Examining the potential of otolith chemistry to determine natal origins of wild Lake Michigan Chinook salmon

2019 ◽  
Vol 76 (11) ◽  
pp. 2035-2044 ◽  
Author(s):  
Alexander C. Maguffee ◽  
Reneé Reilly ◽  
Richard Clark ◽  
Michael L. Jones
Keyword(s):  
Chinook Salmon ◽  
Classification Accuracy ◽  
Inductively Coupled Plasma ◽  
Lake Michigan ◽  
Oncorhynchus Tshawytscha ◽  
Regional Scale ◽  
Otolith Microchemistry ◽  
Inductively Coupled ◽  
Plasma Mass Spectrometry ◽  
Wide Scale

Previous research has demonstrated a large movement of hatchery-reared Chinook salmon (Oncorhynchus tshawytscha) from Lake Huron to Lake Michigan, suggesting the potential for wild fish to exhibit similar movement patterns. We assessed the feasibility of using otolith microchemistry to estimate the natal source composition of wild Chinook salmon in Lake Michigan and evaluate interbasin movement. Otolith pairs were extracted from juvenile and adult fish collected in 2015 and 2016 from Great Lakes tributaries. Otoliths were analyzed using laser ablation inductively coupled plasma mass spectrometry to determine trace element concentrations, and four multivariate classification algorithms were evaluated for classification accuracy. Juvenile data reclassified to their natal regions with up to 89% success on a basin level, with a random forest approach performing the best among all models. Assigning adults to their natal origins resulted in more success on a basin-wide scale (74% to 88%) compared with a regional scale (32% to 51%), but success was still below juvenile reclassification accuracy. Our findings suggest that otolith microchemistry can be used to estimate wild Chinook salmon interbasin movement and that classification accuracy can be improved by matching juvenile and adult year classes in our assessment samples. Ultimately, we intend to use these models to assess the effects of wild Chinook salmon interbasin movement on Lake Michigan predatory demand and evaluate the risks of various stocking alternatives.

scholarly journals Chemometric Analysis of Elemental Fingerprints for GE Authentication of Multiple Geographical Origins

2019 ◽  
Vol 2019 ◽  
pp. 1-7 ◽  
Author(s):  
Lu Xu ◽  
Qiong Shi ◽  
Si-Min Yan ◽  
Hai-Yan Fu ◽  
Shunping Xie ◽  
...  
Keyword(s):  
Classification Accuracy ◽  
Inductively Coupled Plasma ◽  
Chinese Herb ◽  
Mineral Elements ◽  
Gastrodia Elata ◽  
Inductively Coupled ◽  
Pattern Recognition Methods ◽  
Icp Ms ◽  
Chemical Pattern ◽  
Plasma Mass Spectrometry

The feasibility of combining elemental fingerprints and chemical pattern recognition methods for authentication of the geographical origins of a Chinese herb, Gastrodia elata BI. (GE), was studied in this paper. A total of 210 GE samples were collected from 7 different producing areas. The levels of 15 mineral elements in GE, including Zn, Cd, Co, Cr, Cu, Ca, Mg, Mn, Mo, Ni, Pb, Sr, Fe, Na, and K, were determined using inductively coupled plasma mass spectrometry (ICP-MS). Using the autoscaled data of elemental fingerprints and partial least-squares discriminant analysis (PLSDA), two chemometrics strategies for multiclass classifications, One-Versus-Rest (OVR) and One-Versus-One (OVO), were studied and compared in discrimination of GE geographical origins. As a result, OVR-PLSDA and OVO-PLSDA could achieve the classification accuracy of 0.672 and 0.925, respectively. The results indicate that mineral elemental fingerprints coupled with chemometrics can provide a useful alternative method for simultaneous discrimination of multiple GE geographical origins.

scholarly journals Development and Application of Nanoparticle-Nanopolymer Composite Spheres for the Study of Environmental Processes

2021 ◽  
Vol 3 ◽  
Author(s):  
Robert J. Rauschendorfer ◽  
Kyle M. Whitham ◽  
Star Summer ◽  
Samantha A. Patrick ◽  
Aliandra E. Pierce ◽  
...  
Keyword(s):  
Inductively Coupled Plasma ◽  
Large Scale ◽  
Analytical Techniques ◽  
Inductively Coupled ◽  
The Past ◽  
Icp Ms ◽  
Sensitivity And Selectivity ◽  
Plasma Mass Spectrometry ◽  
Wide Scale ◽  
Synthetic Copolymer

Plastics have long been an environmental contaminant of concern as both large-scale plastic debris and as micro- and nano-plastics with demonstrated wide-scale ubiquity. Research in the past decade has focused on the potential toxicological risks posed by microplastics, as well as their unique fate and transport brought on by their colloidal nature. These efforts have been slowed by the lack of analytical techniques with sufficient sensitivity and selectivity to adequately detect and characterize these contaminants in environmental and biological matrices. To improve analytical analyses, microplastic tracers are developed with recognizable isotopic, metallic, or fluorescent signatures capable of being identified amidst a complex background. Here we describe the synthesis, characterization, and application of a novel synthetic copolymer nanoplastic based on polystyrene (PS) and poly(2-vinylpyridine) (P2VP) intercalated with gold, platinum or palladium nanoparticles that can be capped with different polymeric shells meant to mimic the intended microplastic. In this work, particles with PS and polymethylmethacrylate (PMMA) shells are used to examine the behavior of microplastic particles in estuarine sediment and coastal waters. The micro- and nanoplastic tracers, with sizes between 300 and 500 nm in diameter, were characterized using multiple physical, chemical, and colloidal analysis techniques. The metallic signatures of the tracers allow for quantification by both bulk and single-particle inductively-coupled plasma mass spectrometry (ICP-MS and spICP-MS, respectively). As a demonstration of environmental applicability, the tracers were equilibrated with sediment collected from Bellingham Bay, WA, United States to determine the degree to which microplastics bind and sink in an estuary based of grain size and organic carbon parameters. In these experiments, between 80 and 95% of particles were found to associate with the sediment, demonstrative of estuaries being a major anticipated sink for these contaminants. These materials show considerable promise in their versatility, potential for multiplexing, and utility in studying micro- and nano-plastic transport in real-world environments.

Otolith microchemistry to identify sources of larval yellow perch in a fluvial lake: an approach towards freshwater fish management

2018 ◽  
Vol 75 (3) ◽  
pp. 474-487 ◽  
Author(s):  
Angélique Lazartigues ◽  
Chantale Girard ◽  
Philippe Brodeur ◽  
Frédéric Lecomte ◽  
Marc Mingelbier ◽  
...  
Keyword(s):  
Freshwater Fish ◽  
Inductively Coupled Plasma ◽  
Yellow Perch ◽  
Otolith Microchemistry ◽  
Inductively Coupled ◽  
Natal Origin ◽  
Fish Management ◽  
Plasma Mass Spectrometry ◽  
Local Recruitment ◽  
Spawning Sites

The study aims at determining which spawning sites are contributing to yellow perch (Perca flavescens) juveniles’ recruitment in Lake Saint-Pierre (St. Lawrence River, Canada). We expect to highlight new management perspectives. Thus, we investigated both natal origin and connectivity processes for young of the year prior to their first winter. Otolith chemical composition was measured at larval and juvenile stages using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Five spawning sites were sampled and discriminated using a three-elemental model (manganese, barium, strontium). Results showed that (i) all within-lake sites contributed similarly to juvenile production and (ii) production results from both local recruitment and lake-wide connectivity processes. The study suggests fish management should include an overall evaluation of the lake-wide recruitment. Both local and widespread actions are required, depending on the level of connectivity in the lake, which plays a central role in shaping the spatial pattern of recruitment. Finally, otolith microchemistry proves to be an efficient tool for freshwater fish managers to evaluate both natal origin and connectivity in heterogeneous aquatic ecosystems.

scholarly journals Till geochemical signatures associated with the Sisson W-Mo deposit, New Brunswick, Canada

2014 ◽  
Vol 50 ◽  
pp. 116 ◽  
Author(s):  
Beth McClenaghan ◽  
Allen Seaman ◽  
Michael Parkhill ◽  
Antonius Pronk
Keyword(s):  
New Brunswick ◽  
Inductively Coupled Plasma ◽  
Total Concentration ◽  
Regional Scale ◽  
Analytical Techniques ◽  
Cost Effective ◽  
Inductively Coupled ◽  
Cost Effective Method ◽  
Plasma Mass Spectrometry ◽  
Modern Analytical

 A till composition study was carried out around the Sisson W-Mo deposit, New Brunswick, Canada, one of the largest W deposits in the world, to test modern analytical methods for W in till and document glacial dispersal from a significant W source. The <0.063 mm fraction of till defines glacial dispersal down ice of the deposit and use of this fraction is recommended for W-Mo exploration in the region. Metal-rich till overlying the deposit contains up to 816 ppm W and 63 ppm Mo. One km down ice, till contains 75 ppm W and 8 ppm Mo, and till in background areas contains a maximum of 7 ppm W, and 2 ppm Mo. Indicator elements for the deposit include W and Mo, and pathfinder elements include Ag, As, Bi, Cd, Cu, In, Pb, Te, and Zn. This list of elements is more extensive than previously identified for the Sisson deposit or identified in other published till geochemical studies because of the polymetallic nature of the Sisson deposit and the broad suite of elements that can now be determined using modern analytical techniques. Lithium meta/tetraborate fusion inductively coupled plasma-mass spectrometry was used to determine the total concentration of W in till and is a fast and cost effective method as compared to those reported in the older literature. Glacial dispersal of W and Mo from the Sisson deposit is detectable at a regional scale at least 14 km down ice (southeast) using surface till sampling. A 2 km till sample spacing should be sufficient to detect glacial dispersal from a W-Mo deposit of this size. 

scholarly journals Chronological Classification of Ancient Mortars Employing Spectroscopy and Spectrometry Techniques: Sagunto (Valencia, Spain) Case

2018 ◽  
Vol 2018 ◽  
pp. 1-10 ◽  
Author(s):  
M. Ramacciotti ◽  
S. Rubio ◽  
G. Gallello ◽  
M. Lezzerini ◽  
S. Columbu ◽  
...  
Keyword(s):  
Inductively Coupled Plasma ◽  
Principal Component ◽  
Islamic Period ◽  
Inductively Coupled ◽  
Minor Elements ◽  
Imperial Period ◽  
Icp Ms ◽  
Plasma Mass Spectrometry ◽  
Wide Scale ◽  
Two Phases

Forty-two mortar samples, from two archaeological excavations located in Sagunto (Valencian Community, Spain), were analysed by both portable energy dispersive X-ray fluorescence spectroscopy (pED-XRF) and inductively coupled plasma mass spectrometry (ICP-MS) to determine major and minor elements and traces including rare earth elements (REEs). Collected data were crossed with those previously obtained from Sagunto Castle mortars, and principal component analysis (PCA) was applied to discriminate the construction phases of the unearthed buildings. REE permitted to ascribe most of the masonries to the Roman Imperial period. Moreover, a statistical model was built by employing partial least squares discriminant analysis (PLS-DA) in order to classify the mortars from Roman Imperial period and from Islamic period due to the problematic overlapping between these two phases. Results confirmed the effectiveness of the developed indirect chronology method, based on REE data, to discriminate among historic mortars from different construction periods on a wide scale including different Sagunto archaeological sites.

Metal-Organic Frameworks vs. Buffers: Case Study of UiO-66 Stability

2020 ◽  
Author(s):  
Daniel Bůžek ◽  
Slavomír Adamec ◽  
Kamil Lang ◽  
Jan Demel
Keyword(s):  
Inductively Coupled Plasma ◽  
Buffer Capacity ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Analytical Techniques ◽  
Aqueous Dispersions ◽  
Inductively Coupled ◽  
Plasma Mass Spectrometry ◽  
Metal Organic

<div><p>UiO-66 is a zirconium-based metal-organic framework (MOF) that has numerous applications. Our group recently determined that UiO-66 is not as inert in aqueous dispersions as previously reported in the literature. The present work therefore assessed the behaviour of UiO-66 in buffers: 2-amino-2-(hydroxymethyl)-1,3-propanediol (TRIS), 4-(2-hydroxyethyl)piperazine-1-ethane sulfonic acid (HEPES), N-ethylmorpholine (NEM) and phosphate buffer (PB), all of which are commonly used in many UiO-66 applications. High pressure liquid chromatography and inductively coupled plasma mass spectrometry were used to monitor degradation of the MOF. In each buffer, the terephthalate linker was released to some extent, with a more pronounced leaching effect in the saline forms of these buffers. The HEPES buffer was found to be the most benign, whereas NEM and PB should be avoided at any concentration as they were shown to rapidly degrade the UiO-66 framework. Low concentration TRIS buffers are also recommended, although these offer minimal buffer capacity to adjust pH. Regardless of the buffer used, rapid terephthalate release was observed, indicating that the UiO-66 was attacked immediately after mixing with the buffer. In addition, the dissolution of zirconium, observed in some cases, intensified the UiO-66 decomposition process. These results demonstrate that sensitive analytical techniques have to be used to monitor the release of MOF components so as to quantify the stabilities of these materials in liquid environments.</p></div>

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