Isotopic studies of ore-leads of the circum-Kisseynew volcanic belt of Manitoba and Saskatchewan

1978 ◽  
Vol 15 (7) ◽  
pp. 1112-1121 ◽  
Author(s):  
D. F. Sangster

Volcanic rocks, distributed to the north, west, and south of the Kisseynew gneissic belt in Manitoba and Saskatchewan, define a crescent-shaped belt herein informally referred to as the 'circum-Kisseynew volcanic belt'. Field relationships lead to the conclusion that the flanking volcanics are correlative with, and grade basinward to, greywackes and shales.Nearly 30 volcanogenic massive sulfide deposits, interpreted as coeval with their host rocks, are distributed throughout the circum-Kisseynew volcanic belt. Lead isotopic abundances in a representative number of these deposits are, apart from 204-error, relatively homogeneous in composition and model lead ages determined from these isotopic ratios fall, for the most part, between 1700 and 1900 Ma. This is regarded as good evidence that the circum-Kisseynew volcanic belt, as well as its greywacke equivalent, is largely Aphebian in age.Model lead ages for sulfide deposits from the entire circum-Kisseynew volcanic belt, with one exception, agree well with recent Rb–Sr and U–Pb age determinations from the southern portion of the belt. Reasons for the exception, in the Hanson Lake area, are discussed in some detail.

1972 ◽  
Vol 9 (5) ◽  
pp. 500-513 ◽  
Author(s):  
D. F. Sangster

Lead isotope abundances in 4 stratabound sulfide ores are presented and show characteristics of being single-stage lead deposits. Model ages based on these data range from 1780 ± 44 to 1900 ± 44 m.y. and are considered to be close approximations of the time of ore formation. Geological evidence in the massive sulfide deposits suggests they are coeval with their host rocks, which are predominantly volcanics of the Amisk Group. If this assumption is correct the average model lead age of the ores is essentially the age of the enclosing rocks. Within error limits the results are in good agreement with published Rb-Sr ages for Amisk rocks of the Flin Flon area, and with U-Pb ages in zircons of rhyolites, which also contain similar, massive sulfide ores in the Churchill Province of Arizona. This is considered to be good evidence that the Hanson Lake-Flin Flon-Snow Lake volcanic mineral belt, previously regarded as Archean, is Aphebian in part.A previously published Archean, Rb-Sr isochron for volcanic rocks in the Hanson Lake area may indicate that Amisk-type rocks are a folded complex of both Aphebian and Archean lithologies. The suggested Aphebian age of the Amisk-Missi Groups and their equivalents, indicates they are possibly eugeosynclinal equivalents of the miogeosynclinal Hurwitz sediments.


Author(s):  
Shelby Brandon Austin-Fafard ◽  
Michelle DeWolfe ◽  
Camille Partin ◽  
Bernadette Knox

Neoarchean volcanic rocks of the Beaulieu River volcanic belt structurally overlie basement rocks of the Sleepy Dragon Complex (ca. 2.85 Ga), approximately 100 km east northeast of Yellowknife. The volcanic belt is comprised of complex lithofacies, including basalt, andesite, rhyolite, and associated volcaniclastic rocks, and hosts the Sunrise volcanogenic massive sulfide deposit. The absolute age of the volcanic strata is not known, nor is the stratigraphy well-defined; therefore, the Beaulieu River volcanic belt cannot be easily correlated to other greenstone belts within the Slave craton. The main objective of this study is to document the litho- and chemo-stratigraphy of the volcanic rocks, and particularly the rhyolite dome, located at the south end  of Sunset Lake to reconstruct their volcanic and petrogenetic evolution, and determine their relationship to the volcanic strata that hosts the Sunrise VMS deposit, located ~6km to the north of the study area. Detailed mapping (1:2000) was completed over two field seasons (2018 and 2019) and shows that the volcanic rocks in the south Sunset Lake area comprise a complex stratigraphy consisting of basaltic, andesitic and rhyolitic lithofacies. This includes massive to pillow basalt and andesite, with lesser amounts of massive to in-situ brecciated, weakly quartz-plagioclase porphyritic rhyolite, heterolithic tuff to lapilli- tuff and felsic tuff to tuff breccia. The felsic clasts within the felsic volcaniclastic rocks are similar in composition to the coherent rhyolite. Units have a trace element geochemical signatures that vary from tholeiitic to calc-alkaline, arc-like rocks. Volumetrically, the volcanic strata in the south Sunset Lake area has a significant amount of volcaniclastic rocks, ranging from tuff to tuff breccia units. The volcaniclastic rocks are interpreted to have been deposited by a series of debris flows and eruption-fed density currents. The stratigraphy of the volcanic rocks in south Sunset Lake is very similar to that of the stratigraphy that hosts the Sunrise VMS deposit. Evidence of a vent proximal environment (e.g. rhyolite dome, peperite, syn-volcanic intrusions) and porous, volcanic debris accumulating on the seafloor highlight conditions favourable for volcanogenic massive sulfide-type mineralization in the south Sunset Lake area.


1991 ◽  
Vol 28 (11) ◽  
pp. 1699-1730 ◽  
Author(s):  
T. J. Barrett ◽  
W. H. MacLean ◽  
S. Cattalani ◽  
L. Hoy ◽  
G. Riverin

The Ansil massive sulfide deposit occurs at the contact of the underlying Northwest Rhyolite and the overlying Rusty Ridge Andesite, in the lower part of the Central Mine sequence of the Blake River Group. The orebody, which is roughly ellipsoidal in outline and up to 200 m × 150 m across, contained reserves of 1.58 Mt of massive sulfide grading 7.2% Cu, 0.9% Zn, 1.6 g/t Au, and 26.5 g/t Ag. Production began in 1989. Least-altered host rocks are low-K basaltic andesites and low-K rhyolites. These rocks have Zr/Y ratios of ~5 and LaN/YbN ratios of ~2.3, typical of tholeiitic volcanic rocks, although their major-element chemistry is transitional between tholeiitic and calc-alkaline volcanic rocks.The Ansil deposit, which dips ~50° east, is a single orebody comprising two main massive sulfide lenses (up to ~35 m thick) connected laterally via a thinner blanket of massive sulfides, with thin discontinuous but conformable massive magnetite units at the base and top of the orebody. Sulfide ore consists of massive to banded pyrrhotite–chalcopyrite. In the downplunge lens, up to 10 m of massive magnetite are capped by up to 10 m of massive sulfide. Finely banded cherty tuff, with sphalerite–pyrite–chalcopyrite, forms a discontinuous fringe to the deposit.The two main lenses of massive sulfide have the highest contents of Cu, Ag, and Au and are thought to have formed in areas of major hydrothermal input. Altered feeder zones contain either chlorite + chalcopyrite + pyrrhotite ± magnetite, or chlorite + magnetite ± sulfides. Footwall mineralization forms semiconformable zones ~5–10 m thick that directly underlie the orebody and high-angle pipelike zones that extend at least 50 m into the footwall. Ti–Zr–Al plots indicate that almost all altered footwall rocks were derived from a homogeneous rhyolite precursor. Hanging-wall andesites were also altered. Despite some severe alteration, all initial volcanic rock compositions can be readily identified, and thus mass changes can be calculated. Silica has been both significantly added or removed from the footwall, whereas K has been added except in feeder pipes. Oxygen-isotope compositions up to at least 50 m into the hanging wall and footwall are typically depleted in δ18O by 2–6‰. These rocks have gained Fe + Mg and lost Si. Altered samples in general range from light-rare-earth-element (REE) depleted to light-REE enriched, although some samples exhibit little REE modification despite strong alkali depletion. Mineralized volcanic rocks immediately below the orebody are enriched in Eu (as are some Cu-rich sulfides in the orebody).Contact and petrographic relations generally suggest that the main zone of massive magnetite formed by replacement of cp–po-rich sulfides, although local relations are ambiguous. Magnetite formation may reflect waning hydrothermal activity, during which fluids mixed with seawater and became cooler and more oxidized. Cu-rich feeder pipes that cut magnetite-rich footwall indicate a renewal of Cu-sulfide mineralization after magnetite deposition. Chloritic zones with disseminated sulfides occur up to a few hundred metres above the orebody, attesting to continuing hydrothermal activity.


1975 ◽  
Vol 12 (11) ◽  
pp. 1820-1849 ◽  
Author(s):  
Guy Spitz ◽  
Richard Darling

The Louvem copper deposit, a carrot-shaped body of mineralized silicic pyroclastic rock, appears generally conformable with surrounding, steeply dipping volcanic rocks, but otherwise closely resembles the cross-cutting feeder pipes that underlie many Archean stratiform volcanogenic massive sulfide deposits. It is, like many such deposits, associated with peraluminous and calc-alkaline rocks in the felsic upper portion of a volcanic sequence.Naming of the Louvem volcanic host rocks by means of their chemical composition is rendered difficult by intense local alteration which has changed their original compositions. Of the four classification schemes tried, that based on sample SiO2 content appears to provide results that are least affected by this alteration and which therefore reflect most clearly the original compositions of the rocks surrounding the ore deposit.The calc-alkaline nature of Louvem volcanic rocks is apparent even for very altered near-ore samples. This is revealed by Ol–Ne–Qz and AFM diagrams, which appear to be suitable for the genetic classification of such altered rocks.The chemical nature of the wallrock alteration in and around the deposit is revealed by certain petrologic diagrams. All rocks in the study area show magnesium enrichment, but no petrologic diagram illustrates this very clearly. Outside the orebody, the alteration consists mainly of Na and Ca depletion, and those diagrams which show such depletion are the most useful. Of these, the AKF, AFM, and ACF plots appear to be most practical.


1991 ◽  
Vol 28 (4) ◽  
pp. 465-488 ◽  
Author(s):  
T. J. Barrett ◽  
S. Cattalani ◽  
W. H. MacLean

The Horne massive sulfide deposits occur within volcanic rocks of the Blake River Group of the Archean Abitibi greenstone belt. The orebodies dip subvertically within rhyolitic flows, breccias, and tuffs that are bounded by the Andesite and the Horne Creek faults. Least-altered rhyolites have low K2O contents and other geochemical features that place them within the FII tholeiitic series. Graded volcaniclastic beds, metal zoning in the orebodies, and locations of chloritized–mineralized rhyolites indicate that the volcanic sequence youngs to the north. The volcanics in the fault wedge are variably silicified and sericitized, and local zones in the orebody sidewalls and footwall are chloritized.The H orebodies formed podiform masses up to 120 m wide, 100 m thick, and 300 m in downplunge extent, consisting of chalcopyrite–pyrrhotite–pyrite Au ore. Between 1927 and 1976, 54 × 106 t of ore were recovered, grading 2.2% Cu, 6.1 g/t Au, and 13.0 g/t Ag (Zn and Pb are &lt0.1% and <0.01%, respectively). A semicontinuous Cu-rich base (up to ~15 m thick) exists above the footwall and adjacent to the sidewalls of the orebodies. The ore changes stratigraphically upwards from a chalcopyrite-rich base, through middle pyrrhotite–pyrite-rich zones, to upper pyrite-rich zones. Au enrichments occur in some of the Cu-rich ores but also in overlying pyritic ores and in adjacent host volcanics. Cu–Au-bearing chloritized rhyolites occur mainly in the western and eastern sidewalls and at downplunge terminations of the H orebodies.The No. 5 zone occurs at lower mine levels and consists of numerous, partly overlapping Zn-bearing pyritic lenses up to 30 m thick, within mineralized rhyolitic breccias and tuffs. The No. 5 zone extends up to 750 m along strike and at least 1500 m downdip, with high-pyrite reserves of ~22 × 106 t between the 21st and 39th levels, grading 1.2% Zn, 0.15% Cu, and 1.4 g/t Au. Massive pyritic lenses are richer in Zn (> 50 ×) and Pb, Ag, As, Cd, and Sb relative to the H orebodies but are low in Cu and Au.The restored stratigraphic level of the H orebodies and No. 5 zone was dominated from south to north by rhyolite flows and breccias, then rhyolite breccias and tuffs. The volcanic rocks are interpreted as proximal to distal facies on a volcanic edifice that was affected by widespread silicification and sericitization. A graben system on the flank of the edifice became the depositional site of the H orebodies. High-temperature fluid discharge occurred along the fault-bounded graben margins, producing zones of chloritization and stringer-type Cu mineralization ± Au in rhyolites, and infilling the grabens with Cu-bearing massive sulfides. Lower on the edifice, in the No. 5 zone, Zn-bearing pyritic sulfide lenses accumulated within broader, breccia-based depressions roughly on strike with the H orebodies. Mineralization in the No. 5 zone may reflect lower temperature, more diffuse fluid discharge through a permeable sequence of volcaniclastic rocks.


Author(s):  
Peter R. Dawes ◽  
Bjørn Thomassen ◽  
T.I. Hauge Andersson

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Dawes, P. R., Thomassen, B., & Andersson, T. H. (2000). A new volcanic province: evidence from glacial erratics in western North Greenland. Geology of Greenland Survey Bulletin, 186, 35-41. https://doi.org/10.34194/ggub.v186.5213 _______________ Mapping and regional geological studies in northern Greenland were carried out during the project Kane Basin 1999 (see Dawes et al. 2000, this volume). During ore geological studies in Washington Land by one of us (B.T.), finds of erratics of banded iron formation (BIF) directed special attention to the till, glaciofluvial and fluvial sediments. This led to the discovery that in certain parts of Daugaard-Jensen Land and Washington Land volcanic rocks form a common component of the surficial deposits, with particularly colourful, red porphyries catching the eye. The presence of BIF is interesting but not altogether unexpected since BIF erratics have been reported from southern Hall Land just to the north-east (Kelly & Bennike 1992) and such rocks crop out in the Precambrian shield of North-West Greenland to the south (Fig. 1; Dawes 1991). On the other hand, the presence of volcanic erratics was unexpected and stimulated the work reported on here.


1983 ◽  
Vol 115 ◽  
pp. 49-56
Author(s):  
B Chadwick ◽  
M.A Crewe ◽  
J.F.W Park

The programme of field investigations in the north of the Ivisartoq region begun in 1981 by Chadwick & Crewe (1982) was continued in 1982. Julia Park began mapping the Taserssuaq granodiorite, its host rocks and the Ataneq fault in the north-west. Dur team was joined by D. Bellur, Geological Survey of India, nominally as an assistant. In this report we present only summary notes of new findings relevant to the interpretation of the geometry and chronology of this segment of the Archaean crust in southern West Greenland. We use the established terminology for the Archaean rocks of the Godthåbsfjord region.


Minerals ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 478
Author(s):  
Yongjun Shao ◽  
Huajie Tan ◽  
Guangxiong Peng ◽  
Jiandong Zhang ◽  
Jianzhou Chen ◽  
...  

The Xialiugou polymetallic deposit is located in the North Qilian Orogenic Belt, Northwest China, of which the main ore-bearing strata are the Middle Cambrian Heicigou Group. The mineralization is zoned with “black” orebodies (galena–sphalerite), which are stratigraphically above the “yellow” orebodies (pyrite–chalcopyrite–tennantite) at the lower zone, corresponding to the alteration assemblages of quartz–sericite in the ore-proximal zone and chlorite in the ore-distal zone. The Xialiugou mineralization can be divided into three stages: (1) Stage I (pyrite); (2) Stage II (chalcopyrite–tennantite–sphalerite); and (3) Stage III (galena–sphalerite). Fluid inclusions data indicate that the physicochemical conditions that lead to ore formation were the medium–low temperature (157–350 °C) and low salinity (0.17–6.87 wt % NaCleqv), and that the ore-forming temperature tended to decrease with the successive mineralization processes. Taking the H–O isotopic compositions (δDV-SMOW = −51.0‰ to −40.5‰, δ18OH2O = −0.4‰ to 8.6‰) into consideration, the ore-forming fluids were most likely derived from seawater with a small amount of magmatic- and meteoric-fluids input. In addition, the combined S (−3.70‰ to 0.10‰) and Pb isotopic (206Pb/204Pb = 18.357 to 18.422, 207Pb/204Pb = 15.615 to 15.687, 208Pb/204Pb = 38.056 to 38.248) data of pyrite indicate that the ore-bearing volcanic rocks may be an important source of ore-forming materials. Finally, we inferred that the Xialiugou deposit shares similarities with the most important volcanogenic massive sulfide (VMS) deposits (Baiyinchang ore field) in China and typical “black ore” type VMS deposits worldwide.


Geophysics ◽  
2012 ◽  
Vol 77 (5) ◽  
pp. WC15-WC23 ◽  
Author(s):  
Suvi Heinonen ◽  
Marcello Imaña ◽  
David B. Snyder ◽  
Ilmo T. Kukkonen ◽  
Pekka J. Heikkinen

In the Pyhäsalmi case study, the seismic data is used in direct targeting of shallowly dipping mineralized zones in a massive sulfide ore system that was deformed in complex fold interference structures under high-grade metamorphic conditions. The Pyhäsalmi volcanic-hosted massive sulfide (VHMS) deposit ([Formula: see text]) is located in a Proterozoic volcanic belt in central Finland. Acoustic impedance of Pyhäsalmi ore ([Formula: see text]) is distinct from the host rocks ([Formula: see text]), enabling its detection with seismic reflection methods. Drill-hole logging further indicates that the seismic imaging of a contact zone between mafic and felsic volcanic rocks possibly hosting additional mineralizations is plausible. Six seismic profiles showed discontinuous reflectors and complicated reflectivity patterns due to the complex geology. The most prominent reflective package at 1–2 km depth was produced by shallowly dipping contacts between interlayered felsic and mafic volcanic rocks. The topmost of these bright reflections coincides with high-grade zinc mineralization. Large acoustic impedances associated with the sulfide minerals locally enhanced the reflectivity of this topmost contact zone which could be mapped over a wide area using the seismic data. Seismic data enables extrapolation of the geologic model to where no drill-hole data exists; thus, seismic reflection profiling is an important method for defining new areas of interest for deep exploration.


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