The volcanic and magmatic evolution of Tongariro volcano, New Zealand

<p>Detailed mapping studies of Quaternary stratovolcanoes provide critical frameworks for examining the long-term evolution of magmatic systems and volcanic behaviour. For stratovolcanoes that have experienced glaciation, edifice-forming products also act as climate-proxies from which ice thicknesses can be inferred at specific points in time. One such volcano is Tongariro, which is located in the southern Taupō Volcanic Zone of New Zealand’s North Island. This study presents the results of new detailed mapping, geochronological and geochemical investigations on edifice-forming materials to reconstruct Tongariro’s volcanic and magmatic history which address the following questions: (1) Does ice coverage on stratovolcanoes influence eruptive rates and behaviour (or record completeness)? (2) What is the relationship between magmatism, its expression (i.e. volcanism) and external but related processes such as tectonics? (3) How are intermediate-composition magmas assembled and what controls their diversity? (4) What are the relative proportions of mantle-derived and crust-derived materials in intermediate composition arc magmas? (5) Do genetic relationships exist between andesite and rhyolite magmas in arc settings? Samples from 250 new field localities in under-examined areas of Tongariro were analysed for major oxide, trace element and Sr-Nd-Pb isotope compositions. Analyses were performed on whole-rock, groundmass and xenolith samples. The stratigraphic framework for these geochemical data was established from field observations and 29 new 40Ar/39Ar age determinations, which were synthesised with volume estimates and petrographic observations for all Tongariro map units. Mapping results divide Tongariro into 36 distinct map units (at their greatest level of subdivision) which were organised into formations and constituent members. New 40Ar/39Ar age determinations reveal continuous eruptive activity at Tongariro from at least 230 ka to present, including during glacial periods. This adds to the discovery of an inlier of old basaltic-andesite (512 ± 59 ka) on Tongariro’s NW sector that has an unclear source vent. Hornblende-phyric andesite boulders, mapped into the Tupuna Formation (new), yield the oldest 40Ar/39Ar age determination (304 ± 11 ka) for materials confidently attributed to Tongariro. Tupuna Formation andesites are correlated with Turakina Formation debris flows that were deposited between 349 to 309 ka in the Wanganui Basin, ~100 km south of Tongariro, which indicates that Ruapehu did not exist at this time, at least not in its current form. Tongariro has a total edifice volume of ~90 km3, 19 km3 of which is represented by exposed mapped units. The total ringplain volume immediately adjacent to Tongariro contains ~60 km3 of material. The volume of exposed glacial deposits are no more than 1 km3. During periods of major ice coverage, edifice-building rates on Tongariro were only 17-21 % of edifice-building rates during warmer climatic periods. Because shifts in edifice-building rates do not coincide with changes in erupted compositions, differences in edifice-building rates reflect a preservation bias. Materials erupted during glacial periods were emplaced onto ice masses and conveyed to the ringplain as debris, which explains reduced preservation rates at these times. MgO concentrations in Tongariro stratigraphic units with ages between 230 and 0 ka display successive and irregular cyclicity that occurs over ~10-70 kyr intervals, which reflect episodes of enhanced mafic magma replenishment. During these cycles, more rapid (≤10 kyr) increases in MgO concentrations to ≥5-9 wt% are followed by gradual declines to ~2-5 wt%, with maxima at ~230, ~160, ~117, ~88, ~56, ~35, ~17.5 ka and during the Holocene. Contemporaneous variations in Tongariro and Ruapehu magma compositions (e.g. MgO, Rb/Sr, Sr-Nd-Pb isotope ratios) for the 200-0 ka period coincide with reported zircon growth model-ages in Taupō magmas. This contemporaneity reflects regional tectonic processes that have externally regulated and synchronised the timings of elevated mafic replenishment episodes versus periods of prolonged crustal residence at each of these volcanoes. Isotopic Sr-Nd-Pb data from metasedimentary xenoliths, groundmass separates and whole-rock samples indicate that two or three separate metasedimentary terranes (in the upper 15 km of the crust) were assimilated into Tongariro magmas. These are the Kaweka terrane and the Waipapa or Pahau terranes (or both). Subhorizontal juxtapositioning of these terranes is indicated by the coexistence of multiple terranes in the same eruptive units. Paired whole-rock and groundmass (interstitial melt) samples have effectively equal Sr-Nd-Pb isotope ratios for the complete range of Tongariro compositions. Despite intra-crystal isotopic heterogeneities that are likely widespread, the new data show that crystal fractionation and assimilation occur in approximately equal balance for essentially all Tongariro eruptives. Assimilated country rock accounts for 22-31 wt% of the average Tongariro magma. Initial evolution from a Kakuki basalt-type to a Tongariro Te Rongo Member basaltic-andesite reflects the addition of 17 % assimilated metasedimentary basement with a mass assimilation rate/mass crystal fractionation rate ratio—a.k.a. ‘r value’ of 1.8-3.5. Subsequent evolution from a Te Rongo Member basaltic-andesite to other Tongariro eruptive compositions represents 5-14 % more assimilated crust (r values of ~0.1-1.0). Magma evolution from high (>1) to lower (0.1-1.0) r values can explain the dearth of andesitic melt inclusions in (bulk) andesite magmas observed globally. High relative assimilation rates characterise rapid evolution from basalt to basaltic-andesite bulk compositions which contain andesitic interstitial melts. Thus, andesitic melt inclusions have a reduced chance of being preserved in crystals which can explain their low representation in global datasets.</p>

The volcanic and magmatic evolution of Tongariro volcano, New Zealand

<p>Detailed mapping studies of Quaternary stratovolcanoes provide critical frameworks for examining the long-term evolution of magmatic systems and volcanic behaviour. For stratovolcanoes that have experienced glaciation, edifice-forming products also act as climate-proxies from which ice thicknesses can be inferred at specific points in time. One such volcano is Tongariro, which is located in the southern Taupō Volcanic Zone of New Zealand’s North Island. This study presents the results of new detailed mapping, geochronological and geochemical investigations on edifice-forming materials to reconstruct Tongariro’s volcanic and magmatic history which address the following questions: (1) Does ice coverage on stratovolcanoes influence eruptive rates and behaviour (or record completeness)? (2) What is the relationship between magmatism, its expression (i.e. volcanism) and external but related processes such as tectonics? (3) How are intermediate-composition magmas assembled and what controls their diversity? (4) What are the relative proportions of mantle-derived and crust-derived materials in intermediate composition arc magmas? (5) Do genetic relationships exist between andesite and rhyolite magmas in arc settings? Samples from 250 new field localities in under-examined areas of Tongariro were analysed for major oxide, trace element and Sr-Nd-Pb isotope compositions. Analyses were performed on whole-rock, groundmass and xenolith samples. The stratigraphic framework for these geochemical data was established from field observations and 29 new 40Ar/39Ar age determinations, which were synthesised with volume estimates and petrographic observations for all Tongariro map units. Mapping results divide Tongariro into 36 distinct map units (at their greatest level of subdivision) which were organised into formations and constituent members. New 40Ar/39Ar age determinations reveal continuous eruptive activity at Tongariro from at least 230 ka to present, including during glacial periods. This adds to the discovery of an inlier of old basaltic-andesite (512 ± 59 ka) on Tongariro’s NW sector that has an unclear source vent. Hornblende-phyric andesite boulders, mapped into the Tupuna Formation (new), yield the oldest 40Ar/39Ar age determination (304 ± 11 ka) for materials confidently attributed to Tongariro. Tupuna Formation andesites are correlated with Turakina Formation debris flows that were deposited between 349 to 309 ka in the Wanganui Basin, ~100 km south of Tongariro, which indicates that Ruapehu did not exist at this time, at least not in its current form. Tongariro has a total edifice volume of ~90 km3, 19 km3 of which is represented by exposed mapped units. The total ringplain volume immediately adjacent to Tongariro contains ~60 km3 of material. The volume of exposed glacial deposits are no more than 1 km3. During periods of major ice coverage, edifice-building rates on Tongariro were only 17-21 % of edifice-building rates during warmer climatic periods. Because shifts in edifice-building rates do not coincide with changes in erupted compositions, differences in edifice-building rates reflect a preservation bias. Materials erupted during glacial periods were emplaced onto ice masses and conveyed to the ringplain as debris, which explains reduced preservation rates at these times. MgO concentrations in Tongariro stratigraphic units with ages between 230 and 0 ka display successive and irregular cyclicity that occurs over ~10-70 kyr intervals, which reflect episodes of enhanced mafic magma replenishment. During these cycles, more rapid (≤10 kyr) increases in MgO concentrations to ≥5-9 wt% are followed by gradual declines to ~2-5 wt%, with maxima at ~230, ~160, ~117, ~88, ~56, ~35, ~17.5 ka and during the Holocene. Contemporaneous variations in Tongariro and Ruapehu magma compositions (e.g. MgO, Rb/Sr, Sr-Nd-Pb isotope ratios) for the 200-0 ka period coincide with reported zircon growth model-ages in Taupō magmas. This contemporaneity reflects regional tectonic processes that have externally regulated and synchronised the timings of elevated mafic replenishment episodes versus periods of prolonged crustal residence at each of these volcanoes. Isotopic Sr-Nd-Pb data from metasedimentary xenoliths, groundmass separates and whole-rock samples indicate that two or three separate metasedimentary terranes (in the upper 15 km of the crust) were assimilated into Tongariro magmas. These are the Kaweka terrane and the Waipapa or Pahau terranes (or both). Subhorizontal juxtapositioning of these terranes is indicated by the coexistence of multiple terranes in the same eruptive units. Paired whole-rock and groundmass (interstitial melt) samples have effectively equal Sr-Nd-Pb isotope ratios for the complete range of Tongariro compositions. Despite intra-crystal isotopic heterogeneities that are likely widespread, the new data show that crystal fractionation and assimilation occur in approximately equal balance for essentially all Tongariro eruptives. Assimilated country rock accounts for 22-31 wt% of the average Tongariro magma. Initial evolution from a Kakuki basalt-type to a Tongariro Te Rongo Member basaltic-andesite reflects the addition of 17 % assimilated metasedimentary basement with a mass assimilation rate/mass crystal fractionation rate ratio—a.k.a. ‘r value’ of 1.8-3.5. Subsequent evolution from a Te Rongo Member basaltic-andesite to other Tongariro eruptive compositions represents 5-14 % more assimilated crust (r values of ~0.1-1.0). Magma evolution from high (>1) to lower (0.1-1.0) r values can explain the dearth of andesitic melt inclusions in (bulk) andesite magmas observed globally. High relative assimilation rates characterise rapid evolution from basalt to basaltic-andesite bulk compositions which contain andesitic interstitial melts. Thus, andesitic melt inclusions have a reduced chance of being preserved in crystals which can explain their low representation in global datasets.</p>

Max Ernst’s Woman, Old Man, and Flower (1923–24): Four Paintings in One Revealed by Technical Imaging

Examining the painting Woman, Old Man, and Flower (1923–24) by Max Ernst with macro-X-ray fluorescence scanning (MA-XRF), X-ray radiography (XRR) as well as photography under ultraviolet (UVF), infrared reflected (IRR) and transmitted (IRT) illumination revealed the existence and sequence of three distinct paintings concealed under the final composition. The study confirmed a known and previously documented intermediate composition and uncovered two additional states: a very first state exposed by XRR, and a third state revealed in the elemental distribution maps obtained by MA-XRF. The complimentary images document the insertion, mutation, and concealing of several human and anthropomorphic subjects across the four layers, expanding our understanding of the painting and of Ernst’s collage-like pictorial development. In addition, a list of pigments is proposed based on the elemental information provided by MA-XRF, contributing to the technical literature devoted to the materials of Ernst’s paintings during the transitional period between Dada and Surrealism.

Monazite as an Exploration Tool for Iron Oxide-Copper-Gold Mineralisation in the Gawler Craton, South Australia

The chemistry of hydrothermal monazite from the Carrapateena and Prominent Hill iron oxide-copper-gold (IOCG) deposits in the IOCG-rich Gawler Craton, South Australia, is used here to define geochemical criteria for IOCG exploration in the Gawler Craton as follows: Monazite associated with IOCG mineralisation: La + Ce > 63 wt% (where La > 22.5 wt% and Ce > 37 wt%), Y and/or Th < 1 wt% and Nd < 12.5 wt%; Intermediate composition monazite (between background and ore-related compositions): 45 wt% < La + Ce < 63 wt%, Y and/or Th < 1 wt%. Intermediate monazite compositions preserving Nd > 12.5 wt% are considered indicative of Carrapateena-style mineralisation; Background compositions: La + Ce < 45 wt% or Y or Th > 1 wt%. Mineralisation-related monazite compositions are recognised within monazite hosted within cover sequence materials that directly overly IOCG mineralisation at Carrapateena. Similar observations have been made at Prominent Hill. Recognition of these signatures within cover sequence materials demonstrates that the geochemical signatures can survive processes of weathering, erosion, transport and redeposition into younger cover sequence materials that overlie older, mineralised basement rocks. The monazite geochemical signatures therefore have the potential to be dispersed within the cover sequence, effectively increasing the geochemical footprint of mineralisation.

Boxite reservoirs of the Paleozoic-Mesozoic transition of the Western Siberian plate

Bauxite rocks of the pre-Jurassic complex of the Urmano- Archinskaya area of the West Siberian Plate are considered, which were formed mainly due to proluvial-deluvial-alluvial redeposition of weathering products into karst traps. The parent rocks could be volcanic rock of intermediate composition and clay deposits, drilled by wells into erosion-tectonic uplift of the basement to the north-east of the study area. The reservoir properties and alumina enrichment of study sediments are due to the leaching by hydrothermal solutions of bauxite rocks during deep-burial diagenesis.

Early Ediacaran Magmatism in the Yenisei Ridge and Evolution of the Southwestern Margin of the Siberian Craton

We present the first comprehensive data for the early Ediacaran stage of evolution of the western active continental margin of the Siberian Craton (Yenisei Ridge). U-Pb (SHRIMP-II SIMS) data for zircons from dikes of picrodolerites, quartz diorites, and leucocratic granites show that they were emplaced at 625 ± 5, 623 ± 8, and 626 ± 5 Ma, respectively, which indicates a narrow time window of Ediacaran magmatic events. The mafic tholeiitic rocks have OIB and E-MORB mantle components in their magmatic sources. Mineralogical and geochemical observations showed that the mantle-sourced mafic melts assimilated some crustal material, forming Th-enriched dikes of intermediate composition and K- and Rb-enriched felsic rocks. The possible geodynamic conditions for the formation of these early Ediacaran dikes are shown and a geodynamic model is presented for the development of the Yenisei Ridge orogen from the late Cryogenian to the late Ediacaran.

Glaciovolcanic emplacement of an intermediate hydroclastic breccia-lobe complex during the penultimate glacial period (190–130 ka), Ruapehu volcano, New Zealand

An intermediate-composition hydroclastic breccia deposit is exposed in the upper reaches of a deep glacial valley at Ruapehu volcano, New Zealand, indicating an ancient accumulation of water existed near the current summit area. Lobate intrusions within the deposit have variably fluidal and brecciated margins, and are inferred to have been intruded while the deposit was wet and unconsolidated. The tectonic setting, elevation of Ruapehu, and glacial evidence suggest that the deposit-forming eruption took place in meltwater produced from an ancient glacier. The breccia-lobe complex is inferred to have been emplaced at &gt; 154 ± 12 ka, during the penultimate glacial period (190–130 ka) when Ruapehu’s glaciers were more extensive than today. This age is based on overlying radiometrically dated lava flows, and by correlation with a well-constrained geochemical stratigraphy for Ruapehu. Field relations indicate that the glacier was at least 150 m thick, and ubiquitous quench textures and jigsaw-fit fracturing suggest that the clastic deposit was formed from non-explosive fragmentation of lava in standing water. Such features are unusual for the high flanks of a volcanic edifice where steep topography typically hinders accumulation of water or thick ice, and hence the formation and retention of hydroclastic material. Although not well-constrained for this time, the vent configuration at Ruapehu is inferred to have contributed to an irregular edifice morphology, allowing thick ice to locally accumulate and meltwater to be trapped.

Paleoproterozoic Iron Oxide Apatite (IOA) and Iron Oxide-Copper-Gold (IOCG) mineralization in the East Arm Basin, Northwest Territories, Canada

The Paleoproterozoic East Arm Basin of Canada hosts polymetallic vein, iron oxide–apatite (IOA), and potential iron oxide–copper–gold (IOCG) mineral occurrences, mainly associated with a belt of ca. 1.87 Ga intermediate-composition sills termed the Compton intrusions. Advances in our knowledge of the East Arm Basin and of IOA and IOCG deposits within the broader context of iron oxide and alkali-calcic alteration systems enables a new regional analysis of this mineralization and facilitates comparison of these mineral occurrences and host rocks to the nearby Great Bear magmatic zone IOCG districts. The Compton intrusions and co-magmatic Pearson Formation volcanic rocks are comparable in age and composition to intrusive plus volcanic rocks of the Great Bear magmatic zone that host IOA–IOCG mineralization. Taking into account fault displacements, emplacement of Compton intrusions and Pearson Formation volcanic rocks are also consistent with the architecture of modern arcs, supporting a direct relationship with the Great Bear subduction zone. Trace element patterns of uraninite contained in IOA occurrences of the East Arm Basin are also similar to the patterns of uraninite from the Great Bear magmatic zone occurrences, consistent with both regions having experienced similar iron oxide and alkali-calcic alteration and mineralization. Our new results indicate that exploration for IOA, IOCG, and affiliated deposits in the East Arm Basin should focus on delineating increased potassic-iron alteration types and fault/breccia zones associated with these systems through field mapping and application of geochemical, radiometric, magnetic, and gravity surveys.

A comparison between the stability fields of a Cl-rich scapolite and the end-member marialite

Scapolites are pervasive rock-forming aluminosilicates that are found in metamorphic, igneous, and hydrothermal environments; nonetheless, the stability field of Cl-rich scapolite is not well constrained. This experimental study investigated two reactions involving Cl-rich scapolite. First, the anhydrous reaction 1 of plagioclase + halite + calcite to form scapolite [modeled as: 3 plagioclase (Ab80An20) + 0.8 NaCl + 0.2 CaCO3 = scapolite (Ma80Me20)] was investigated to determine the effect of the Ca-rich meionite (Me = Ca4Al6Si6O24CO3) component on the Na end-member marialite (Ma = Na4Al3Si9O24Cl). Second, the effect of water on this reaction was investigated using the hydrothermally equivalent reaction 2, H2O + scapolite (Ma80Me20) = 3 plagioclase (Ab80An20) + CaCO3 + liquid, where the liquid is assumed to be a saline-rich hydrous-silicate melt. Experiments were conducted with synthetic phases over the range of 500–1030 °C and 0.4–2.0 GPa. For reaction 1, intermediate composition scapolite shows a wide thermal stability and is stable relative to plagioclase + halite + calcite at temperatures above 750 °C at 0.4 GPa and 760 °C at 2.0 GPa. For reaction 2, intermediate scapolite appears to be quite tolerant of water; it forms at a minimum bulk salinity [XNaCl = molar ratio of NaCl/(NaCl+H2O)] of the brine of approximately 0.2 XNaCl at 830 and 680 °C at pressures of 2.0 and 1.5 GPa, respectively. Based on the study done by Almeida and Jenkins (2017), pure marialite is very intolerant of water when compared to intermediate composition scapolite. Compositional changes in the scapolite and plagioclase were characterized by X-ray diffraction and electron microprobe analysis and found to shift from the nominal bulk compositions to the observed compositions of Ma85Me15 for scapolite and to Ab91An09 for plagioclase. These results were used to model the phase equilibria along the marialitemeionite join in temperature-composition space. This study demonstrates that a small change in the scapolite composition from end-member marialite to Ma85Me15 expands the stability field of marialite significantly, presumably due to the high entropy of mixing in scapolite, as well as increases its tolerance to water. This supports the much more common presence of intermediate scapolites in hydrothermal settings than either end-member meionite or marialite as is widely reported in the literature.