Quasigermatranes and their monocyclic analogs with highly electronegative substituents at the germanium atom: A new synthesis strategy

2010 ◽  
Vol 36 (5) ◽  
pp. 623-627 ◽  
Author(s):  
G. S. Samokhin ◽  
D. V. Vrazhnov ◽  
T. A. Kochina ◽  
M. G. Voronkov
Keyword(s):  
Germanium Atom ◽  
New Synthesis ◽  
Synthesis Strategy

“Ship-in-a-bottle”, a new synthesis strategy for preparing novel hybrid host–guest nanocomposites for highly selective membrane gas separation

2018 ◽  
Vol 6 (4) ◽  
pp. 1751-1771 ◽  
Author(s):  
Abtin Ebadi Amooghin ◽  
Hamidreza Sanaeepur ◽  
Mohammadreza Omidkhah ◽  
Ali Kargari
Keyword(s):  
Gas Separation ◽  
Functional Materials ◽  
Hybrid Nanocomposites ◽  
Membrane Gas Separation ◽  
Polymeric Matrices ◽  
Inorganic Hybrid ◽  
New Synthesis ◽  
Synthesis Strategy ◽  
Selective Membrane

Organic–inorganic hybrid nanocomposites within polymeric matrices have potential as functional materials for membrane gas separation.

Soluble polymer supported synthesis of a monosubstituted tetraaryl porphyrin

1989 ◽  
Vol 67 (3) ◽  
pp. 411-416 ◽  
Author(s):  
Y. Takahashi ◽  
J. E. Guillet ◽  
M. A. Winnik
Keyword(s):  
Molecular Weight ◽  
Ethylene Glycol ◽  
High Yield ◽  
Separation And Purification ◽  
Poly Ethylene Glycol ◽  
Soluble Polymer ◽  
New Synthesis ◽  
Synthesis Strategy ◽  
Polymer Supported ◽  
Poly Ethylene

A new synthesis of monosubstituted tetraarylporphines is described based upon the soluble polymer supported synthesis strategy. Low molecular weight poly(ethylene glycol) is chloromethylated at both ends. These ends are then used to build up the polymer-bound ether of 5-(4′-hydroxymethyl)-10,15,20-tritolylporphine, which, after purification of the polymer, can be cleaved in high yield with TiCl4. While the method offers useful conveniences, such as the ease of separation and purification of the desired material, the overall yield is low: 100 mg from 40 g of polymer. Oligomerization of the polymer during chloromethylation increases the polymer molecular weight and thereby decreases the number of end groups per gram of polymer. Keywords: porphyrin, tetraaryl, monosubstituted poly(ethylene glycol) oligomerization, polymer-supported synthesis.

A new synthesis strategy towards enhancing the structure and cycle stabilities of the LiNi0.80Co0.15Al0.05O2 cathode material

2017 ◽  
Vol 5 (2) ◽  
pp. 835-841 ◽  
Author(s):  
H. Z. Zhang ◽  
C. Liu ◽  
D. W. Song ◽  
L. Q. Zhang ◽  
L. J. Bie
Keyword(s):  
Cathode Material ◽  
Layered Structure ◽  
Compensation Method ◽  
Electrochemical Performances ◽  
Synthetic Strategy ◽  
New Synthesis ◽  
Synthesis Strategy

A new synthetic strategy (Al-compensation method) for LNCA cathodes is proposed in this paper. As a result, the obtained LNCA electrodes exhibit a more stable layered structure and enhanced electrochemical performances.

scholarly journals Design of Dye-Sensitized Solar triphenodioxazine using TiO2 as a semiconductor

2019 ◽  
Vol 6 (1) ◽  
pp. 42-49
Author(s):  
F. Allama ◽  
N. Gherraf ◽  
Y. Nicolas ◽  
T. Toupance ◽  
D. Khatmi
Keyword(s):  
Photovoltaic Cells ◽  
Solar Spectrum ◽  
Oxide Semiconductor ◽  
Dye Sensitized ◽  
New Synthesis ◽  
Synthesis Strategy ◽  
Uv Visible ◽  
Materials Used ◽  
High Yields ◽  
Conversion Efficiencies

Abstract The present work deals with the synthesis of multichromophores which strongly absorb the solar spectrum to functionalize the nanoparticle oxide semiconductor used in the hybrid cells. At first, we developed a material that forms a chromophore triphenodioxazine. We obtained some triphenodioxazines with high yields up to 70 percent. On the other hand, we have carried out many tests such as UV-Visible, Cyclic voltammetry for our molecules to check their electronic and optical properties. The results confirmed that these chromophores meet the criteria for use in photovoltaic cells. Finally, we have successfully realized photovoltaic cells with triphenodioxazine. The findings were very interesting since the photovoltaic conversion efficiencies ranged from 4.30% to 6.30%. The new synthesis strategy of these chromophores opens a way for the development of organic materials used for photovoltaics.

New Synthesis Strategy for DNA Functional Gold Nanoparticles

2011 ◽  
Vol 115 (8) ◽  
pp. 3243-3249 ◽  
Author(s):  
Liguang Xu ◽  
Yingyue Zhu ◽  
Wei Ma ◽  
Wei Chen ◽  
Liqiang Liu ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
New Synthesis ◽  
Synthesis Strategy

A New Synthesis Strategy for Rhodanine and Its Derivatives

Synlett ◽  
2021 ◽  
Author(s):  
Zhenliang Pan ◽  
Wankai AN ◽  
Lulu Wu ◽  
Liangxin Fan ◽  
Guoyu Yang ◽  
...  
Keyword(s):  
Thioglycolic Acid ◽  
Biological Activities ◽  
Wide Spectrum ◽  
Synthesis Method ◽  
New Approach ◽  
Pharmacological Research ◽  
New Synthesis ◽  
Synthesis Strategy ◽  
One Step ◽  
Privileged Structures

Rhodanine and its derivatives have been known as privileged structures in pharmacological research because of their wide spectrum of biological activities, but the synthesis method of rhodanine skeleton is limited. In this paper, not only rhodanine skeleton, but also N-aryl rhodanines can be directly prepared via the reaction of thioureas and thioglycolic acid in one step catalyzed by protic acid, which provides a new approach of the synthesis of rhodanine and its derivatives. The developed strategy is straightforward, efficient, atom economical and convenient in good yields.

A new synthesis strategy for chiral CdS nanotubes based on a homochiral MOF template

2015 ◽  
Vol 51 (27) ◽  
pp. 5955-5958 ◽  
Author(s):  
Xuan Kuang ◽  
Yu Ma ◽  
Caiyun Zhang ◽  
Hao Su ◽  
Jine Zhang ◽  
...  
Keyword(s):  
New Synthesis ◽  
Synthesis Strategy

We present a convenient and rapid way to prepare helical CdS nanotubes, with a MOF as the template.

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