Coupling constants nitrogen-15-nitrogen-15 and nitrogen-15-hydrogen in phenylhydrazones forming hydrogen bond

1981 ◽  
Vol 46 (4) ◽  
pp. 892-897 ◽  
Author(s):  
Antonín Lyčka ◽  
Dobroslav Šnobl
Keyword(s):  
Hydrogen Bond ◽  
Carbonyl Group ◽  
Ester Group ◽  
Natural Abundance ◽  
Coupling Constants ◽  
The Other ◽  
A Value ◽  
Proton Signal ◽  
Hydrazone Form

Absolute values of the coupling constants 1J(15N15N), 1J(15NH) of six phenylhydrazones forming hydrogen bond, 2J(15N15NH) of four, and 4J(15NH) of two phenylhydrazones have been determined. Three coupling constants 1J(15N15N) have been obtained from the nitrogen-15 monolabelled compounds by measuring the other nitrogen at natural abundance. The coupling constants 2J(15N15NH) have been measured with the nitrogen-15 doubly labelled compounds, because in the arrangement 15N14NH there exists a broadening of the proton signal due to nitrogen-14. Absolute values of the coupling constants 1J(15N15N) of the phenylhydrazones forming hydrogen bond to the ester group are smaller ( 10.8 Hz) than those of the phenylhydrazones having hydrogen bond to carbonyl group ( 11.1 Hz). The coupling constants 2J(15N15NH) have a value 2.4 ± 0.2 Hz. The value of 1J(15N15N) of 1-phenylazo-2-naphthalenol decreases with increasing content of hydrazone form. The values of 2J(15N15NH) of this compound are within 1.2 to 1.6 Hz.

Conformational Terminology for Crystalline Cellulose

1972 ◽  
Vol 50 (6) ◽  
pp. 792-794 ◽  
Author(s):  
P. R. Sundararajan ◽  
R. H. Marchessault
Keyword(s):  
Hydrogen Bond ◽  
Intramolecular Hydrogen Bond ◽  
The Other ◽  
Crystalline Cellulose ◽  
Chain Model ◽  
Glucose Residue ◽  
Straight Chain ◽  
A Value ◽  
Intramolecular Hydrogen ◽  
Mathematical Interpretation

Two different crystalline models of cellulose have received attention from crystallographers: the "straight chain" model of Meyer and Misch and the "bent chain" model of P. H. Hermans. We have examined these models and have given a mathematical interpretation of each in terms of the conformational angles [Formula: see text] and ψ and the glycosidic angle τ. For a given geometry of the glucose residue, the "straight chain" corresponds to a unique value of τ; for a value of τ greater than the unique value, two "bent chains" are possible, one allowing an intramolecular hydrogen bond (O-3 … O-5′) and the other not. It is suggested that the former only be referred to as the Hermans conformation.

scholarly journals COUPLING CONSTANT UNIFICATION IN EXTENSIONS OF STANDARD MODEL

2004 ◽  
Vol 19 (19) ◽  
pp. 3217-3224 ◽  
Author(s):  
LING-FONG LI ◽  
FENG WU
Keyword(s):  
Standard Model ◽  
Strong Coupling ◽  
Coupling Constants ◽  
The Other ◽  
Coupling Constant ◽  
Supersymmetric Extension ◽  
A Value ◽  
Weinberg Angle

Unification of electromagnetic, weak, and strong coupling constants is studied in the extension of Standard Model with additional fermions and scalars. It is remarkable that this unification in the supersymmetric extension of Standard Model yields a value of Weinberg angle which agrees very well with experiments. We discuss the other possibilities which can also give same result.

The three conformations of 3,5-dichloro-2-hydroxythiophenol in solution

1981 ◽  
Vol 59 (22) ◽  
pp. 3204-3207
Author(s):  
Ted Schaefer ◽  
Richard P. Veregin ◽  
David M. McKinnon
Keyword(s):  
Hydrogen Bond ◽  
Free Energy ◽  
Chemical Shifts ◽  
Coupling Constants ◽  
The Other ◽  
Spin Coupling ◽  
Ring Plane ◽  
Spin Coupling Constants ◽  
Spin Spin Coupling ◽  
Energy Preference

The long-range spin–spin coupling constants for the sidechain protons in 3,5-dichloro-2-hydroxythiophenol show that the compound exists as a mixture of three conformers in CCl4 solution at 305 K. The conformer, in which the S—H bond is held roughly perpendicular to the ring plane by an [Formula: see text] hydrogen bond, is 13% abundant. The other two conformers, of roughly equal proportions, contain an [Formula: see text] hydrogen bond. One of these has the S—H bond cis to the OH group, the other has it trans. The chemical shifts of the SH proton and of H-6 are in agreement with these conclusions. The free energy preference of the [Formula: see text] over the [Formula: see text] bond is 1140 ± 100 cal/mol at 305 K. The five-bond coupling between the sidechain protons is negative and very likely involves proximate interactions via lone pairs on oxygen and/or sulfur.

The Electron Effect of Aromatic Group: Control Conformation of 2-Aromatic Cyclododecanone Derivatives

2020 ◽  
Vol 24 (10) ◽  
pp. 1139-1147
Author(s):  
Yang Mingyan ◽  
Wang Daoquan ◽  
Wang Mingan
Keyword(s):  
1H Nmr ◽  
13C Nmr ◽  
Nmr Spectra ◽  
Coupling Constants ◽  
The Other ◽  
Repulsive Interaction ◽  
X Ray Diffraction ◽  
X Ray ◽  
Electron Effect ◽  
Group Control

2-Phenylcyclododecanone and 2-cyclohexylcyclododecanone derivatives were synthesized and characterized by 1H NMR, 13C NMR, HR-ESI-MS and X-ray diffraction. Their preferred conformations were analyzed by the coupling constants in the 1H NMR spectra and X-ray diffraction, which showed the skeleton ring of these derivatives containing [3333]-2-one conformation, and the phenyl groups were located at the side-exo position of [3333]-2-one conformation due to the strong π-π repulsive interaction between the π- electron of benzene ring and π-electron of carbonyl group. The cyclohexyl groups were located at the corner-syn or the side-exo position of [3333]-2-one conformation depending on the hindrance of the other substituted groups. The π-π electron effect played a crucial role in efficiently controlling the preferred conformation of 2-aromatic cyclododecanone and the other 2-aromatic macrocyclic derivatives with the similar preferred square and rectangular conformations.

15N, 13C, and 1H NMR Spectra of Azo and Hydrazo Compounds Derived from 1,3,3-Trimethyl-2-methylidene-2,3-dihydroindole (Fischer Base)

1998 ◽  
Vol 63 (7) ◽  
pp. 1012-1020 ◽  
Author(s):  
Antonín Lyčka ◽  
Josef Jirman ◽  
Alois Koloničný
Keyword(s):  
Double Bond ◽  
Hydrochloric Acid ◽  
Nmr Spectra ◽  
Coupling Constants ◽  
Azo Compounds ◽  
Passive Component ◽  
Geometric Isomers ◽  
H Nmr ◽  
Fischer Base ◽  
Hydrazone Form

The 15N, 13C, and 1H NMR spectra were measured for azo and hydrazo compounds derived from 1,3,3-trimethyl-2-methylidene-2,3-dihydroindole (Fischer base), which is a passive component with a terminal methylidene group. Products prepared by coupling in hydrochloric acid exist in the corresponding hydrazone form as the E-isomers. Neutralization gives a mixture of two isomeric azo compounds which differ in the arrangement at the C(2)=C(10) double bond. This mixture was alkylated with methyl iodide to obtain the =N-N(CH3)- hydrazone derivatives. The geometric isomers were resolved based on the NOESY approach and the stereospecific behaviour of the 2J(15N,13C) coupling constants was studied for the 15N-labelled compounds.

Effect of Catfish Bone Paste on the Properties of Steamed Bread

2014 ◽  
Vol 881-883 ◽  
pp. 757-760
Author(s):  
Xiao Qing Ren ◽  
Li Zhen Ma ◽  
Xin Yi He
Keyword(s):  
Weight Loss ◽  
Specific Volume ◽  
Cell Structure ◽  
The Other ◽  
Gas Cell ◽  
A Value ◽  
Crumb Structure ◽  
Steamed Bread ◽  
Different Levels ◽  
Structure Properties

The objective of this study was to examine the effect of different levels of catfish bone paste to flour on the physicochemical, textural and crumb structure properties of steamed bread. Six different levels (0, 1, 3, 5, 7,10 %) of catfish bone paste to flour were used in the formulation of the steamed bread. The results showed that the weight loss and TTA of steamed bread decreased with an increase in the levels of the catfish bone paste. On the other hand, the pH increased with an increase in the levels of the catfish bone paste. The specific volume, hardness, chewiness and gas cell structure in the crumb of steamed bread with catfish bone paste at 5% supplementation level were better. Thus, a value of 5% catfish bone paste was considered a better level for incorporation into the steamed bread.

Effects of Light on Schooling and Feeding of Jack Mackerel, Trachurus symmetricus

1968 ◽  
Vol 25 (2) ◽  
pp. 393-407 ◽  
Author(s):  
John R. Hunter
Keyword(s):  
Motion Picture ◽  
Nearest Neighbor ◽  
Motion Pictures ◽  
Separation Distance ◽  
The Other ◽  
Angular Deviation ◽  
Jack Mackerel ◽  
A Value

Schools of six jack mackerel each were photographed with infrared film at eight levels of luminance and also in darkness. Three indices were used to measure the behavior of the school from motion pictures. Two of the indices, mean distance to nearest neighbor and mean separation distance, were measures of the distances between individuals in a school; the other, mean angular deviation, was a measure of differences in orientation between individuals. A value for each index was calculated for each motion picture frame.From 12.1 to 6 × 10−6 ft-L no differences existed in the angular deviation of the school or in the distances between fish. At 6 × 10−7 ft-L the intervals between fish were much larger than at higher levels of brightness and groups showed little uniformity in their orientation. Below 6 × 10−7 ft-L (darkness) schools were dispersed and the distributions of values of angular deviation were random.The ability of jack mackerel to feed on live adult Artemia was also tested at eight levels of luminance and in darkness. The number of Artemia eaten at 6 × 10−5 ft-L was about half of that eaten at the normal daytime level of 12.1 ft-L. Few Artemia were eaten at 6 × 10−7 ft-L and none in darkness.Comparison of these data with measurements of light in the sea indicated that jack mackerel probably would be able to maintain schools near the surface on a moonless starlit night and that they probably could feed effectively near the surface on a full moonlight night.

scholarly journals Symmetry breakdown and coupling constants of leptons

2007 ◽  
Vol 79 (2) ◽  
pp. 195-208 ◽  
Author(s):  
Gil C. Marques ◽  
Dominique Spehler
Keyword(s):  
Coupling Constants ◽  
Electroweak Interactions ◽  
New Approach ◽  
Fundamental Interactions ◽  
Electromagnetic Interactions ◽  
Symmetry Breakdown ◽  
A Value ◽  
Intermediate Bosons ◽  
The One ◽  
The Way

Based on a new approach to symmetries of the fundamental interactions we deal, in this paper, with the electroweak interactions of leptons. We show that the coupling constants, arising in the way leptons are coupled to intermediate bosons, can be understood as parameters associated to the breakdown of SU(2) and parity symmetries. The breakdown of both symmetries is characterized by a new parameter (the asymetry parameter) of the electroweak interactions. This parameter gives a measure of the strength of breakdown of symmetries. We analyse the behaviour of the theory for three values of this parameter. The most relevant value is the one for which only the electromagnetic interactions do not break parity (the maximally allowed left-right asymetric theory). Maximamally allowed parity asymmetry is a requirement that is met for a value of Weinberg's theta-angle that is quite close to the experimental value of this parameter.

Proton spin–spin coupling constants and intramolecular hydrogen bonding in bromine derivatives of 1,3-dihydroxybenzene

1976 ◽  
Vol 54 (14) ◽  
pp. 2228-2230 ◽  
Author(s):  
Ted Schaefer ◽  
J. Brian Rowbotham
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Proton Spin ◽  
Coupling Constants ◽  
Spin Coupling ◽  
Hydroxyl Groups ◽  
Oh Groups ◽  
Spin Coupling Constants ◽  
Spin Spin Coupling ◽  
Derivatives Of

The conformational preferences in CCl4 solution at 32 °C of the hydroxyl groups in bromine derivatives of 1,3-dihydroxybenzene are deduced from the long-range spin–spin coupling constants between hydroxyl protons and ring protons over five bonds. Two hydroxyl groups hydrogen bond to the same bromine substituent in 2-bromo-1,3-dihydroxybenzene but prefer to hydrogen bond to different bromine substituents when available, as in 2,4-dibromo-1,3-dihydroxybenzene. When the OH groups can each choose between two ortho bromine atoms, as in 2,4,6-tribromoresorcinol, they apparently do so in a very nearly statistical manner except that they avoid hydrogen bonding to the common bromine atom.

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