Transient Kinetic and Thermodynamic Behaviour of Langmuir Adsorption in a Flow System
1999 ◽
Vol 64
(4)
◽
pp. 726-734
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Keyword(s):
Various kinetic pathways to the adsorption equilibrium in an isothermal differential bed of adsorbent are illustrated on several examples. Discussion is based on the computed transient responses of adsorption rate and distance from adsorption equilibrium to the start of adsorptive feed. It is shown that adsorption behaviour in flow system may not be smooth and very steep changes on the rate responses may appear. Even the simple reaction need not approach equilibrium smoothly but at a jump. The approach assuming "closeness to the equilibrium" should be used very carefully, in this case.
2011 ◽
Vol 233-235
◽
pp. 91-94
2014 ◽
Vol 809-810
◽
pp. 493-499
2011 ◽
Vol 354-355
◽
pp. 33-36
Keyword(s):
2012 ◽
Vol 217-219
◽
pp. 1213-1217
2000 ◽
Vol 35
(16)
◽
pp. 2583-2599
◽
2012 ◽
Vol 581-582
◽
pp. 180-184
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Keyword(s):