scholarly journals The use of Biomaterials as Adsorbents for Removing Colorants from Aqueous Solution Case of Straw with Respect to Methylene Blue

2021 ◽  
Vol 18 (1) ◽  
pp. 71-84
Author(s):  
L Kasmi ◽  
M. Soussi. El-begrani ◽  
A. Ben Ali ◽  
M.M.M. Hajaji ◽  
S. Tazi
Keyword(s):  
Methylene Blue ◽  
Adsorption Isotherms ◽  
Second Order ◽  
Point Of Zero Charge ◽  
First Order ◽  
Infra Red ◽  
Pseudo Second Order ◽  
Modeling Of Adsorption ◽  
Good Agreement

In the following study, we have tested Straw as a biomaterial for removing methylene blue (MB) by adsorption. The characterization of the adsorbent was carried out by scanning electron microscopy coupled with EDX (SEM), infra-red spectroscopy with Fourier transform and the point of zero charge (PZC). The studied variables are: the mass of adsorbent, the initial concentration of dye, the contact time, pH and temperature. Kinetic data were modeled by equations pseudo first order and pseudo-second order, and revealed that the adsorption of MB on the straw pseudo second order for initial dye concentration. The MB adsorption isotherms on straw were analyzed by models of Langmuir and Freundlich. The modeling of adsorption isotherms obtained good agreement with the model of Freundlich.

scholarly journals Investigation into the Adsorption of Methylene Blue and Methyl Orange by UiO-66-NO2 Nanoparticles

2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Hien Thi Dinh ◽  
Nam Trung Tran ◽  
Dai Xuan Trinh
Keyword(s):  
Methylene Blue ◽  
Methyl Orange ◽  
Adsorption Capacity ◽  
Metal Organic Framework ◽  
Second Order ◽  
Mesomeric Effect ◽  
First Order ◽  
Pseudo Second Order ◽  
Pseudo First Order ◽  
Kinetics Of

In this work, the adsorptive removal of methylene blue and methyl orange by UiO-66-NO2 nanoparticles was studied. The influence of pH on the adsorption capacity was assessed. The kinetics of the adsorption process were investigated and compared with pseudo-first-order, pseudo-second-order, Elovich, and intraparticle models. The kinetics of the adsorption fits moderately with the pseudo-first-order, but perfectly fits with pseudo-second-order models, and has a very good fit with the Elovich and intraparticle models. The adsorption isotherms were measured and compared with the Langmuir and Freundlich models. The adsorption capacity of methyl orange (MO) on UiO-66-NO2 nanoparticles (142.9 mg/g) was over three times higher than that of methylene blue (MB) on the nanoparticles (41.7 mg/g). The discrepancy between these capacities was attributed to the presence of the -NO2 functional group, which caused a strong negative mesomeric effect in the metal-organic framework structure.

scholarly journals Elimination Study of Methylene Blue Dye Using PANI and PANI/SiO2 Composite.

2021 ◽  
Author(s):  
BENSEDIRA Abderrahim ◽  
HADDAOUI Nacerddine ◽  
DOUFNOUNE Rachida ◽  
MEZIANE Ouahiba ◽  
N. S. Labidi
Keyword(s):  
Methylene Blue ◽  
Adsorption Equilibrium ◽  
Dye Adsorption ◽  
Second Order ◽  
Blue Dye ◽  
Order Kinetic ◽  
Adsorption Models ◽  
First Order ◽  
Adsorption Processes ◽  
Pseudo Second Order

Abstract Conducting Polymeric composites have attracted great attention over the last years because of their potential uses in chemical, electronic and optical devices, and as catalysts as well as in adsorption processes. Chemical synthesis of polyaniline (PANI) and polyaniline-SiO2 composite and their adsorptive performance were reported in the present work. These materials were prepared and evaluated for their methylene blue (MB) dye adsorption characteristics from aqueous solution. Adsorption equilibrium kinetic and thermodynamic experiments of MB onto PANI and PANI/SiO2 were studied. The effects of initial dye concentration, contact time and temperature on the adsorption capacity of PANI/SiO2 for MB have been investigated. The pseudo-first order and pseudo-second order kinetic models were used to describe the kinetic data. It was found that adsorption kinetics followed the pseudo-second order at all of the studied temperatures. The Langmuir, Freundlich and Dubinin Raduschkevich adsorption models were used for the mathematical description and the fit obtained using the Dubinin Raduschkevich isotherm has a medium R2 value.

scholarly journals Preparation, Characterization, and Application of Metakaolin-Based Geopolymer for Removal of Methylene Blue from Aqueous Solution

2019 ◽  
Vol 2019 ◽  
pp. 1-14 ◽  
Author(s):  
Marouane El Alouani ◽  
Saliha Alehyen ◽  
Mohammed El Achouri ◽  
M’hamed Taibi
Keyword(s):  
Methylene Blue ◽  
Aqueous System ◽  
Second Order ◽  
Point Of Zero Charge ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
X Ray ◽  
Endothermic Process ◽  
Pseudo Second Order ◽  
Edx Analyses

Metakaolin-based geopolymers are aluminosilicate materials that can be used as cationic dye adsorbents in aqueous system treatment. Our aim in this paper is to study the ability of geopolymer powder produced from metakaolin and alkaline activators to act as an adsorbent to remove methylene blue (MB). The solid materials were systematically analyzed by X-ray fluorescence (XRF), X-ray diffraction (XRD), Fourier-transform infrared spectrometery (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), and the point of zero charge. XRF, FTIR, XRD, SEM, and EDX analyses confirmed the formation of a geopolymer composite by geopolymerization reaction. The influence of various experimental factors such as geopolymer dosage, pH, initial dye concentration, contact time, and temperature was assessed. Adsorption isotherms were evaluated by Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich isotherms. Kinetics data were studied using pseudo-first-order, pseudo-second-order, and intraparticle diffusion models. The thermodynamic parameters, namely, Gibbs free energy (ΔG°), enthalpy (ΔH°), and entropy (ΔS°), were determined. The results indicated that the maximum decolorization was found in high pH values. The collected isotherm data were best fitted by the Langmuir isotherm, and the maximum adsorption capacity of dye onto the geopolymer was 43.48 mg/g. The experiment kinetics followed the pseudo-second-order kinetic models. The thermodynamic results demonstrated that the adsorption of the obtained material occurs spontaneously as an endothermic process. The results confirmed that the prepared adsorbent can be used for remediation of water contaminated by MB dye.

Adsorption of methylene blue from aqueous solution onto activated carbons developed from eucalyptus bark and Crataegus oxyacantha core

2016 ◽  
Vol 74 (9) ◽  
pp. 2021-2035 ◽  
Author(s):  
Mohammad Ali Zazouli ◽  
Ali Azari ◽  
Samaneh Dehghan ◽  
Razieh Salmani Malekkolae
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Activated Carbon ◽  
Activated Carbons ◽  
Second Order ◽  
Point Of Zero Charge ◽  
Polluted Water ◽  
Order Kinetic ◽  
Pseudo Second Order ◽  
Eucalyptus Bark

In this study, eucalyptus bark and Crataegus oxyacantha core-based activated carbon were synthesized and their morphological features characterized by scanning electron microscopy and Fourier transform infrared spectroscopy techniques. The efficiency of synthesized adsorbents in removal of methylene blue (MB) from aqueous solution was investigated in a series of batch experiments. Furthermore, the influences of various experimental factors involving the contact time, the initial dye concentration, the adsorbent dosage, and the pH of the dye solution were investigated. The point of zero charge (pHpzc) of the applied adsorbents was also determined. In addition, the experimental data were expressed by Langmuir, Freundlich and Tempkin isotherms and pseudo-first order and pseudo-second order kinetic models. Adsorption equilibrium of the two adsorbents was reached within 1 h for MB concentrations of 20 to 100 mg/L. The equilibrium data obtained at optimum conditions of MB sorption by eucalyptus bark activated carbon and Crataegus oxyacantha core activated carbon were best fitted to Tempkin and Langmuir isotherm models, respectively. Besides, it was revealed that the adsorption rate follows a pseudo-second order kinetic model. From the findings of this study, it can be postulated that these adsorbents could be of great potential as a new class of adsorbents for organic dye removal from polluted water.

Kinetic and Equilibrium of Biosorption of Methylene Blue by Anaerobic Granular Sludge in Wastewater

2012 ◽  
Vol 550-553 ◽  
pp. 2291-2295
Author(s):  
Hong Ying Xu ◽  
Chan Zhang
Keyword(s):  
Methylene Blue ◽  
Granular Sludge ◽  
Second Order ◽  
Batch Adsorption ◽  
Anaerobic Granular Sludge ◽  
First Order ◽  
Freundlich Isotherms ◽  
Equilibrium Data ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order

With anaerobic granular sludge as adsorbent, the adsorption kinetics and thermodynamics of methylene blue (MB) from aqueous solution was studied by batch adsorption technique.The pseudo-first order, pseudo- second order models and Langmuir, Freundlich isotherms models were used to describe the kinetic data.The experimental results show that the anaerobic granular sludge had strong and fast speed adsorption capacity for MB adsorption in wastewater. The adsorption equilibrium could be reached in 2h, and the maximum adsorption rate was 98.6%. the pseudo-second order equation is the best model that describes the adsorption behavior.The equilibrium data were fitted to Langmuir isotherms and the equilibrium adsorption was well described by the Langmuir isotherm model. The calculation values of thermodynamic parameters present that the adsorption is spontaneous and endothermic in nature.Our results suggest the anaerobic granular sludge is a potential MB cleaner in wastewater.

Analysis of the First Order and Slowly Varying Motions of an Axisymmetric Floating Body in Bichromatic Waves

2013 ◽  
Vol 135 (1) ◽  
Author(s):  
João Pessoa ◽  
Nuno Fonseca ◽  
C. Guedes Soares
Keyword(s):  
Vertical Cylinder ◽  
Vertical Axis ◽  
Second Order ◽  
The Body ◽  
Floating Body ◽  
Drift Motion ◽  
First Order ◽  
Motion Responses ◽  
Simple Geometry ◽  
Good Agreement

The paper presents an experimental and numerical investigation on the motions of a floating body of simple geometry subjected to harmonic and biharmonic waves. The experiments were carried out in three different water depths representing shallow and deep water. The body is axisymmetric about the vertical axis, like a vertical cylinder with a rounded bottom, and it is kept in place with a soft mooring system. The experimental results include the first order motion responses, the steady drift motion offset in regular waves and the slowly varying motions due to second order interaction in biharmonic waves. The hydrodynamic problem is solved numerically with a second order boundary element method. The results show a good agreement of the numerical calculations with the experiments.

Amphibole and mica 40Ar/39Ar ages from the Kaipokok and Aillik domains, Makkovik Province, Labrador: towards a characterization of back-arc processes in the Paleoproterozoic

2002 ◽  
Vol 39 (5) ◽  
pp. 749-764 ◽  
Author(s):  
Nicholas Culshaw ◽  
Peter Reynolds ◽  
Gavin Sinclair ◽  
Sandra Barr
Keyword(s):  
Thermal Effect ◽  
Shear Zone ◽  
Second Order ◽  
Greenschist Facies ◽  
Metamorphic Rocks ◽  
Arc Magmatism ◽  
First Order ◽  
Back Arc ◽  
Order Pattern

We report amphibole and mica 40Ar/39Ar ages from the Makkovik Province. Amphibole ages from metamorphic rocks decrease towards the interior of the province, indicating a first-order pattern of monotonic cooling with progressive migration of the province into a more distal back-arc location. The amphibole data, in combination with muscovite ages, reveal a second-order pattern consisting of four stages corresponding to changing spatial and temporal configurations of plutonism and deformation. (1) The western Kaipokok domain cooled through muscovite closure by 1810 Ma, long after the cessation of arc magmatism. (2) The Kaipokok Bay shear zone, bounding the Kaipokok and Aillik domains, cooled through amphibole closure during 1805–1780 Ma, synchronous with emplacement of syn-tectonic granitoid plutons. (3) Between 1740 and 1700 Ma, greenschist-facies shearing occurred along the boundary between the Kaipokok domain and Nain Province synchronous with A-type plutonism and localized shearing in the western Kaipokok domain, cooling to muscovite closure temperatures in the Kaipokok Bay shear zone, and A-type plutonism and amphibole closure or resetting in the Aillik domain. (4) In the period 1650–1640 Ma, muscovite ages, an amphibole age from a shear zone, and resetting of plutonic amphibole indicate a thermal effect coinciding in part with Labradorian plutonism in the Aillik domain. Amphibole ages from dioritic sheets in the juvenile Aillik domain suggest emplacement between 1715 and 1685 Ma. Amphibole ages constrain crystallization of small mafic plutons in the Kaipokok domain (reworked Archean foreland) to be no younger than 1670–1660 Ma. These ages are the oldest yet obtained for Labradorian plutonism in the Makkovik Province.

scholarly journals Kinetic Study of the Bioadsorption of Methylene Blue on the Surface of the Biomass Obtained from the Algae D. antarctica

2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Jhonatan R. Guarín ◽  
Juan Carlos Moreno-Pirajan ◽  
Liliana Giraldo
Keyword(s):  
Methylene Blue ◽  
Kinetic Study ◽  
Adsorption Capacity ◽  
Scientific Community ◽  
Second Order ◽  
Maximum Adsorption Capacity ◽  
Pseudo Second Order ◽  
Best Fit ◽  
Total Elimination ◽  
Purification Of Water

Currently, there is a great pollution of water by the dyes; due to this, several studies have been carried out to remove these compounds. However, the total elimination of these pollutants from the aquatic effluents has represented a great challenge for the scientific community, for which it is necessary to carry out investigations that allow the purification of water. In this work, we studied the bioadsorption of methylene blue on the surface of the biomass obtained from the algae D. antarctica. This material was characterized by SEM and FTIR. To the data obtained in the biosorption experiments, different models of biosorption and kinetics were applied, finding that the best fit to the obtained data is given by applying the pseudo-second-order models and the Toth model, respectively. It was also determined that the maximum adsorption capacity of MB on the surface of the biomass is 702.9 mg/g, which shows that this material has great properties as a bioadsorbent.

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