The Chengwatana Volcanics, Wisconsin and Minnesota: petrogenesis of the southernmost volcanic rocks exposed in the Midcontinent rift

1997 ◽  
Vol 34 (4) ◽  
pp. 536-548 ◽  
Author(s):  
Karl R. Wirth ◽  
Zachary J. Naiman ◽  
Jeffrey D. Vervoort
Keyword(s):  
Trace Element ◽  
Volcanic Rocks ◽  
Crustal Contamination ◽  
Geothermal Gradient ◽  
Limited Range ◽  
Geochemical Data ◽  
Rift System ◽  
Midcontinent Rift ◽  
Element Abundances ◽  
Isotopic Compositions

The southernmost exposed rocks of the North American Midcontinent rift system (1100 Ma) consist of 3000 m of mafic volcanic flows and minor interflow sediment exposed along the St. Croix River in Minnesota and Wisconsin. The flows are mostly high-Fe tholeiitic basalt with plagioclase phenocrysts and ophitic to subophitic clinopyroxene. Abundant secondary chlorite, epidote, and actinolite indicate the group was metamorphosed to greenschist facies (~350 °C). Low sodium (M4 site) and tetrahedral aluminum (AlIV) contents of actinolite indicate low-pressure metamorphism (0.25 GPa) and imply a geothermal gradient of 45 – 50 °C/km. Low magnesium (Mg# = 0.37–0.58) and Ni contents (36–185 ppm) indicate the basalts have undergone significant fractionation and are not primary mantle melts. Incompatible element abundances are inversely correlated with Mg#, and most samples plot within either high or low trace element groups (e.g., Ti, P, Zr). The basalts are enriched in the light rare earth elements and Th, and are variably depleted in Ta and Nb relative to La and Th. Initial 143Nd/144Nd compositions of the group range from 0.51099 to 0.51122 (initial εNd = −4.5 to +0.1). Most flows have isotopic compositions within a relatively limited range (initial εNd = −2.5 to −1.6), but exhibit variable trace element abundances. Flows with the highest and lowest initial 143Nd/144Nd ratios have isotopic compositions that are inversely correlated with trace element abundances and ratios (e.g., La/Yb, Th/La, Th/Ta). The combined geochemical data suggest that the Chengwatana basalts originated from plume-derived melts and underwent variable fractional crystallization and crustal contamination. These melts may have interacted with lithospheric mantle enriched during Penokean subduction.

A comparison of Eastern North America and Coastal New England magma suites: implications for subcontinental mantle evolution and the broad-terrane hypothesis

2005 ◽  
Vol 42 (9) ◽  
pp. 1571-1587 ◽  
Author(s):  
Michael J Dorais ◽  
Matthew Harper ◽  
Susan Larson ◽  
Hendro Nugroho ◽  
Paul Richardson ◽  
...  
Keyword(s):  
North America ◽  
New England ◽  
Trace Element ◽  
Crustal Contamination ◽  
Flood Basalt ◽  
Incompatible Trace Element ◽  
Eastern North America ◽  
Mantle Evolution ◽  
Isotopic Compositions ◽  
Maritime Canada

New England and Maritime Canada host two major suites of Mesozoic diabase dykes. The oldest is the Coastal New England dykes that were emplaced between 225 and 230 Ma. These rocks are dominantly alkaline with trace element and isotopic compositions indicative of a high-238U/204Pb mantle (HIMU) source. The oldest of the ~200 Ma Mesozoic rift magmas is represented by the Talcott basalt of the Hartford basin and its feeder dykes. External to the basin is the compositionally equivalent Higganum dyke. The extension of the Higganum, the Onway dyke in New Hampshire, is identical in major and trace element and isotopic compositions indicating that the dyke system represented a feeder to flows of flood basalt proportions. The Talcott system rocks have some trace element similarities with arc basalts and have been interpreted as representing melts of a subduction zone modified mantle beneath the Laurentian- Gondwanan suture. Incompatible trace element ratios and Ba, Th, and U values are, however, unlike arc basalts and are more indicative of crustal contamination of the primary magma. The coastal New England magmas have oceanic island basalt signatures that are generally thought to represent plume-tail magmatism, which is antithetic to a plume-head origin for the younger eastern North America magmas. However, coastal New England rocks have the same trace element signatures as the alkaline rocks of the Loihi seamount, which represent the pre-shield stage to the voluminous tholeiitic magmatism in Hawaii.

Superposed Neoproterozoic and Silurian magmatic arcs in central Cape Breton Island, Canada: geochemical and geochronological constraints

2000 ◽  
Vol 137 (2) ◽  
pp. 137-153 ◽  
Author(s):  
J. D. KEPPIE ◽  
J. DOSTAL ◽  
R. D. DALLMEYER ◽  
R. DOIG
Keyword(s):  
New Brunswick ◽  
New England ◽  
Volcanic Rocks ◽  
Geochemical Data ◽  
Zircon Age ◽  
Cape Breton Island ◽  
Northern Margin ◽  
Element Abundances ◽  
Southern New England ◽  
Cape Breton

Isotopic and geochemical data indicate that intrusions in the eastern Creignish Hills of central Cape Breton Island, Canada represent the roots of arcs active at ∼ 540–585 Ma and ∼ 440 Ma. Times of intrusion are closely dated by (1) a nearly concordant U–Pb zircon age of 553±2 Ma in diorites of the Creignish Hills pluton; (2) a lower intercept U–Pb zircon age of 540±3 Ma that is within analytical error of 40Ar/39 Ar hornblende plateau isotope-correlation ages of 545 and 550±7 Ma in the River Denys diorite; and (3) an upper intercept U–Pb zircon age of 586±2 Ma in the Melford granitic stock. On the other hand, ∼ 441–455 Ma 40Ar/39 Ar muscovite plateau ages in the host rock adjacent to the Skye Mountain granite provide the best estimate of the time of intrusion, and are consistent with the presence of granitic dykes cutting the Skye Mountain gabbro–diorite previously dated at 438±2 Ma. All the intrusions are calc-alkaline; the Skye Mountain granite is peraluminous. Trace element abundances and Nb and Ti depletions of the intrusive rocks are characteristic of subduction-related rocks. The ∼ 540–585 Ma intrusions form part of an extensive belt running across central Cape Breton Island, and represent the youngest Neoproterozoic arc magmas in this part of Avalonia. Nearby, they are overlain by Middle Cambrian units containing rift-related volcanic rocks, which bracket the transition from convergence to extension between ∼ 540 and 505/520 Ma. This transition varies along the Avalon arc: 590 Ma in southern New England, 560–538 Ma in southern New Brunswick, and 570 Ma in eastern Newfoundland. The bi-directional diachronism in this transition is attributed to northwestward subduction of two mid-ocean ridges bordering an oceanic plate, and the migration of two ridge–trench–transform triple points. Following complete subduction of the ridges, remnant mantle upwelling along the subducted ridges produced uplift, gravitational collapse and the high-temperature/low-pressure metamorphism in the arc in both southern New Brunswick and central Cape Breton Island. The ∼ 440 Ma arc magmatism in the Creignish Hills extends through the Cape Breton Highlands and into southern Newfoundland, and has recently been attributed to northwesterly subduction along the northern margin of the Rheic Ocean.

Sr-Nd-Pb-Hf-Mg isotope geochemistry of volcanic rocks from Oldoinyo Lengai, Tanzania

2020 ◽  
Author(s):  
Sung Hi Choi ◽  
Seung Gi Jung ◽  
Kang Hyeun Ji
Keyword(s):  
Rift Valley ◽  
Source Region ◽  
Regression Line ◽  
Volcanic Rocks ◽  
Primitive Mantle ◽  
Geochemical Data ◽  
Stability Field ◽  
Crustal Material ◽  
Oldoinyo Lengai ◽  
Isotopic Compositions

<p>Oldoinyo Lengai is the only active carbonatite volcano within the East African Rift Valley in northern Tanzania. The volcano is dominated by peralkaline silicate rocks with natrocarbonatites. This study presents new mineralogical and geochemical data, including Sr–Nd–Pb–Hf–Mg isotopic compositions, for volcanic rocks at Oldoinyo Lengai and lavas from the nearby Gregory Rift Valley. The samples analyzed in this study include olivine melilitite, melanephelinite, wollastonite nephelinite, and phonolite. The olivine melilitites and melanephelinites have highly fractionated REE patterns with (La/Yb)<sub>N</sub> values of 26.4–64.9, suggesting that they formed from magmas generated by low-degree (up to ~7%) of partial melting within the garnet stability field. The wollastonite nephelinites have much higher (La/Sm)<sub>N</sub> values but lower (Sm/Yb)<sub>N</sub> values relative to typical OIB, with flat HREE patterns [(La/Yb)<sub>N</sub> = ~22]. The phonolites have elevated REE abundances but with patterns intermediate between the other two sample groups [(La/Yb)<sub>N</sub> = ~41]. All samples have primitive-mantle-normalized incompatible element patterns that are characterized by negative K and Rb anomalies but no significant Eu anomalies. They also have elevated Yb contents relative to the compositions of modeled garnet peridotite-derived melts, suggesting that they were derived from a sublithospheric source containing enriched HIMU-like recycled oceanic crustal material. However, the wollastonite nephelinites have significantly positive Ba, U, Sr, and Pb anomalies similar to those found within the Oldoinyo Lengai natrocarbonatites. The wollastonite nephelinites might have been sourced from a region of sub-continental lithospheric mantle (SCLM) that was previously metasomatized by interaction with carbonatite melts. The phonolites in the study area have also weakly positive Pb and Sr anomalies indicative of some interaction with the SCLM. All samples have d<sup>26</sup>Mg values (–0.39‰ ± 0.07‰) lighter than the composition of normal mantle material (–0.25‰ ± 0.04‰). In addition, a negative correlation between d<sup>26</sup>Mg values and MgO concentrations suggests derivation from a source region containing recycled carbonate. The samples from the study area define a mixing array between HIMU- and EM1-type OIB in Sr–Nd and Pb–Pb isotopic correlation diagrams, and have pronounced Nd–Hf isotopic decoupling, plotting below the mantle regression line in Nd–Hf isotopic space. The negative deviation from the Nd–Hf isotopic mantle array and the presence of an EM1-type mantle component in the Sr–Nd isotopic compositions of the Oldoinyo Lengai volcanic rocks can be generated by recycling of E-MORB-type oceanic crustal material with an age of 1.5–1.0 Ga.</p>

Geochemistry of two metavolcanic arc suites from the Central Metasedimentary Belt of the Grenville Province, southeastern Ontario, Canada

1991 ◽  
Vol 28 (9) ◽  
pp. 1429-1443 ◽  
Author(s):  
Luc Harnois ◽  
John M. Moore
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Trace Element ◽  
Partial Melting ◽  
Volcanic Rocks ◽  
Parental Magma ◽  
Major Elements ◽  
Grenville Province ◽  
Element Abundances ◽  
Felsic Rocks

Samples of two subalkaline metavolcanic suites, the Tudor formation (ca. 1.28 Ga) and the overlying Kashwakamak formation, have been analysed for major elements and 27 trace elements (including rare-earth elements). The Tudor formation is tholeiitic and contains mainly basaltic flows, whereas the Kashwakamak formation is calc-alkaline and contains mainly andesitic rocks with minor felsic rocks. The succession has been regionally metamorphosed to upper greenschist – lower amphibolite facies. Trace-element abundances and ratios indicate that rocks of the Tudor and Kashwakamak formations are island-arc type. Geochemical modelling using rare-earth elements, Zr, Ti, and Y indicates that the Tudor volcanic rocks are not derived from a single parental magma through simple fractional crystallization. Equilibrium partial melting of a heterogeneous Proterozoic upper mantle can explain the trace-element abundances and ratios of Tudor formation volcanic rocks. The intermediate to felsic rocks of the Kashwakamak formation appear to have been derived from a separate partial melting event. The data are consistent with an origin of the arc either on oceanic crust or on thinned continental crust, and with accretion of the arc to a continental margin between the time of extrusion of Tudor volcanic rocks and that of Kashwakamak volcanic rocks.

Mineralogical composition of and trace-element accumulation in lower Toarcian anoxic sediments: a case study from the Bilong Co. oil shale, eastern Tethys

2015 ◽  
Vol 153 (4) ◽  
pp. 618-634 ◽  
Author(s):  
XIUGEN FU ◽  
JIAN WANG ◽  
XINGLEI FENG ◽  
WENBIN CHEN ◽  
DONG WANG ◽  
...  
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Oil Shale ◽  
Volcanic Rocks ◽  
Mineralogical Composition ◽  
Geochemical Data ◽  
Anoxic Sediments ◽  
Marine Influence ◽  
High Concentrations ◽  
Element Enrichment

AbstractThe sediments of organic-rich oil shales in the Bilong Co. area can be correlated with those of the early Toarcian anoxic black-shale events in Europe. The Bilong Co. sediments are rich in trace elements Se, Mo, Cd, As and Ni, and, to a lesser extent, Li, F, V, Co, Cu, Cs, Hg and Bi, in comparison to the upper continental crust. Thirty-two oil shale samples were collected from the Bilong Co. oil shale to evaluate the controlling factors of trace-element enrichment in the lower Toarcian anoxic sediments. Minerals identified in the Bilong Co. oil shale include calcite, quartz, illite, feldspar and dolomite, and trace amounts of siderite, magnesite, halite, haematite, zeolite, amphibole, gypsum, anhydrite, apatite, pyrite, sphalerite, barite and mixed-layer illite/smectite. Mineralogical and geochemical data show that seawater and hydrothermal activities are the dominant influences on the mineralogical composition and elevated trace-element concentrations in the oil shale. The clay minerals, quartz and feldspar in the Bilong Co. oil shale were derived from the Nadi Kangri volcanic rocks. Input of sediment from this source may have led to enrichment of trace elements Li, Cr and Cs in the oil shale. Carbonate minerals and nodular- and framboidal-pyrite are authigenic phases formed from seawater. The enrichment of V, Co, Ni, Cu, Mo, As, Se, Bi and U in the oil shale was owing to marine influence. Barite, sphalerite and fracture-filling pyrites were derived from hydrothermal solutions. High concentrations of F, Zn and Cd were probably derived from hydrothermal fluids.

Geochemistry and petrogenesis of Ordovician arc-related mafic volcanic rocks in the Popelogan Inlier, northern New Brunswick

2003 ◽  
Vol 40 (9) ◽  
pp. 1171-1189 ◽  
Author(s):  
Reginald A Wilson
Keyword(s):  
Trace Element ◽  
Mantle Source ◽  
Volcanic Rocks ◽  
Type I ◽  
Type Ii ◽  
Pyroclastic Rocks ◽  
Middle Ordovician ◽  
Element Abundances ◽  
Bearing Plate ◽  
Ridge Subduction

The Popelogan Inlier consists mainly of mafic volcanic rocks (lapilli tuffs and massive to amygdaloidal, plagioclase-phyric flows) of the Middle Ordovician Goulette Brook Formation. Pyroclastic rocks include high-MgO–Cr–Ni picritic tuffs (type I) containing, in some cases, >20% MgO, and related high-MgO andesitic tuff (type II). High-MgO rocks were generated by 30–40% partial melting of an enriched mantle source; type II is descended from type I mainly by fractionation of olivine. Mafic flows comprise basaltic andesites (type III) with low trace-element abundances and strongly fractionated, trace-element-enriched andesites (type IV). Types III and IV represent ~20 and ~10% partial melts, respectively, of a mantle source similar to that of the pyroclastic rocks, based on similar ratios of high field strength elements (HFSE). Unlike types I and II, petrogenesis of mafic flows involved fractionation of plagioclase and possibly amphibole. Volcanic arc signatures include negative Nb and Ti anomalies in all basalt types, along with low abundances of HFSE. Trace-element abundances are inconsistent with prior depletion in the back arc and require involvement of a mantle plume or subcontinental lithosphere. The highly magnesian composition of the picrites demands high melting temperatures and rapid transit through the crust, both of which suggest extension of the arc-bearing plate. Compositionally similar rocks in the South Pacific are associated with unusual tectono-magmatic settings involving ridge subduction, which may have established the necessary extensional environment. It is proposed that subduction of a plume-influenced ridge segment could explain the chemistry of the Goulette Brook volcanic rocks.

Petrogenetic modelling of Quaternary post-collisional volcanism: a case study of central and eastern Anatolia

2004 ◽  
Vol 141 (1) ◽  
pp. 81-98 ◽  
Author(s):  
PINAR ALICI ŞEN ◽  
ABİDİN TEMEL ◽  
ALAIN GOURGAUD
Keyword(s):  
Trace Element ◽  
Mantle Source ◽  
Lithospheric Mantle ◽  
Volcanic Rocks ◽  
Crustal Contamination ◽  
Central Anatolia ◽  
Eastern Anatolia ◽  
Alkali Basalts ◽  
Alkaline Volcanism ◽  
Trace Elemental

Extensive continental collision-related volcanism occurred in Turkey during Neogene–Quaternary times. In central Anatolia, calc-alkaline to alkaline volcanism began in the Middle–Late Miocene. Here we report trace elemental and isotopic data from Quaternary age samples from central and eastern Anatolia. Most mafic lavas from central Anatolia are basalt and basaltic andesite, with lesser amounts of basaltic trachyandesite and andesite. All magma types exhibit enrichment in LILE (Sr, Rb, Ba and Pb) relative to HFSE (Nb, Ta). Trace element patterns are characteristic of continental margin volcanism with high Ba/Nb and Th/Nb ratios. 87Sr/86Sr and 143Nd/144Nd isotopic ratios of central Anatolian lavas range between 0.704105–0.705619 and 0.512604–0.512849, respectively. The Quaternary alkaline volcanism of eastern Anatolia has been closely linked to the collision between the Arabian and Eurasian plates. Karacadaǧ and Tendürek volcanic rocks are represented by alkali basalts and basaltic trachyandesites, respectively. As expected from their alkaline nature, they contain high abundances of LIL elements, but Tendürek lavas also show depletion in Nb and Ta, indicating the role of crustal contamination in the evolution of these magmas. 87Sr/86Sr and 143Nd/144Nd ratios of the Karacadaǧ and Tendürek lavas range from 0.703512 to 0.704466; 0.512742 to 0.512883 and 0.705743 to 0.705889 and 0.512676, respectively. Petrogenetic modelling has been used to constrain source characteristics for the central and eastern Anatolian volcanic rocks. Trace element ratio plots and REE modelling indicate that the central Anatolian volcanism was generated from a lithospheric mantle source that recorded the previous subduction events between Afro-Arabian and Eurasian plates during Eocene to Miocene times. In contrast, The Karacadaǧ alkaline basaltic volcanism on the Arabian foreland is derived from an OIB-like mantle source with limited crustal contamination. Tendürek volcanism, located on thickened crust, north of the Bitlis thrust zone, derived from the lithospheric mantle via small degrees (1.5 %) of partial melting.

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