Sulphur isotopic composition of sulphides from the Beaver Dam and other Meguma-Group-hosted gold deposits, Nova Scotia: implications for genetic models

1989 ◽  
Vol 26 (8) ◽  
pp. 1617-1629 ◽  
Author(s):  
Daniel J. Kontak ◽  
Paul K. Smith
Keyword(s):  
Nova Scotia ◽  
Gold Mineralization ◽  
Source Region ◽  
Gold Deposits ◽  
Genetic Models ◽  
Gold Deposition ◽  
Published Data ◽  
Sulphide Mineral ◽  
Beaver Dam ◽  
Wide Range

Sulphur isotopic compositions were determined for sulphide mineral phases in Meguma-Group-hosted gold deposits, Nova Scotia, in order to resolve (i) potential source regions for sulphur in these deposits, (ii) prevailing ambient physiochemical conditions during sulphide (and gold?) deposition, and (iii) possible implications of δ34S values on genetic models. The Beaver Dam deposit was selected as a test case, and results (± 1σ) from 32 sulphides analyzed for δ34S are as follows (‰): pyrite, 9.9 ± 1.1 (n = 16); pyrrhotite, 9.9 ± 0.2 (n = 4); arsenopyrite, 10.5 ± 0.4 (n = 11); and 9.4 for a single galena. The strikingly narrow range for sulphur isotope data and the sulphide mineral assemblage together are interpreted as implying that the prevailing chemical conditions during sulphide deposition remained at or below the H2S-SO4 buffer and constant relative to it, thus δ34Smineral is a good approximation of δ34Sfluid. Considering that the sulphide minerals analyzed represent a wide range in paragenesis and mode of occurrence, the uniform values suggest a homogeneous sulphur composition in the fluid, with little if any influence of local wall rocks during sulphide deposition. This is consistent with extensive alteration zones (i.e., silicification) throughout the deposit, indicating both high fluid/rock ratios and disequilibrium conditions. Data for an additional seven Meguma Group gold deposits (arsenopyrite only) indicate for δ34S a total range of about 9–25‰; however, the intradeposit variation is consistently small (2–3‰). These results are confirmed by previously published data for a variety of sulphide phases from three other deposits.Comparison of the results for Meguma-hosted deposits with a wide range of both similar and dissimilar gold deposits of variable age indicates that the large positive values (i.e., >9–10‰) are unique to the deposits examined. Two possible explanations are offered: first, the δ34S values originally may have been similar to those of other deposits (i.e., around 0‰ or slightly enriched) and then modified during transport to the site of deposition, or second, the source region of the fluids contained sulphur in an oxidized form (e.g., evaporites). The former hypothesis is currently favoured.Potential reservoirs for sulphur in the Meguma Zone include the Meguma Group metasedimentary rocks and younger peraluminous granitoid batholiths. The sulphur isotopic data are inconsistent with an unmodified magmatic source, and if the Meguma Group is favoured, then the dominant contribution was from the greywacke component. In the latter case, results for the Beaver Dam deposit may represent relatively unmodified fluid, whereas deposits characterized by enriched sulphur may reflect increasing amounts of greywacke-derived sulphur.The data somewhat constrain the possible genetic models for Meguma Group gold deposits. Syngenetic and magmatic models are considered unlikely; instead, a metamorphogenic origin is favoured. However, the ultimate source for mineralizing fluids is considered as lying beneath the Meguma Group, with variable amounts of contamination of this fluid during passage through Meguma Group strata. The relationship between gold mineralization and sulphur isotopic signatures of the associated sulphides is unclear, although a metamorphic protolith is probable.

scholarly journals Role of the Environment in the Placement of Apocarbonate Gold Mineralization Chakylkalyan Megablock (Southern Uzbekistan)

2021 ◽  
Vol 7 (6) ◽  
Author(s):  
T. Yarboboev ◽  
Sh. Sultanov ◽  
I. Ochilov
Keyword(s):  
Carbonate Rocks ◽  
Gold Mineralization ◽  
Gold Deposits ◽  
Gold Deposition ◽  
Sufficient Detail ◽  
Available Information ◽  
Gold Bearing ◽  
Geochemical Specialization

Analysis of the available information and the results of many years of research on gold deposits in Uzbekistan made it possible to identify the main unconventional types of deposits. Among them, the most interesting are apocarbonate, crustal, sulfide-carbonaceous and apovolcanogenic quartzite (Upper-Kattakashkasai ore occurrence). The apocarbonate type is widespread in Uzbekistan, has been studied in sufficient detail and information is provided on it in this article. The article examines the existence, distribution and genesis of ores of Karlin type gold deposits. The generalizing characteristics of the Karlin type gold mineralization are given. The issues of geochemical specialization of the Paleozoic strata of the Chakylkalyan megablock are considered, the most favorable stratolevel for the localization of mineralized zones is determined, and the features of carbonate rocks in the process of gold deposition during reactions with silicic solutions are characterized. Based on the materials of regional geochemical profiling, the behavior of the main ore-forming elements in the rocks of both carbonate and volcanogenic-terrigenous strata is analyzed. As a result of the analysis, subclarkic contents of the main ore-forming elements (As, Co, Ni, Pb, Cu, Ag, V, Cr, Sc) were revealed, which create increased concentrations in gold-bearing pyrites of both apocarbonate gold mineralization and related formations.

Gold mineralization in Lower Cambrian McNaughton Formation, Athabasca Pass, Canadian Rocky Mountains: structural, mineralogical, and temporal relationships

1990 ◽  
Vol 27 (4) ◽  
pp. 477-493 ◽  
Author(s):  
Robert P. Shaw ◽  
Roger D. Morton
Keyword(s):  
Rocky Mountains ◽  
Lower Cambrian ◽  
Gold Mineralization ◽  
White Mica ◽  
Gold Deposits ◽  
Process Models ◽  
Gold Deposition ◽  
Canadian Rocky Mountains ◽  
Gold Stage ◽  
Gold Bearing

Gold-bearing quartz veins were recently discovered in archimetamorphic quartzite–rudite and quartzite–pelite sequences of the Lower Cambrian McNaughton Formation in the main ranges of the central Canadian Rocky Mountains. There are two distinct vein types: an early syntectonic, syn- to postmetamorphic, auriferous, bedding-parallel type, generated during repeated northeast-directed compressive tectonism; and a late, postpenetrative deformational discordant type, which contains only minor gold (<500 ppb Au). Gold emplacement and discordant veining were confined to the onset of late compression leading to development of the Chatter Creek Fault.The spatial distribution and dimensions of the veins attest to mechanically founded lithologic anisotropy. Bedding-parallel veins are confined to less competent, volumetrically minor pelitic rock types. Discordant veins are confined to competent quartzitic units.Bedding-parallel vein filling took place in two paragenetic stages: a protracted, pre-gold stage (quartz ± minor white mica and pyrite) depositing over 90% of vein material; and a late gold-bearing–post-gold stage (quartz–pyrite–gold–galena ± white mica and Fe carbonate). Gold usually occurs in association with brecciated pelites and penecontemporaneous sulfides. Discordant veins (quartz ± minor pyrite) record a single stage of vein filling broadly coeval with gold deposition. Minor hydrothermal alteration (pyrite ± white mica ± carbonate) of adjacent wall rocks accompanied gold emplacement and is mineralogically congruent with the regional archimetamorphic and bedding-parallel vein assemblages.In terms of their setting and morphology, the Athabasca Pass gold lodes are viewed as a siliciclastic-hosted analogue of the turbidite-hosted class of gold deposits. Principle geochemical differences from published process models for turbidite-hosted gold deposits are a function of the mineralogical maturity of the siliciclastic host strata in the Athabasca Pass.

Chapter 16: Giant Carlin-Type Gold Deposits of the Cortez District, Lander and Eureka Counties, Nevada

2020 ◽  
pp. 335-353
Author(s):  
Mark A. Bradley ◽  
L. Page Anderson ◽  
Nathan Eck ◽  
Kevin D. Creel
Keyword(s):  
Great Basin ◽  
Genetic Model ◽  
Gold Mineralization ◽  
Late Eocene ◽  
Gold Deposits ◽  
Gold Deposition ◽  
Lower Paleozoic ◽  
Fine Grained ◽  
Siliciclastic Rocks ◽  
Carlin Type Gold Deposits

Abstract The Cortez district is in one of the four major Carlin-type gold deposit trends in the Great Basin province of Nevada and contains three giant (&gt;10 Moz) gold orebodies: Pipeline, Cortez Hills, and Goldrush, including the recently discovered Fourmile extension of the Goldrush deposit. The district has produced &gt;21 Moz (653 t) of gold and contains an additional 26 Moz (809 t) in reserves and resources. The Carlin-type deposits occur in two large structural windows (Gold Acres and Cortez) of Ordovician through Devonian shelf- and slope-facies carbonate rocks exposed through deformed, time-equivalent lower Paleozoic siliciclastic rocks of the overlying Roberts Mountains thrust plate. Juxtaposition of these contrasting Paleozoic strata occurred during the late Paleozoic Antler orogeny along the Roberts Mountains thrust. Both upper and lower plate sequences were further deformed by Mesozoic compressional events. Regional extension, commencing in the Eocene, opened high- and low-angle structural conduits for mineralizing solutions and resulted in gold deposition in reactive carbonate units in structural traps, including antiforms and fault-propagated folds. The Pipeline and Cortez Hills deposits are located adjacent to the Cretaceous Gold Acres and Jurassic Mill Canyon granodioritic stocks, respectively; although these stocks are genetically unrelated to the later Carlin-type mineralization event, their thermal metamorphic aureoles may have influenced ground preparation for later gold deposition. Widespread decarbonatization, argillization, and silicification of the carbonate host rocks accompanied gold mineralization, with gold precipitated within As-rich rims on fine-grained pyrite. Pipeline and Cortez Hills also display deep supergene oxidation of the hypogene sulfide mineralization. Carlin-type mineralization in the district is believed to have been initiated in the late Eocene (&gt;35 Ma) based on the age of late- to postmineral rhyolite dikes at Cortez Hills. The Carlin-type gold deposits in the district share common structural, stratigraphic, alteration, and ore mineralogic characteristics that reflect common modes of orebody formation. Ore-forming fluids were channeled along both low-angle structures (Pipeline, Goldrush/Fourmile) and high-angle features (Cortez Hills), and gold mineralization was deposited in Late Ordovician through Devonian limestone, limy mudstone, and calcareous siltstone. The Carlin-type gold fluids are interpreted to be low-salinity (2–3 wt % NaCl equiv), low-temperature (220°–270°C), and weakly acidic, analogous to those in other Carlin-type gold deposits in the Great Basin. The observed characteristics of the Cortez Carlin-type gold deposits are consistent with the recently proposed deep magmatic genetic model. Although the deposits occur over a wide geographic area in the district, it is possible that they initially formed in greater proximity to each other and were then spatially separated during Miocene and post-Miocene regional extension.

Temperature-Controlled Ore Evolution in Orogenic Gold Systems Related to Synchronous Granitic Magmatism: An Example from The Iron Quadrangle Province, Brazil

2020 ◽  
Author(s):  
Wendell Fabricio-Silva ◽  
Hartwig E. Frimmel ◽  
Maria Emília Shutesky ◽  
Carlos A. Rosière ◽  
Armando J. Massucatto
Keyword(s):  
Inductively Coupled Plasma ◽  
Gold Mineralization ◽  
Heat Engine ◽  
Gold Deposits ◽  
Orogenic Gold ◽  
Oscillatory Zoning ◽  
Granitic Magma ◽  
Iron Quadrangle ◽  
Granitic Magmatism ◽  
Wide Range

Abstract Against the background of an ongoing debate on the genetic relationship between orogenic gold and granitic magmatism, we studied the evolution of a gold-mineralizing system in shear zone-hosted veins that are spatially associated with a syn- to late tectonic 2.69 Ga granite at the Satinoco deposit in the Archean Pitangui greenstone belt (Iron Quadrangle, Brazil). Detailed underground mine mapping, petrography, laser ablation-inductively coupled plasma-mass spectrometry (LA-ICPMS), and elemental mapping of sulfide grains revealed a complex polyphase history, with at least three gold-bearing stages: (1) A syntectonic arsenopyrite (Apy1)-löllingite-pyrrhotite assemblage I that formed during prograde metamorphism from ca. 475° to 650°C at 3 to 4 kbars; (2) further fluid circulation during syn- to late tectonic retrograde metamorphism from ca. 510° to 445°C, which led to a pyrrhotite-arsenopyrite (Apy2) ± löllingite ± galena assemblage II; and (3) a pyrite-pyrrhotite-galena ± chalcopyrite ± sphalerite ± ullmannite assemblage III formed during a later post-tectonic brittle deformation event from ca. 350° to 300°C at 1 to 2 kbars. Ascending granitic magma acted as a heat engine for peak metamorphic temperatures locally, that is at the immediate contact, reaching as much as 730°C and, together with the dehydration of mafic and ultramafic host rocks, generated the sulfide assemblage I. Crosscutting field relationships, together with existing S isotope data, indicate a metamorphic origin for all the sulfide stages with a contribution from granite-derived magmatogenic fluids to the mineralizing system at stage II. New X-ray element maps together with LA-ICPMS spot analyses document oscillatory zoning of As, Fe, and Ni in Apy1 and enrichment in Ni, Mn, Zn, and V. The large amount of pyrrhotite in assemblage II is explained by granite-related Fe metasomatism. This stage led to an enrichment in Co, Sb, and Pb and the redistribution of Au. Assemblage III involved the formation of pyrite veins and precipitation of free gold and Pb-Sb-Cu-Zn sulfides in microfractures of this pyrite. This stage was likely responsible for the remobilization of Ni, Cu, Zn, and Bi-Te minerals. Based on existing geochronological data, at least most of the gold formed between ~2.72 and 2.68 Ga. This study revealed that gold mineralization took place over a wide range of temperatures—a finding that might be not only specific to the Satinoco deposit but possibly to other orogenic-type gold deposits elsewhere as well.

Contexte structural et minéralisations aurifères des gîtes Casa-Berardi, Abitibi, Québec

1990 ◽  
Vol 27 (12) ◽  
pp. 1672-1685 ◽  
Author(s):  
P. Pilote ◽  
J. Guha ◽  
R. Daigneault ◽  
F. Robert ◽  
J. P. Golightly
Keyword(s):  
Deformation Zone ◽  
Gold Mineralization ◽  
Distinct Element ◽  
Relative Length ◽  
Gold Deposits ◽  
The Other ◽  
Ductile Deformation ◽  
Gold Deposition ◽  
Lateral Extent ◽  
East West

The Casa-Berardi gold deposits are located 180 km north of Rouyn-Noranda within Archean rocks of the Abitibi Subprovince. The Casa-Berardi deformation zone (CBDZ), which contains these deposits, is an east–west trending structure that is recognized along a minimum distance of 80 km. Ductile deformation has affected the lithologies in the central portion of the CBDZ. The CBDZ juxtaposes distinct sedimentary and volcanic lithostratigraphic packages which locally display opposite facing directions. Within the CBDZ the Casa-Berardi fault has been recognized; it is a brittle structure with a reverse motion. This fault represents a distinct element associated with the progression of deformation in the CBDZ and appears late in the geodynamical evolution of this deformation zone. Two other deformation zones have been identified in this region: (i) the east–west-trending Boivin-Paradis deformation zone, which has limited lateral extent and is located at the periphery of a granitoid intrusion, and (ii) the Laberge deformation zone, which has a northwest to east–west trend and crosscuts the regional structural grain. Most of the economic gold mineralization in the Casa-Berardi deposits is found in the second set of four recognized vein and fracture sets. The mineralized veins are found within zones of intense deformation which are preferentially developed close to contacts between sedimentary and volcanic units. The geometry of the different sets of quartz veins, their relative chronology, and their respective hydrothermal alterations can be explained by the progression of deformation within the CBDZ and bracket the gold mineralization as syn- to late-tectonic. The CBDZ is distinguished from the other two deformation zones by its greater lateral extent, the juxtaposition of distinct lithological domains, the complexity of its internal fabrics, and the relative length of the deformation event. These features indicate that in contrast with the other two deformation zones, the CBDZ was the site of a major mineralizing event. The recognition of contrasting characteristics between the different deformation zones has repercussions on the understanding of the different criteria that control gold deposition and, ultimately, on gold exploration.

SULFIDE RECRYSTALLIZATION AND GOLD REMOBILIZATION DURING THE 2.0 GA STAGE OF THE MINAS OROGENY: IMPLICATIONS FOR GOLD MINERALIZATION IN THE QUADRILÁTERO FERRÍFERO AREA, BRAZIL

2021 ◽  
Author(s):  
Mariana Brando Soares ◽  
David Selby ◽  
Laurence Robb ◽  
Atlas Vasconcelos Corrêa Neto
Keyword(s):  
Thermal Effects ◽  
Gold Mineralization ◽  
Gold Deposits ◽  
Coarse Grained ◽  
Gold Deposition ◽  
Mining District ◽  
Mean Square ◽  
Fine Grained ◽  
Tectonic Events ◽  
Quadrilátero Ferrífero

Abstract The historic Quadrilátero Ferrífero mining district in Brazil is a polydeformed Archean terrane recording several tectonic events. This history has hampered the accurate dating of its important gold deposits, given that most of the geochronological clocks have been affected by multiple thermal events. To determine an accurate time constraint for the mineralizing events in this region, we provide the first Re-Os dating for a gold deposit in the Quadrilátero Ferrífero, obtained from 13 mineral separates of disseminated sulfide phases (pyrrhotite, coarse-grained arsenopyrite, fine-grained arsenopyrite, and pyrite) at the recently discovered São Sebastião deposit (northwest Quadrilátero Ferrífero). Three distinct successive sulfidation stages are interpreted at the deposit. The final stage, texturally associated with gold, is marked by fine-grained arsenopyrite and pyrite (assemblage III) and is associated with high-temperature (~600°C) features. A Re-Os errorchron is obtained when considering the data of all samples collectively; however, a comprehensive Re-Os isochron age of 1987 ± 72 Ma (2σ; n = 4; IsoplotR model 3; initial 187Os/188Os = 2.1 ± 0.7) is obtained from assemblage III. A 187Re-187Osr isochron at 1988 ± 56 Ma (mean square of weighted deviates = 0.1, initial 187Osr = –0.1 ± 2.6 ppt; n = 4) is obtained if an initial 187Os/188Os composition of ca. 2.1, is used, this being consistent with the fact that the 187Os in the sulfides in assemblage III is largely radiogenic (187Osr). Earlier assemblages (I and II) individually show variable initial 187Os/188Os, indicative of disturbance to the Re-Os systematics at ~2.0 Ga. This age is considered the best estimate for the timing of gold mineralization at São Sebastião, being coincident with the waning stages of the Minas orogeny, the thermal effects of which are restricted to the southern Quadrilátero Ferrífero. Hence, we consider that the hot fluids from which assemblage III crystallized were responsible for resetting the Re-Os systematics in assemblages I and II and were central to Paleoproterozoic gold deposition in the region. This ~2.0 Ga age challenges previous notions of a late Archean, ~2.7 Ga mineralizing event in the Quadrilátero Ferrífero and makes it possible that gold remobilization occurred elsewhere in the region, particularly in areas representing deeper crustal levels.

Studi Awal Geologi di Daerah Beruang Kanan Kabupaten Gunung Mas Propinsi Kalimantan Tengah

PROMINE ◽  
2018 ◽  
Vol 6 (1) ◽  
pp. 1-11
Author(s):  
Retno Anjarwati ◽  
Arifudin Idrus ◽  
Lucas Donny Setijadji
Keyword(s):  
Gold Mineralization ◽  
Volcanic Rocks ◽  
Gold Deposits ◽  
Central Kalimantan ◽  
Magmatic Arc ◽  
Tertiary Sediment ◽  
Copper Gold ◽  
Regional Tectonic ◽  
Mineralization Processes ◽  
High Yields

The regional tectonic conditions of the KSK Contract of Work are located in the mid-Tertiary magmatic arc (Carlile and Mitchell, 1994) which host a number of epithermal gold deposits (eg, Kelian, Indon, Muro) and significant prospects such as Muyup, Masupa Ria, Gunung Mas and Mirah. Copper-gold mineralization in the KSK Contract of Work is associated with a number of intrusions that have occupied the shallow-scale crust at the Mesozoic metamorphic intercellular junction to the south and continuously into the Lower Tertiary sediment toward the water. This intrusion is interpreted to be part of the Oligocene arc of Central Kalimantan (in Carlile and Mitchell 1994) Volcanic rocks and associated volcanoes are older than intrusions, possibly aged Cretaceous and exposed together with all three contacts (Carlile and Mitchell, 1994) some researchers contribute details about the geological and mineralogical background, and some papers for that are published for the Beruang Kanan region and beyond but no one can confirm the genesis type of the Beruang Kanan region The mineralization of the Beruang Kanan area is generally composed by high yields of epithermal sulphide mineralization. with Cu-Au mineralization This high epithermal sulphide deposition coats the upper part of the Cu-Au porphyry precipitate associated with mineralization processes that are generally controlled by the structure

It is better an approximate answer to the right question than the exact answer to the wrong question : the case of the psychometric analysis of the ASQ:SE

2020 ◽  
Author(s):  
Luis Anunciacao ◽  
janet squires ◽  
J. Landeira-Fernandez
Keyword(s):  
Internal Structure ◽  
Statistical Methods ◽  
Principal Component ◽  
Psychological Theory ◽  
Published Data ◽  
Multivariate Statistical ◽  
Exact Answer ◽  
Wide Range ◽  
Ages And Stages Questionnaire ◽  
The Right

One of the main activities in psychometrics is to analyze the internal structure of a test. Multivariate statistical methods, including Exploratory Factor analysis (EFA) and Principal Component Analysis (PCA) are frequently used to do this, but the growth of Network Analysis (NA) places this method as a promising candidate. The results obtained by these methods are of valuable interest, as they not only produce evidence to explore if the test is measuring its intended construct, but also to deal with the substantive theory that motivated the test development. However, these different statistical methods come up with different answers, providing the basis for different analytical and theoretical strategies when one needs to choose a solution. In this study, we took advantage of a large volume of published data (n = 22,331) obtained by the Ages and Stages Questionnaire Social-Emotional (ASQ:SE), and formed a subset of 500 children to present and discuss alternative psychometric solutions to its internal structure, and also to its subjacent theory. The analyses were based on a polychoric matrix, the number of factors to retain followed several well-known rules of thumb, and a wide range of exploratory methods was fitted to the data, including EFA, PCA, and NA. The statistical outcomes were divergent, varying from 1 to 6 domains, allowing a flexible interpretation of the results. We argue that the use of statistical methods in the absence of a well-grounded psychological theory has limited applications, despite its appeal. All data and codes are available at https://osf.io/z6gwv/.

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