Adsorption Equilibrium and Kinetics of Copper from Aqueous Solutions on Steel Slag

2011 ◽  
Vol 354-355 ◽  
pp. 33-36
Author(s):  
Jian Yun Li ◽  
Quan Xian Hua ◽  
Jun Ling Niu ◽  
Jian Wei Tang ◽  
Ke Xu
Keyword(s):  
Aqueous Solutions ◽  
Adsorption Equilibrium ◽  
Steel Slag ◽  
Adsorption Rate ◽  
Batch Adsorption ◽  
Equilibrium And Kinetics ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Adsorption Equilibrium Data ◽  
Kinetics Of

The adsorption of copper in aqueous solutions by steel slag was studied in batch adsorption experiments. The adsorption equilibrium data fitted best with Langmuir and Freundlich equations. The adsorption was preferential type. A comparison of the kinetics models on the apparent adsorption rate showed that the adsorption system was best described by the pseudo-second-order kinetics. The adsorption rate was controlled by both liquid film diffusion and intraparticle dispersion.

scholarly journals Removal of Fluoride and Arsenate from Aqueous Solutions by Aluminum-Modified Guava Seeds

2018 ◽  
Vol 8 (10) ◽  
pp. 1807 ◽  
Author(s):  
Sarai Ramos-Vargas ◽  
Ruth Alfaro-Cuevas-Villanueva ◽  
Rafael Huirache-Acuña ◽  
Raúl Cortés-Martínez
Keyword(s):  
Aqueous Solutions ◽  
Adsorption Equilibrium ◽  
Order Model ◽  
Freundlich Model ◽  
Equilibrium Time ◽  
Fluoride Adsorption ◽  
Batch Type ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Adsorption Equilibrium Data

The contamination of groundwater by arsenic and fluoride is a major problem worldwide, causing diseases in the population that uses these waters for their consumption. Therefore, the removal of these types of pollutants from groundwater is a very important issue. In this work, the removal of arsenate and fluoride from aqueous solutions by using aluminum-modified guava seeds (Al-GSs) was evaluated. Batch-type adsorption experiments were carried out with aqueous solutions of As(V) and F− and Al-GSs. The kinetic and equilibrium parameters of adsorption were determined, as well as the effects of adsorbent dose and pH. The adsorbent was characterized by scanning electron microscopy and infrared spectroscopy in order to determine its morphology and the functional groups present in the material. The results showed that hydroxyl and carboxyl are the main groups involved in the adsorption of As(V) and F−. The fluoride adsorption kinetics indicate that the equilibrium time was reached at 150 min and it can be described by the Lagergren model, while for As(V) the equilibrium time was lower (120 min) and the kinetic data were fitted well to the pseudo-second-order model. The Langmuir-Freundlich model can describe the adsorption equilibrium data in all cases. The fluoride adsorption capacity by Al-GS was 0.3445 mg/g, and for As(V) it was 4 mg/g. It can be established that the removal of arsenates and fluoride in Al-GSs is due to chemisorption on a heterogeneous surface.

scholarly journals Adsorption isotherm and thermodynamic studies of As(III) removal from aqueous solutions using used cigarette filter ash

2019 ◽  
Vol 9 (8) ◽  
Author(s):  
Pezhman Zein Al-Salehin ◽  
Farid Moeinpour ◽  
Fatemeh S. Mohseni-Shahri
Keyword(s):  
Aqueous Solutions ◽  
Langmuir Isotherm ◽  
Adsorption Equilibrium ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Cigarette Filter ◽  
Electron Microscopy Analysis ◽  
Equilibrium Data ◽  
Thermodynamic Variables ◽  
Adsorption Equilibrium Data

Abstract In the present paper, used cigarette filter ash was prepared and used as an active adsorbent to remove As(III) ions from aqueous solutions. The prepared adsorbent structure was identified by scanning electron microscopy analysis, Brunauer–Emmett–Teller method and energy-dispersive X-ray spectroscopy analysis. The influence of contact time, pH, adsorbent dose and initial concentration of As(III) on the removal of As(III) was assessed. Several isotherm models were checked to illustrate the adsorption equilibrium. The adsorption equilibrium data adapted well with the Langmuir isotherm model. The maximum adsorption capacity of 33.33 mg/g was acquired from the Langmuir isotherm. The calculated thermodynamic variables verified that the adsorption process is spontaneous and endothermic.

Alkaline deoxygenated graphene oxide as adsorbent for cadmium ions removal from aqueous solutions

2015 ◽  
Vol 71 (11) ◽  
pp. 1611-1619 ◽  
Author(s):  
Jun Liu ◽  
Hongyan Du ◽  
Shaowei Yuan ◽  
Wanxia He ◽  
Pengju Yan ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Aqueous Solutions ◽  
Batch Adsorption ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Transmission Electron ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Ft Ir

Alkaline deoxygenated graphene oxide (aGO) was prepared through alkaline hydrothermal treatment and used as adsorbent to remove Cd(II) ions from aqueous solutions for the first time. The characterization results of transmission electron microscopy, X-ray diffraction, Raman spectroscopy, and Fourier transform infrared (FT-IR) spectra indicate that aGO was successfully synthesized. The batch adsorption experiments showed that the adsorption kinetics could be described by the pseudo-second-order kinetic model, and the isotherms equilibrium data were well fitted with the Langmuir model. The maximum adsorption capacity of Cd(II) on aGO was 156 mg/g at pH 5 and T = 293 K. The adsorption thermodynamic parameters indicated that the adsorption process was a spontaneous and endothermic reaction. The mainly adsorption mechanism speculated from FT-IR results may be attributed to the electrostatic attraction between Cd2+ and negatively charged groups (–CO−) of aGO and cation-π interaction between Cd2+ and the graphene planes. The findings of this study demonstrate the potential utility of the nanomaterial aGO as an effective adsorbent for Cd(II) removal from aqueous solutions.

Thermodynamics of Cr(VI) Adsorption on Thiourea Chelating Ion Exchange Fiber

2014 ◽  
Vol 894 ◽  
pp. 121-124 ◽  
Author(s):  
Yan Qiang Jian ◽  
Ming Yu Li ◽  
Qing Xuan Zeng
Keyword(s):  
Ion Exchange ◽  
Adsorption Process ◽  
Adsorption Equilibrium ◽  
Polypropylene Fiber ◽  
Equation Model ◽  
Batch Adsorption ◽  
Equilibrium Data ◽  
Endothermic Process ◽  
Adsorption Equilibrium Data ◽  
Ion Exchange Fiber

A chelating ion exchange fiber containing thioureido groups for the removal of Cr (VI) has been prepared from chloramethylated styrene grafted polypropylene fiber (2.96 mmol/g Cl) reacted with thiourea, batch adsorption experiments are adopted to investigate its adsorption equilibrium properties, Adsorption isotherms at various temperatures were obtained. Langmuir linear equation model can well describe the adsorption equilibrium data suggesting that the adsorption process involves both chemisorption and physisorption. The values of thermodynamic parameters, including ΔH, ΔGand ΔS, indicate that the adsorption of Cr (VI) is a spontaneous, entropy-driven and endothermic process.

Adsorption mechanism of As(V) and As(III) on Fe–Mn binary oxides in synthetic and real water matrices

2016 ◽  
Vol 16 (4) ◽  
pp. 992-1001 ◽  
Author(s):  
Jasmina Nikić ◽  
Jasmina Agbaba ◽  
Malcolm Watson ◽  
Snežana Maletić ◽  
Jelena Molnar Jazić ◽  
...  
Keyword(s):  
Adsorption Mechanism ◽  
Adsorption Equilibrium ◽  
Order Kinetic ◽  
Freundlich Isotherms ◽  
Binary Oxides ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Adsorption Equilibrium Data ◽  
The Eu

A series of Fe–Mn binary oxides with different Fe:Mn ratios (1:1, 3:1, 6:1, 9:1) were synthesized to investigate the optimal Fe:Mn ratio for the removal of As(III) and As(V). Batch experiments were performed to determine the rate of adsorption and equilibrium isotherms. Adsorption kinetics were well described by the pseudo-second-order kinetic model for both As(III) and As(V). The adsorption equilibrium data fitted well to Langmuir and Freundlich isotherms. The maximum As(V) sorption capacity was observed at an Fe:Mn ratio of 6:1 (65.0 mg/g), whereas maximum As(III) uptake was at Fe:Mn ratio 3:1 (46.9 mg/g). Arsenic levels in real water samples were reduced from 37 μg/l to below the EU Water Framework Directive limit (10 μg/L) after treatment with Fe–Mn adsorbents.

scholarly journals SYNTHESIS AND APPLICATION OF CHITOSAN/GRAPHENE OXIDE/MAGNETITE NANOSTRUCTURED COMPOSITE FOR Fe(III) REMOVAL FROM AQUEOUS SOLUTION

2018 ◽  
Vol 56 (2) ◽  
pp. 158
Author(s):  
Truong Dang Le ◽  
Hoang Vinh Tran ◽  
Le Dieu Thu ◽  
Tran Ngoc Quang ◽  
Nguyen Thi Minh Hang ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Aqueous Solutions ◽  
Metal Ion ◽  
Heavy Metal Ions ◽  
Adsorption Equilibrium ◽  
Efficient Removal ◽  
Nanostructured Composite ◽  
Equilibrium Data ◽  
Adsorption Equilibrium Data ◽  
Efficient Adsorbent

In this research, the potential of chitosan/Fe3O4/graphene oxide (CS/Fe3O4/GO) nanocomposite for efficient removal of Fe(III) a cationic metal ion from aqueous solutions was investigated. The synthesized CS/Fe3O4/GO was characterized by XRD, VSM and SEM techniques. Also, the various parameters affecting Fe3+ removal were investigated. Fe(III) adsorption equilibrium data were fitted well to the Langmuir isotherm and the maximum monolayer capacity (qmax), was calculated from the Langmuir as 6.5 mg.g-1. The results show that, CS/Fe3O4/GO nanocomposite, can be used as a cheap and efficient adsorbent for removal of heavy metal ions from aqueous solutions.

Synthesis of carboxylated chitosan and its adsorption properties for cadmium (II), lead (II) and copper (II) from aqueous solutions

2009 ◽  
Vol 60 (2) ◽  
pp. 467-474 ◽  
Author(s):  
K. L. Lv ◽  
Y. L. Du ◽  
C. M. Wang
Keyword(s):  
Aqueous Solutions ◽  
Ph Value ◽  
Order Model ◽  
Adsorption Capacities ◽  
Kinetic Rates ◽  
Experimental Parameters ◽  
Exothermic Process ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Adsorption Equilibrium Data

Carboxylated chitosan (CKCTS) was prepared for the removal of Cd(II), Pb(II), and Cu(II) from aqueous solutions. The effects of experimental parameters such as pH value, initial concentration, contact time and temperature on the adsorption were studied. From the results we can see that the adsorption capacities of Cd(II), Pb(II), and Cu(II) increase with increasing pH of the solution. The kinetic rates were best fitted to the pseudo-second-order model. The adsorption equilibrium data were fitted well with the Langmuir isotherm, which revealed that the maximum adsorption capacities for monolayer saturation of Cd(II), Pb(II), and Cu(II) were 0.555, 0.733 and 0.827 mmol/g, respectively. The adsorption was an exothermic process.

scholarly journals The Adsorption Properties ofBacillus atrophaeusSpores on Single-Wall Carbon Nanotubes

2009 ◽  
Vol 2009 ◽  
pp. 1-6 ◽  
Author(s):  
P. Cortes ◽  
S. Deng ◽  
G. B. Smith
Keyword(s):  
Carbon Nanotubes ◽  
Adsorption Equilibrium ◽  
Effective Diffusivity ◽  
Single Wall Carbon Nanotubes ◽  
Batch Adsorption ◽  
Water Supply Systems ◽  
Single Wall Carbon ◽  
Transmission Electron ◽  
Equilibrium Data ◽  
Adsorption Equilibrium Data

An adsorption equilibrium and a kinetic study ofBacillus atrophaeuson Single-Wall Carbon Nanotubes (SWCNTs) were here performed to provide the basis for developing biosensor devices for detecting threatening micro-organisms in water supply systems.B. atrophaeusspores and carbon nanotubes were subjected to a batch adsorption process to document their equilibria and kinetics. Here, commercial nanotubes were either studied as received or were acid-purified before adsorption experiments. TheBacillusspores appear to show higher affinity towards the purified nanotubes than to the as-received nanomaterial. The effective diffusivity of the spores onto the purified nanotubes was found to be approximately 30 percent higher than onto the as-received nanotubes. It seems that the removal of amorphous carbon from the as-received nanotubes through a purification process yielded an intimate nantoubes-spore interaction as revealed by transmission electron microscopy. Freundlich model successfully correlated the adsorption equilibrium data for the nanotubes-spore interaction. Transmission electron micrographs showed extensive contact between theBacillusand the purified nanotubes, but the association appeared less intimate between the spores and the as-received nanotubes.

scholarly journals Experimental investigation of titanium dioxide as an adsorbent for removal of Congo red from aqueous solution, equilibrium and kinetics modeling

2020 ◽  
Vol 10 (3) ◽  
pp. 251-266
Author(s):  
Moussa Abbas
Keyword(s):  
Titanium Dioxide ◽  
Congo Red ◽  
Active Sites ◽  
Batch Adsorption ◽  
Physical Parameters ◽  
Solution Interface ◽  
Initial Ph ◽  
Equilibrium And Kinetics ◽  
Equilibrium Data ◽  
Pseudo Second Order

Abstract The adsorption of Congo red onto titanium dioxide (TiO2) material has been investigated at batch conditions. The effects of contact time (0–60 min), initial pH (3–11), agitation speed (100–500 rpm), temperature (298–343 K), adsorbent dosage (0.5–2 g/L), and Congo red concentration (5–15 mg/L) on the Congo red adsorption by TiO2 have been studied. The kinetic parameters, rate constants, and equilibrium adsorption capacities were calculated and discussed for each kinetic model. The adsorption of Congo red onto TiO2 is well described by the pseudo-second order equation. The adsorption isotherm follows the Langmuir model, providing a better fit of the equilibrium data. The batch adsorption experiments were carried out to optimize the physical parameters on the Congo red removal efficiency. It has been found that 152 mg/g at 25 °C is removed. The thermodynamic parameters indicate the spontaneous and endothermic nature of the adsorption process with activation energy (Ea) of −64.193 kJ/mol. The positive value of the entropy (ΔS°) clearly shows that the randomness is decreased at the solid–solution interface during the Congo red adsorption onto TiO2, indicating that some structural exchange may occur among the active sites of the adsorbent and the ions.

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