Amphibole and mica 40Ar/39Ar ages from the Kaipokok and Aillik domains, Makkovik Province, Labrador: towards a characterization of back-arc processes in the Paleoproterozoic

2002 ◽  
Vol 39 (5) ◽  
pp. 749-764 ◽  
Author(s):  
Nicholas Culshaw ◽  
Peter Reynolds ◽  
Gavin Sinclair ◽  
Sandra Barr

We report amphibole and mica 40Ar/39Ar ages from the Makkovik Province. Amphibole ages from metamorphic rocks decrease towards the interior of the province, indicating a first-order pattern of monotonic cooling with progressive migration of the province into a more distal back-arc location. The amphibole data, in combination with muscovite ages, reveal a second-order pattern consisting of four stages corresponding to changing spatial and temporal configurations of plutonism and deformation. (1) The western Kaipokok domain cooled through muscovite closure by 1810 Ma, long after the cessation of arc magmatism. (2) The Kaipokok Bay shear zone, bounding the Kaipokok and Aillik domains, cooled through amphibole closure during 1805–1780 Ma, synchronous with emplacement of syn-tectonic granitoid plutons. (3) Between 1740 and 1700 Ma, greenschist-facies shearing occurred along the boundary between the Kaipokok domain and Nain Province synchronous with A-type plutonism and localized shearing in the western Kaipokok domain, cooling to muscovite closure temperatures in the Kaipokok Bay shear zone, and A-type plutonism and amphibole closure or resetting in the Aillik domain. (4) In the period 1650–1640 Ma, muscovite ages, an amphibole age from a shear zone, and resetting of plutonic amphibole indicate a thermal effect coinciding in part with Labradorian plutonism in the Aillik domain. Amphibole ages from dioritic sheets in the juvenile Aillik domain suggest emplacement between 1715 and 1685 Ma. Amphibole ages constrain crystallization of small mafic plutons in the Kaipokok domain (reworked Archean foreland) to be no younger than 1670–1660 Ma. These ages are the oldest yet obtained for Labradorian plutonism in the Makkovik Province.

Author(s):  
Stewart Shapiro

Typically, a formal language has variables that range over a collection of objects, or domain of discourse. A language is ‘second-order’ if it has, in addition, variables that range over sets, functions, properties or relations on the domain of discourse. A language is third-order if it has variables ranging over sets of sets, or functions on relations, and so on. A language is higher-order if it is at least second-order. Second-order languages enjoy a greater expressive power than first-order languages. For example, a set S of sentences is said to be categorical if any two models satisfying S are isomorphic, that is, have the same structure. There are second-order, categorical characterizations of important mathematical structures, including the natural numbers, the real numbers and Euclidean space. It is a consequence of the Löwenheim–Skolem theorems that there is no first-order categorical characterization of any infinite structure. There are also a number of central mathematical notions, such as finitude, countability, minimal closure and well-foundedness, which can be characterized with formulas of second-order languages, but cannot be characterized in first-order languages. Some philosophers argue that second-order logic is not logic. Properties and relations are too obscure for rigorous foundational study, while sets and functions are in the purview of mathematics, not logic; logic should not have an ontology of its own. Other writers disqualify second-order logic because its consequence relation is not effective – there is no recursively enumerable, sound and complete deductive system for second-order logic. The deeper issues underlying the dispute concern the goals and purposes of logical theory. If a logic is to be a calculus, an effective canon of inference, then second-order logic is beyond the pale. If, on the other hand, one aims to codify a standard to which correct reasoning must adhere, and to characterize the descriptive and communicative abilities of informal mathematical practice, then perhaps there is room for second-order logic.


Perception ◽  
10.1068/p3378 ◽  
2002 ◽  
Vol 31 (8) ◽  
pp. 1005-1011 ◽  
Author(s):  
Patrick Cavanagh ◽  
Stuart Anstis

A grid of vertical and horizontal lines, each composed of light and dark squares, is moved rigidly at 45° to the vertical on a gray surround. When the luminance of the background is set midway between the luminances of the light and dark squares, the squares appear to race along the lines even though they are actually ‘painted’ on the lines. The effect arises from the unequal apparent speeds of the lines and their textures. The light and dark squares along the lines define a first-order pattern whose apparent speed, parallel or along the line, is close to veridical. The lines themselves have no overall luminance difference from the background so that they are defined by a second-order difference. As reported elsewhere, apparent speed is reduced for second-order motion so that the motion perpendicular to the line is perceived as slower than the motion along the line even though they are physically equal. The imbalance creates the impression that the small squares are moving along the lines rather than moving rigidly with them.


1989 ◽  
Vol 164 ◽  
Author(s):  
P.M Fauchet ◽  
I.H. Campbell

AbstractRaman scattering is becoming a widely used tool for the characterization of semiconductor microcrystals due to its sensitivity to crystal sizes below a few hundred angstroms. Through detailed analysis of the first order Raman spectrum it is possible to determine the size and shape of microcrystalline grains. First order spectra must be examined with care however, since they are sensitive to other factors including: stress/strain, surface vibrations, mixed amorphous/microcrystalline phases and intragrain defects. Second order Raman spectra are more sensitive to microcrystalline effects than first order spectra. They offer the potential to measure crystal sizes greater than a few hundred angstroms but much work remains to be done to quantify the size dependence of the second order spectra.


1998 ◽  
Vol 09 (03) ◽  
pp. 277-294 ◽  
Author(s):  
HANS-JÖRG BURTSCHICK ◽  
HERIBERT VOLLMER

We introduce second-order Lindström quantifiers and examine analogies to the concept of leaf language definability. The quantifier structure in a second-order sentence defining a language and the quantifier structure in a first-order sentence characterizing the appropriate leaf language correspond to one another. Under some assumptions, leaf language definability and definability with second-order Lindström quantifiers may be seen as equivalent. Along the way we tighten the best up to now known leaf language characterization of the classes of the polynomial time hierarchy and give a new model-theoretic characterization of PSPACE.


2021 ◽  
Vol 18 (1) ◽  
pp. 71-84
Author(s):  
L Kasmi ◽  
M. Soussi. El-begrani ◽  
A. Ben Ali ◽  
M.M.M. Hajaji ◽  
S. Tazi

In the following study, we have tested Straw as a biomaterial for removing methylene blue (MB) by adsorption. The characterization of the adsorbent was carried out by scanning electron microscopy coupled with EDX (SEM), infra-red spectroscopy with Fourier transform and the point of zero charge (PZC). The studied variables are: the mass of adsorbent, the initial concentration of dye, the contact time, pH and temperature. Kinetic data were modeled by equations pseudo first order and pseudo-second order, and revealed that the adsorption of MB on the straw pseudo second order for initial dye concentration. The MB adsorption isotherms on straw were analyzed by models of Langmuir and Freundlich. The modeling of adsorption isotherms obtained good agreement with the model of Freundlich.


2020 ◽  
Vol 157 (11) ◽  
pp. 1853-1876
Author(s):  
Mohssen Moazzen ◽  
Zohreh Salimi ◽  
Yann Rolland ◽  
Michael Bröcker ◽  
Robab Hajialioghli

AbstractMetamorphic rocks associated with ophiolitic rocks occur on the eroded surface of a NW–SE-trending anticline in the Allahyarlu area, NW Iran, between the Caucasus and Zagros orogenic belts. Metapelitic rocks consist mainly of quartz, muscovite chlorite, altered biotite and garnet. S1 is the pervasive schistosity, wrapping garnet, which is folded by the second schistosity (S2). The amphibolite records only one phase of deformation as the main lineation. The rocks experienced metamorphism up to the amphibolite facies, then overprinted by greenschist facies condition. Thermobarometry indicates an average pressure of c. 5 kbar and an average temperature of c. 600 °C for the amphibolite facies metamorphism, corresponding to a ∼33 °C km−1 geothermal gradient in response to a thick magmatic arc setting. Greenschist facies metamorphism shows re-equilibration of the rocks during exhumation. Amphibolites whole rock geochemistry shows trace elements patterns similar to both island arc and back-arc basin basalts, suggesting that the protolith-forming magma of the amphibolites was enriched at shallow to medium depth of a subduction system. Negative Nb anomaly and slight enrichment in light rare earth elements (LREE) and large-ion lithophile elements (LILE) of the amphibolites indicate arc-related magmatism for their protolith and a back-arc sialic setting for their formation. 40Ar–39Ar dating on muscovite separated from two gneiss samples, and hornblende separated from three amphibolite samples, documents a Variscan (326–334 Ma) age. The magmatic and metamorphic rock association of the Allahyarlu area suggests the existence of an active continental margin arc during the Variscan orogeny, without clear evidence for a continental collision.


1997 ◽  
Vol 36 (04/05) ◽  
pp. 315-318 ◽  
Author(s):  
K. Momose ◽  
K. Komiya ◽  
A. Uchiyama

Abstract:The relationship between chromatically modulated stimuli and visual evoked potentials (VEPs) was considered. VEPs of normal subjects elicited by chromatically modulated stimuli were measured under several color adaptations, and their binary kernels were estimated. Up to the second-order, binary kernels obtained from VEPs were so characteristic that the VEP-chromatic modulation system showed second-order nonlinearity. First-order binary kernels depended on the color of the stimulus and adaptation, whereas second-order kernels showed almost no difference. This result indicates that the waveforms of first-order binary kernels reflect perceived color (hue). This supports the suggestion that kernels of VEPs include color responses, and could be used as a probe with which to examine the color visual system.


2017 ◽  
Vol 9 (3) ◽  
pp. 17-30
Author(s):  
Kelly James Clark

In Branden Thornhill-Miller and Peter Millican’s challenging and provocative essay, we hear a considerably longer, more scholarly and less melodic rendition of John Lennon’s catchy tune—without religion, or at least without first-order supernaturalisms (the kinds of religion we find in the world), there’d be significantly less intra-group violence. First-order supernaturalist beliefs, as defined by Thornhill-Miller and Peter Millican (hereafter M&M), are “beliefs that claim unique authority for some particular religious tradition in preference to all others” (3). According to M&M, first-order supernaturalist beliefs are exclusivist, dogmatic, empirically unsupported, and irrational. Moreover, again according to M&M, we have perfectly natural explanations of the causes that underlie such beliefs (they seem to conceive of such natural explanations as debunking explanations). They then make a case for second-order supernaturalism, “which maintains that the universe in general, and the religious sensitivities of humanity in particular, have been formed by supernatural powers working through natural processes” (3). Second-order supernaturalism is a kind of theism, more closely akin to deism than, say, Christianity or Buddhism. It is, as such, universal (according to contemporary psychology of religion), empirically supported (according to philosophy in the form of the Fine-Tuning Argument), and beneficial (and so justified pragmatically). With respect to its pragmatic value, second-order supernaturalism, according to M&M, gets the good(s) of religion (cooperation, trust, etc) without its bad(s) (conflict and violence). Second-order supernaturalism is thus rational (and possibly true) and inconducive to violence. In this paper, I will examine just one small but important part of M&M’s argument: the claim that (first-order) religion is a primary motivator of violence and that its elimination would eliminate or curtail a great deal of violence in the world. Imagine, they say, no religion, too.Janusz Salamon offers a friendly extension or clarification of M&M’s second-order theism, one that I think, with emendations, has promise. He argues that the core of first-order religions, the belief that Ultimate Reality is the Ultimate Good (agatheism), is rational (agreeing that their particular claims are not) and, if widely conceded and endorsed by adherents of first-order religions, would reduce conflict in the world.While I favor the virtue of intellectual humility endorsed in both papers, I will argue contra M&M that (a) belief in first-order religion is not a primary motivator of conflict and violence (and so eliminating first-order religion won’t reduce violence). Second, partly contra Salamon, who I think is half right (but not half wrong), I will argue that (b) the religious resources for compassion can and should come from within both the particular (often exclusivist) and the universal (agatheistic) aspects of religious beliefs. Finally, I will argue that (c) both are guilty, as I am, of the philosopher’s obsession with belief. 


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