THE SOMMERFELD MODEL AND THE HEAT OF SOLUTION OF AN ALLOY

1958 ◽  
Vol 36 (5) ◽  
pp. 611-624 ◽  
Author(s):  
W. G. Henry

An approximately self-consistent method, using a Sommerfeld model, and incorporating an approximation to the second-order perturbation energy (Lennard-Jones 1930), is used to calculate the heat of solution of both monovalent–monovalent and monovalent–polyvalent alloy systems. The heat of solution, as given by the second-order approximation, varies directly with the square of the perturbing potential, and inversely with the mean total energy of the free electrons in the solvent. Varley's (1954.) result resembles this, except that his expression varies inversely with the mean kinetic energy of the free electrons in the pure solute. The first-order approximation to the energy of the alloy system is identical, except for a change of sign, with the expression suggested by Friedel (1952, 1954) for the heat of solution. The charge accumulation about a solute site is found to vary directly with the strength of the perturbation, and inversely with the mean energy of the free electrons in the solvent. Varley obtained a comparable expression; however, his function varies inversely with the mean kinetic energy of the free electrons in the pure solute. The calculated charge accumulations in the copper–silver system, and for gold dissolved in silver, agree qualitatively with those of Arafa (1949) and Huang (1948).

2021 ◽  
Vol 37 (3) ◽  
Author(s):  
V. S. Travkin ◽  
◽  
T. V. Belonenko ◽  

Purpose. The Lofoten Basin is one of the most energetic zones of the World Ocean characterized by high activity of mesoscale eddies. The study is aimed at analyzing different components of general energy in the basin, namely the mean kinetic and vortex kinetic energy calculated using the integral of the volume of available potential and kinetic energy of the Lofoten Vortex, as well as variability of these characteristics. Methods and Results. GLORYS12V1 reanalysis data for the period 2010–2018 were used. The mean kinetic energy and the eddy kinetic one were analyzed; and as for the Lofoten Vortex, its volume available potential and kinetic energy were studied. The mesoscale activity of eddies in winter is higher than in summer. Evolution of the available potential energy and kinetic energy of the Lofoten Vortex up to the 1000 m horizon was studied. It is shown that the vortex available potential energy exceeds the kinetic one by an order of magnitude, and there is a positive trend with the coefficient 0,23⋅1015 J/year. It was found that in the Lofoten Basin, the intermediate layer from 600 to 900 m made the largest contribution to the potential energy, whereas the 0–400 m layer – to kinetic energy. The conversion rates of the mean kinetic energy into the vortex kinetic one and the mean available potential energy into the vortex available potential one (barotropic and baroclinic instability) were analyzed. It is shown that the first type of transformation dominates in summer, while the second one is characterized by its increase in winter. Conclusions. The vertical profile shows that the kinetic energy of eddies in winter is higher than in summer. The available potential energy of a vortex is by an order of magnitude greater than the kinetic energy. An increase in the available potential energy is confirmed by a significant positive trend and by a decrease in the vortex Burger number. The graphs of the barotropic instability conversion rate demonstrate the multidirectional flows in the vortex zone with the dipole structure observed in a winter period, and the tripole one – in summer. The barotropic instability highest intensity is observed in summer. The baroclinic instability is characterized by intensification of the regime in winter that is associated with weakening of stratification in this period owing to winter convection.


1963 ◽  
Vol 15 (5) ◽  
pp. 1177-1178 ◽  
Author(s):  
V. N. Okolovich ◽  
V. I. Bol'shov ◽  
L. D. Gordeeva ◽  
G. N. Smirenkin

2020 ◽  
Author(s):  
João Bettencourt ◽  
Carlos Guedes Soares

<p>The Azores Current-Front system coincides with the northern limit of the subtropical gyre in  the Eastern North Atlantic. The mean zonal jet is positioned south of the Azores archipelago  and extends from west of the mid-atlantic ridge to the Gulf of Cadiz, where it partially  turns south. North of the main jet, a sub-surface counter-current is found, flowing westwards. The associated thermal front separates the warm subtropical waters from the colder subpolar waters. The instantaneous flow in the Azores Current/Front system is characterized by the presence of meandering currents with length scales of 200 km that regularly shed anticyclonic warm water and cyclonic cold water eddies to the north and south of the mean jet axis, respectively, due to vortex stretching and the planetary beta effect. The time scale of eddy shedding is 100-200 days. On the meandering arms of the current, downwelling <br>and upwelling cells are found and sharp thermal gradients are formed and a residual poleward heat transport is observed. The instability cycle that originates the mesoscale meanders and the eddies is well-known from quasi-geostrophic and primitive equation models initialized from a basic baroclinic state: a first phase of baroclinic instability feeds on available potential energy to raise eddy kinetic energy levels, that, in a second phase feed the mean kinetic energy by Reynolds stress convergence. The cycle repeats itself as long as the APE reservoir is filled at the end of each cycle.</p><p>However, seasonal variability of the zonal jet dynamics has not been addressed before and it can provide valuable insights in to the variations of the Eastern North Atlantic between the subtropical and subpolar gyres. We use a primitive equation regional ocean model of the Eastern Central North Atlantic with realistic climatological wind and thermal forcing to study the yearly cycle of meandering, eddy shedding and restoration of the mean jet in the Azores/Current system. We observe an semi-annual cycle in the jet's kinetic energy with maxima in Summer/Winter and minima in early Spring/Autumn. Potential energy conversion by baroclinic instability occurs throughout the year but is predominant in the first half of the year. The mean kinetic energy draws from the turbulent kinetic energy through Reynolds stress convergence in periods of 50 - 100 days, that are followed by short barotropic instability periods. During Winter, Reynolds stress convergence, and thus mean jet reinforcement from the mesoscale eddy field, occurs along the jet meridional extent, in the top 500 m of the water column, but from Spring to Autumn it is observed only in the southern flank of the mean jet axis.</p>


2011 ◽  
Vol 68 (4) ◽  
pp. 863-877 ◽  
Author(s):  
Toshiki Iwasaki ◽  
Chihiro Kodama

Abstract The growth rate of baroclinic instability waves is generalized in terms of wave–mean flow interactions, with an emphasis on the influence of the vertical profile of baroclinicity. The wave energy is converted from the zonal mean kinetic energy and the growth rate is proportional to the mean zonal flow difference between the Eliassen–Palm (E-P) flux convergence and divergence areas. Mass-weighted isentropic zonal means facilitate the expression of the lower boundary conditions for the mass streamfunctions and E-P flux. For Eady waves, intersections of isentropes with lower/upper boundaries induce the E-P flux divergence/convergence. The growth rate is proportional to the mean zonal flow difference between the two boundaries, indicating that baroclinicity at each level contributes evenly to the instability. The reduced zonal mean kinetic energy is compensated by a conversion from the zonal mean available potential energy. Aquaplanet experiments are carried out to investigate the actual characteristics of baroclinic instability waves. The wave activity is shown to be sensitive to the upper-tropospheric baroclinicity, though it may be most sensitive to baroclinicity near 800 hPa, which is the maximal level of the E-P flux. The local wave energy generation rate suggests that the increased upper-tropospheric zonal flow directly enhances the upper-tropospheric wave energy at the midlatitudes. Note that the actual baroclinic instability waves accompany a considerable amount of the equatorward E-P flux, which causes extinction of wave energy in the subtropical upper troposphere.


2016 ◽  
Vol 144 (5) ◽  
pp. 054302 ◽  
Author(s):  
Y. Finkelstein ◽  
R. Moreh ◽  
S. L. Shang ◽  
Ya. Shchur ◽  
Y. Wang ◽  
...  

1991 ◽  
Vol 05 (18) ◽  
pp. 2935-2949
Author(s):  
M. BARTKOWIAK ◽  
K.A. CHAO

The self-consistently renormalized high-density expansion (SHDE) is first used to determine temperature dependence of order parameter. Free energy and magnetization of the Ising model has been calculated to the second order. It is shown that the unphysical discontinuity of the order parameter as a function of temperature, which appears in the first-order approximation, still remains in the second-order calculation. Based on the 1/d expansion, we then construct a method to select (1/z)i contributions from the high density expansion terms. This method is applied to the first and second-order self-consistent equation for magnetization. Selection of the first order in 1/z contributions within the first order of the SHDE leads to considerable improvement of the behavior of magnetization as a function of temperature, and application of the local approximation to the second order of the SHDE term gives an acceptable single-value behavior of the order parameter.


Author(s):  
Jin-Song von Storch

The energetics considerations based on Lorenz’s available potential energy A focus on identification and quantification of processes capable of converting external energy sources into the kinetic energy of atmospheric and oceanic general circulations. Generally, these considerations consist of: (a) identifying the relevant energy compartments from which energy can be converted against friction to kinetic energy of motions of interests; (b) formulating for these energy compartments budget equations that describe all possible energy pathways; and (c) identifying the dominant energy pathways using realistic data. In order to obtain a more detailed description of energy pathways, a partitioning of motions, for example, into a “mean” and an “eddy” component, or into a diabatic and an adiabatic component, is used. Since the budget equations do not always suggest the relative importance of all possible pathways, often not even the directions, data that describe the atmospheric and the oceanic state in a sufficiently accurate manner are needed for evaluating the energy pathways. Apart from the complication due to different expressions of A, ranging from the original definition by Lorenz in 1955 to its approximations and to more generally defined forms, one has to balance the complexity of the respective budget equations that allows the evaluation of more possible energy pathways, with the quality of data available that allows sufficiently accurate estimates of energy pathways. With regard to the atmosphere, our knowledge, as inferred from the four-box Lorenz energy cycle, has consolidated in the last two decades, by, among other means, using data assimilation products obtained by combining observations with realistic atmospheric general circulation models (AGCMs). The eddy kinetic energy, amounting to slightly less than 50% of the total kinetic energy, is supported against friction through a baroclinic pathway “fueled” by the latitudinally dependent diabatic heating. The mean kinetic energy is supported against friction by converting eddy kinetic energy via inverse cascades. For the ocean, our knowledge is still emerging. The description through the four-box Lorenz energy cycle is approximative and was only estimated from a simulation of a 0.1° oceanic general circulation models (OGCM) realistically forced at the sea surface, rather than from a data assimilation product. The estimates obtained so far suggest that the oceanic eddy kinetic energy, amounting almost 75% of the total oceanic kinetic energy, is supported against friction through a baroclinic pathway similar to that in the atmosphere. However, the oceanic baroclinic pathway is “fueled” to a considerable extent by converting mean kinetic energy supported by winds into mean available potential energy. Winds are also the direct source of the kinetic energy of the mean circulation, without involving noticeable inverse cascades from transients, at least not for the ocean as a whole. The energetics of oceanic general circulation can also be examined by separating diabatic from adiabatic processes. Such a consideration is thought to be more appropriate for understanding the energetics of the oceanic meridional overturning circulation (MOC), since this circulation is sensitive to density changes induced by diabatic mixing. Further work is needed to quantify the respective energy pathways using realistic data.


2019 ◽  
Vol 141 (4) ◽  
Author(s):  
Xiaoling Jin ◽  
M. Z. Q. Chen ◽  
Zhilong Huang

This paper concentrates on the random vibration suppression of a regular straight beam by using an inerter-based dynamic vibration absorber. For a wideband random point-driven straight beam with an inerter-based dynamic vibration absorber, the distribution of mean-square velocity response along the axis of the straight beam as well as the mean kinetic energy of the whole beam are first analytically derived through the classical linear random vibration theory. Two optimization objectives are established to determine the optimal design parameters: (1) minimizing the maximal mean-square velocity along the axis of the straight beam, which corresponds to the maximal mean kinetic energy density along the axis and (2) minimizing the mean kinetic energy of the whole beam. Numerical search gives the optimal location and the associated optimal parameters of the inerter-based dynamic vibration absorber. Numerical results for a simply supported straight beam illustrate the better performance of an inerter-based dynamic vibration absorber than a traditional dynamic vibration absorber. Parametric sensitivity studies for the robustness analysis of the beam response to deviations from the optimal parameters are conducted. The optimal location locates on the force-excited point, while the suboptimal location locates on its symmetry position. Furthermore, the optimal and suboptimal locations remain invariable regardless of the upper cutoff frequency of band-limited noise, which is fairly important to the location optimization of the inerter-based dynamic vibration absorber.


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