the mantle transition zone, and they influence the style of primordial material preservation. These results indicate the important control that the physical properties of mantle constituents exert on the style of mantle convection and mixing over geologic time. Our numerical models offer fresh insights into these processes and may advance our understanding of the composition and structure of Earth's lower mantle.&lt;/p&gt;


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