scholarly journals Paleoproterozoic Iron Oxide Apatite (IOA) and Iron Oxide-Copper-Gold (IOCG) mineralization in the East Arm Basin, Northwest Territories, Canada

2020 ◽  
Vol 57 (1) ◽  
pp. 167-183
Author(s):  
E.G. Potter ◽  
L. Corriveau ◽  
B.A. Kjarsgaard
Keyword(s):  
Iron Oxide ◽  
Direct Relationship ◽  
Regional Analysis ◽  
Volcanic Rocks ◽  
Intermediate Composition ◽  
Iocg Deposits ◽  
Copper Gold ◽  
Great Bear Magmatic Zone ◽  
Host Rocks ◽  
Fault Breccia

The Paleoproterozoic East Arm Basin of Canada hosts polymetallic vein, iron oxide–apatite (IOA), and potential iron oxide–copper–gold (IOCG) mineral occurrences, mainly associated with a belt of ca. 1.87 Ga intermediate-composition sills termed the Compton intrusions. Advances in our knowledge of the East Arm Basin and of IOA and IOCG deposits within the broader context of iron oxide and alkali-calcic alteration systems enables a new regional analysis of this mineralization and facilitates comparison of these mineral occurrences and host rocks to the nearby Great Bear magmatic zone IOCG districts. The Compton intrusions and co-magmatic Pearson Formation volcanic rocks are comparable in age and composition to intrusive plus volcanic rocks of the Great Bear magmatic zone that host IOA–IOCG mineralization. Taking into account fault displacements, emplacement of Compton intrusions and Pearson Formation volcanic rocks are also consistent with the architecture of modern arcs, supporting a direct relationship with the Great Bear subduction zone. Trace element patterns of uraninite contained in IOA occurrences of the East Arm Basin are also similar to the patterns of uraninite from the Great Bear magmatic zone occurrences, consistent with both regions having experienced similar iron oxide and alkali-calcic alteration and mineralization. Our new results indicate that exploration for IOA, IOCG, and affiliated deposits in the East Arm Basin should focus on delineating increased potassic-iron alteration types and fault/breccia zones associated with these systems through field mapping and application of geochemical, radiometric, magnetic, and gravity surveys.

MAPPING THE MINERAL ZONATION AT THE ERNEST HENRY IRON OXIDE COPPER-GOLD DEPOSIT: VECTORING TO Cu-Au MINERALIZATION USING MODAL MINERALOGY

2022 ◽  
Vol 117 (2) ◽  
pp. 485-494
Author(s):  
Tobias U. Schlegel ◽  
Renee Birchall ◽  
Tina D. Shelton ◽  
James R. Austin
Keyword(s):  
Iron Oxide ◽  
Gamma Ray ◽  
Geochemical Data ◽  
Iocg Deposits ◽  
Mineral Mapping ◽  
Gamma Ray Spectrometer ◽  
Mineral Assemblages ◽  
Copper Gold ◽  
Host Rocks ◽  
Acid Alteration

Abstract Iron oxide copper-gold (IOCG) deposits form in spatial and genetic relation to hydrothermal iron oxide-alkali-calcic-hydrolytic alteration and thus show a mappable zonation of mineral assemblages toward the orebody. The mineral zonation of a breccia matrix-hosted orebody is efficiently mapped by regularly spaced samples analyzed by the scanning electron microscopy-integrated mineral analyzer technique. The method results in quantitative estimates of the mineralogy and allows the reliable recognition of characteristic alteration as well as mineralization-related mineral assemblages from detailed mineral maps. The Ernest Henry deposit is located in the Cloncurry district of Queensland and is one of Australia’s significant IOCG deposits. It is known for its association of K-feldspar altered clasts with iron oxides and chalcopyrite in the breccia matrix. Our mineral mapping approach shows that the hydrothermal alteration resulted in a characteristic zonation of minerals radiating outward from the pipe-shaped orebody. The mineral zonation is the result of a sequence of sodic alteration followed by potassic alteration, brecciation, and, finally, by hydrolytic (acid) alteration. The hydrolytic alteration primarily affected the breccia matrix and was related to economic mineralization. Alteration halos of individual minerals such as pyrite and apatite extend dozens to hundreds of meters beyond the limits of the orebody into the host rocks. Likewise, the Fe-Mg ratio in hydrothermal chlorites changes systematically with respect to their distance from the orebody. Geochemical data obtained from portable X-ray fluorescence (p-XRF) and petrophysical data acquired from a magnetic susceptibility meter and a gamma-ray spectrometer support the mineralogical data and help to accurately identify mineral halos in rocks surrounding the ore zone. Specifically, the combination of mineralogical data with multielement data such as P, Mn, As, P, and U obtained from p-XRF and positive U anomalies from radiometric measurements has potential to direct an exploration program toward higher Cu-Au grades.

scholarly journals Monazite as an Exploration Tool for Iron Oxide-Copper-Gold Mineralisation in the Gawler Craton, South Australia

Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 809
Author(s):  
Caroline Tiddy ◽  
Diana Zivak ◽  
June Hill ◽  
David Giles ◽  
Jim Hodgkison ◽  
...  
Keyword(s):  
Iron Oxide ◽  
South Australia ◽  
Intermediate Composition ◽  
Iocg Deposits ◽  
Basement Rocks ◽  
Copper Gold ◽  
Exploration Tool

The chemistry of hydrothermal monazite from the Carrapateena and Prominent Hill iron oxide-copper-gold (IOCG) deposits in the IOCG-rich Gawler Craton, South Australia, is used here to define geochemical criteria for IOCG exploration in the Gawler Craton as follows: Monazite associated with IOCG mineralisation: La + Ce > 63 wt% (where La > 22.5 wt% and Ce > 37 wt%), Y and/or Th < 1 wt% and Nd < 12.5 wt%; Intermediate composition monazite (between background and ore-related compositions): 45 wt% < La + Ce < 63 wt%, Y and/or Th < 1 wt%. Intermediate monazite compositions preserving Nd > 12.5 wt% are considered indicative of Carrapateena-style mineralisation; Background compositions: La + Ce < 45 wt% or Y or Th > 1 wt%. Mineralisation-related monazite compositions are recognised within monazite hosted within cover sequence materials that directly overly IOCG mineralisation at Carrapateena. Similar observations have been made at Prominent Hill. Recognition of these signatures within cover sequence materials demonstrates that the geochemical signatures can survive processes of weathering, erosion, transport and redeposition into younger cover sequence materials that overlie older, mineralised basement rocks. The monazite geochemical signatures therefore have the potential to be dispersed within the cover sequence, effectively increasing the geochemical footprint of mineralisation.

scholarly journals Evidence of multiple halogen sources in scapolites from iron oxide-copper-gold (IOCG) deposits and regional Na Cl metasomatic alteration, Norrbotten County, Sweden

2017 ◽  
Vol 451 ◽  
pp. 90-103 ◽  
Author(s):  
Nelson F. Bernal ◽  
Sarah A. Gleeson ◽  
Martin P. Smith ◽  
Jaime D. Barnes ◽  
Yuanming Pan
Keyword(s):  
Iron Oxide ◽  
Metasomatic Alteration ◽  
Iocg Deposits ◽  
Copper Gold

Fault reconstructions using aeromagnetic data in the Great Bear magmatic zone, Northwest Territories, Canada

2014 ◽  
Vol 51 (10) ◽  
pp. 927-942 ◽  
Author(s):  
Nathan Hayward ◽  
Louise Corriveau
Keyword(s):  
Iron Oxide ◽  
Vertical Axis ◽  
Fault System ◽  
Aeromagnetic Data ◽  
Block Rotation ◽  
Magmatic Arc ◽  
The North ◽  
Copper Gold ◽  
Great Bear Magmatic Zone ◽  
Transcurrent Faults

The Great Bear magmatic zone, located in Wopmay orogen, is a 1.875–1.84 Ga belt, 450 km long by 100 km wide of volcanic and allied plutonic rocks interpreted as a Paleoproterozoic magmatic arc. The belt, which contains economically important mineralization, was folded and subsequently cut by a swarm of northeast-striking transcurrent faults, which are part of a regional conjugate fault system interpreted to result from terminal collision of the Nahanni – Fort Simpson terrane. Fault reconstructions based on the interpretation of aeromagnetic data and geological maps provide first-order models of deformation mechanisms associated with, and the configuration of the Great Bear magmatic zone prior to, its dissection by northeast-striking transcurrent faults. The models show that vertical axis block rotation (plane strain) of ∼4.5° can explain fault offsets in the south, but that greater rotation is required to explain many of the displacements in the north. However, offsets on transcurrent faults that border the Camsell River district are greater than can be explained by vertical axis block rotation model alone and may include a component of Mesoproterozoic contractional deformation associated with the Racklan–Forward orogeny. Following reconstruction, iron oxide alkali alteration and associated mineralization, which pre-date transcurrent faulting, form a pair of northerly trending zones on the east and west margins of the belt. We suggest that these zones, whose exposure is related to broad synclinal folding of some of the oldest rocks in the Great Bear magmatic zone, are where iron oxide copper–gold (IOCG)-targeted exploration efforts should be focused on these areas in both outcrop and subcrop.

scholarly journals Silician Magnetite from the Copiapó Nordeste Prospect of Northern Chile and Its Implication for Ore-Forming Conditions of Iron Oxide–Copper–Gold Deposits

Minerals ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 529 ◽  
Author(s):  
Elías González ◽  
Shoji Kojima ◽  
Yoshihiko Ichii ◽  
Takayuki Tanaka ◽  
Yoshikazu Fujimoto ◽  
...  
Keyword(s):  
High Temperature ◽  
Iron Oxide ◽  
Gold Deposits ◽  
Northern Chile ◽  
Exchange Reactions ◽  
Iocg Deposits ◽  
X Ray ◽  
Copper Gold ◽  
High Concentrations ◽  
Substantial Factor

Silica-bearing magnetite was recognized in the Copiapó Nordeste prospect as the first documented occurrence in Chilean iron oxide–copper–gold (IOCG) deposits. The SiO2-rich magnetite termed silician magnetite occurs in early calcic to potassic alteration zones as orderly oscillatory layers in polyhedral magnetite and as isolated discrete grains, displaying perceptible optical differences in color and reflectance compared to normal magnetite. Micro-X-ray fluorescence and electron microprobe analyses reveal that silician magnetite has a significant SiO2 content with small amounts of other “impure” components, such as Al2O3, CaO, MgO, TiO2, and MnO. The oscillatory-zoned magnetite is generally enriched in SiO2 (up to 7.5 wt %) compared to the discrete grains. The formation of silician magnetite is explained by the exchange reactions between 2Fe (III) and Si (IV) + Fe (II), with the subordinate reactions between Fe (III) and Al (III) and between 2Fe (II) and Ca (II) + Mg (II). Silician magnetite with high concentrations of SiO2 (3.8–8.9 wt %) was similarly noted in intrusion-related magmatic–hydrothermal deposits including porphyry- and skarn-type deposits. This characteristic suggests that a hydrothermal system of relatively high-temperature and hypersaline fluids could be a substantial factor in the formation of silician magnetite with high SiO2 contents.

A Continuum from Iron Oxide Copper-Gold to Iron Oxide-Apatite Deposits: Evidence from Fe and O Stable Isotopes and Trace Element Chemistry of Magnetite

2020 ◽  
Vol 115 (7) ◽  
pp. 1443-1459 ◽  
Author(s):  
Maria A. Rodriguez-Mustafa ◽  
Adam C. Simon ◽  
Irene del Real ◽  
John F.H. Thompson ◽  
Laura D. Bilenker ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Stable Isotope ◽  
Trace Element ◽  
Minor Element ◽  
Open Pit ◽  
Temporal Association ◽  
Iocg Deposits ◽  
Copper Gold ◽  
Iocg Deposit ◽  
O Isotope

Abstract Iron oxide copper-gold (IOCG) and iron oxide-apatite (IOA) deposits are major sources of Fe, Cu, and Au. Magnetite is the modally dominant and commodity mineral in IOA deposits, whereas magnetite and hematite are predominant in IOCG deposits, with copper sulfides being the primary commodity minerals. It is generally accepted that IOCG deposits formed by hydrothermal processes, but there is a lack of consensus for the source of the ore fluid(s). There are multiple competing hypotheses for the formation of IOA deposits, with models that range from purely magmatic to purely hydrothermal. In the Chilean iron belt, the spatial and temporal association of IOCG and IOA deposits has led to the hypothesis that IOA and IOCG deposits are genetically connected, where S-Cu-Au–poor magnetite-dominated IOA deposits represent the stratigraphically deeper levels of S-Cu-Au–rich magnetite- and hematite-dominated IOCG deposits. Here we report minor element and Fe and O stable isotope abundances for magnetite and H stable isotope abundances for actinolite from the Candelaria IOCG deposit and Quince IOA prospect in the Chilean iron belt. Backscattered electron imaging reveals textures of igneous and magmatic-hydrothermal affinities and the exsolution of Mn-rich ilmenite from magnetite in Quince and deep levels of Candelaria (&gt;500 m below the bottom of the open pit). Trace element concentrations in magnetite systematically increase with depth in both deposits and decrease from core to rim within magnetite grains in shallow samples from Candelaria. These results are consistent with a cooling trend for magnetite growth from deep to shallow levels in both systems. Iron isotope compositions of magnetite range from δ56Fe values of 0.11 ± 0.07 to 0.16 ± 0.05‰ for Quince and between 0.16 ± 0.03 and 0.42 ± 0.04‰ for Candelaria. Oxygen isotope compositions of magnetite range from δ18O values of 2.65 ± 0.07 to 3.33 ± 0.07‰ for Quince and between 1.16 ± 0.07 and 7.80 ± 0.07‰ for Candelaria. For cogenetic actinolite, δD values range from –41.7 ± 2.10 to –39.0 ± 2.10‰ for Quince and from –93.9 ± 2.10 to –54.0 ± 2.10‰ for Candelaria, and δ18O values range between 5.89 ± 0.23 and 6.02 ± 0.23‰ for Quince and between 7.50 ± 0.23 and 7.69 ± 0.23‰ for Candelaria. The paired Fe and O isotope compositions of magnetite and the H isotope signature of actinolite fingerprint a magmatic source reservoir for ore fluids at Candelaria and Quince. Temperature estimates from O isotope thermometry and Fe# of actinolite (Fe# = [molar Fe]/([molar Fe] + [molar Mg])) are consistent with high-temperature mineralization (600°–860°C). The reintegrated composition of primary Ti-rich magnetite is consistent with igneous magnetite and supports magmatic conditions for the formation of magnetite in the Quince prospect and the deep portion of the Candelaria deposit. The trace element variations and zonation in magnetite from shallower levels of Candelaria are consistent with magnetite growth from a cooling magmatic-hydrothermal fluid. The combined chemical and textural data are consistent with a combined igneous and magmatic-hydrothermal origin for Quince and Candelaria, where the deeper portion of Candelaria corresponds to a transitional phase between the shallower IOCG deposit and a deeper IOA system analogous to the Quince IOA prospect, providing evidence for a continuum between both deposit types.

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