Flame-retardant corrugated paper/epoxy composite materials

2019 ◽  
Vol 33 (14n15) ◽  
pp. 1940004
Author(s):  
Jieng-Chiang Chen ◽  
Bo-Yan Huang
Keyword(s):  
Composite Materials ◽  
Water Absorption ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Room Temperature ◽  
Epoxy Composite ◽  
Composite Panels ◽  
Sandwich Composites ◽  
Flame Retardant Properties ◽  
Corrugated Paper

The waterproof and flame-retardant properties of corrugated paper (CP) reinforced epoxy resin sandwich composites are discussed. Two composites, a CP-reinforced epoxy composite (CP/E composite) and a CP-reinforced flame-retardant epoxy composite (CP/FRE composite), were developed in this study. A dipping bath was developed for impregnating the paper with epoxy and a flame-retardant epoxy solution to make the CP/P and CP/FRE composite panels. A room-temperature-cured epoxy resin was blended with various contents (10%, 20%, and 30%) of phosphorus-based flame-retardant compounds and then was used as a matrix to make CP/FRE-10, CP/FRE-20, and CP/FRE-30 composite materials. Water absorption tests of these composites were used to estimate the waterproof properties. In addition, vertical and horizontal burning tests were used to evaluate the flame-retardant properties of the composites.

Improved flame retardant properties of epoxy resin by fluorinated MMT/MWCNT additives

2010 ◽  
Vol 89 (2) ◽  
pp. 225-232 ◽  
Author(s):  
Ji Sun Im ◽  
Sung Kyu Lee ◽  
Se Jin In ◽  
Young-Seak Lee
Keyword(s):  
Flame Retardant ◽  
Epoxy Resin ◽  
Flame Retardant Properties

scholarly journals Synthesis of K-Carrageenan Flame-Retardant Microspheres and Its Application for Waterborne Epoxy Resin with Functionalized Graphene

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1708 ◽  
Author(s):  
Wang ◽  
Teng ◽  
Yang ◽  
You ◽  
Zhang ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Epoxy Resin ◽  
Oxygen Index ◽  
Functionalized Graphene ◽  
Limiting Oxygen Index ◽  
Gas Source ◽  
Waterborne Epoxy ◽  
Emulsion Polymerizations ◽  
Flame Retardant Properties ◽  
Waterborne Epoxy Resin

In this article, the intumescent flame-retardant microsphere (KC-IFR) was prepared by inverse emulsion polymerizations, with the use of k-carrageenan (KC) as carbon source, ammonium polyphosphate (APP) as acid source, and melamine (MEL) as gas source. Meanwhile, benzoic acid functionalized graphene (BFG) was synthetized as a synergist. A “four-source flame-retardant system” (KC-IFR/BFG) was constructed with KC-IFR and BFG. KC-IFR/BFG was blended with waterborne epoxy resin (EP) to prepare flame-retardant coatings. The effects of different ratios of KC-IFR and BFG on the flame-retardant properties of EP were investigated. The results showed that the limiting oxygen index (LOI) values increased from 19.7% for the waterborne epoxy resin to 28.7% for the EP1 with 20 wt% KC-IFR. The addition of BFG further improved the LOI values of the composites. The LOI value reached 29.8% for the EP5 sample with 18 wt% KC-IFR and 2 wt% BFG and meanwhile, UL-94 test reached the V-0 level. In addition, the peak heat release (pHRR) and smoke release rate (SPR) of EP5 decreased by 63.5% and 65.4% comparing with EP0, respectively. This indicated the good flame-retardant and smoke suppression property of EP composites coating.

Research Progress of Heat Hv Insulation Resistance of Macromolecular Composite Materials

2011 ◽  
Vol 391-392 ◽  
pp. 332-335
Author(s):  
Yong Peng Yu
Keyword(s):  
Composite Materials ◽  
Heat Resistance ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
High Performance ◽  
Research Progress ◽  
Insulation Resistance ◽  
Excellent Performance ◽  
Wet Heat

Epoxy resin (EP) with excellent performance was widely used as electronic encapsulation materials, but the traditional EP can not meet require of nowadays electronic encapsulation materials in wet-heat resistance, flame retardant, insulation and other performance. So the current research progress of EP with wet-heat resistance and high-performance was summarized in the field of electronic encapsulation.

scholarly journals Preparation of Intercalated Organic Montmorillonite DOPO-MMT by Melting Method and Its Effect on Flame Retardancy to Epoxy Resin

Polymers ◽  
2021 ◽  
Vol 13 (20) ◽  
pp. 3496
Author(s):  
Junming Geng ◽  
Jianyu Qin ◽  
Jiyu He
Keyword(s):  
Electron Microscopy ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Flame Retardancy ◽  
Flame Retardants ◽  
Characterization Methods ◽  
Melting Method ◽  
Organic Montmorillonite ◽  
Ul 94 ◽  
Flame Retardant Properties

An intercalated organic montmorillonite DOPO-MMT was prepared through the melting method using 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) as a modifier. Epoxy resin (EP) composites were prepared with DOPO-MMT, DOPO, MMT, and the physical mixtures of DOPO+MMT as flame retardants. The microstructure of the flame retardants and EP samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The flame retardant properties, thermal stability, and residual char structure of the EPs were studied by the limited oxygen index (LOI) test, the UL-94 vertical burning test, thermogravimetric analysis (TGA), the differential scanning calorimeter (DSC) test, the cone calorimeter (CONE) test as well as other characterization methods. The results showed that the intercalated organic montmorillonite DOPO-MMT can be successfully prepared by the melting method and that the MMT is evenly dispersed in the EP/DOPO-MMT composite in the form of nanosheets. The EP/DOPO-MMT nanocomposites showed the optimal flame retardancy (LOI, UL-94, PHRR, etc.) among the EPs with DOPO, MMT, and the physical mixture of DOPO+MMT. The flame-retardant grade of the material reached V-0.

scholarly journals Effects of a Macromolecule Spirocyclic Inflatable Flame Retardant on the Thermal and Flame Retardant Properties of Epoxy Resin

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 132 ◽  
Author(s):  
Kunpeng Song ◽  
Yinjie Wang ◽  
Fang Ruan ◽  
Jiping Liu ◽  
Nianhua Li ◽  
...  
Keyword(s):  
Heat Release ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Phosphorus Oxychloride ◽  
Raw Materials ◽  
Smoke Suppression ◽  
Step Method ◽  
Scanning Calorimetry ◽  
New Strategy ◽  
Flame Retardant Properties

A new strategy for the preparation of an integrated three-source intumescent flame retardant (IFR) has been developed to improve the flame-retardant and smoke suppression performance of epoxy resin (EP) with a synergistic flame retardant effect. Herein, the synthesis of a macromolecular spirocyclic phosphorus/nitrogen-containing IFR poly sulfonamide spirocyclic pentaerythritol bisphosphonate (SAPC) is reported via a two-step method that uses pentaerythritol, phosphorus oxychloride and sulfonamide (SAA) as raw materials. Subsequently, the SAPC was incorporated into EP to prepare the composite to investigate its thermal stability, flame retardancy, and smoke suppression performance. Herein, a differential scanning calorimetry (DSC) analysis showed that the addition of SAPC increased the glass transition temperature (Tg) of the composite. Cone test results indicated that the incorporation of 8 wt % SAPC significantly improved the flame-retardant performance for the composite, with a 43.45% decrease in peak of heat release rate, a 28.55% reduction in total heat release, and a 30.04% decrease in total smoke release. Additionally, the composite received the V-0 rating in a UL-94 vertical burning test, accompanied by the “blowout” phenomenon. After the addition of SAPC, the amount of flammable gas products from the EP composite decomposition was obviously suppressed, and the amount of non-flammable as was increased. All of this suggests a good dilution role of SAPC. There are enough reasons to believe that the enhanced flame-retardant and toxicity suppression performance for the EP composite can be attributed to the good coordination of carbonization agent, acid source, and blowing agent in the SAPC structure.

Microstructure and Flexural Property of CaCO3 Whisker Reinforced Epoxy Composite Material

2009 ◽  
Vol 620-622 ◽  
pp. 433-436 ◽  
Author(s):  
Peng Liu ◽  
Hui Cheng Shi ◽  
Hai Yun Jin ◽  
Nai Kui Gao ◽  
Zong Ren Peng
Keyword(s):  
Composite Material ◽  
Composite Materials ◽  
Flexural Strength ◽  
Epoxy Resin ◽  
Epoxy Composite ◽  
Flexural Property ◽  
Pure Epoxy ◽  
Reinforced Composite ◽  
Maximum Value

Reinforcement was performed to epoxy resin by CaCO3 whisker, and the effect of flexural property of CaCO3 whisker reinforced composite materials was studied. The microstructures of the composite materials were observed by SEM. The results showed that the flexural strength of the composites increased with increasing CaCO3 whisker content, and the flexural strength reached to the maximum value when CaCO3 whisker content was about 15wt.%, and the maximum value was about 11% higher than that of pure epoxy resin. But, the strength would drop sharply with the excessive CaCO3 whisker.

Luteolin-based epoxy resin with exceptional heat resistance, mechanical and flame retardant properties

2021 ◽  
pp. 131173
Author(s):  
Tian-Yu Gao ◽  
Fen-Dou Wang ◽  
Yu Xu ◽  
Chun-Xiang Wei ◽  
San-E Zhu ◽  
...  
Keyword(s):  
Heat Resistance ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Flame Retardant Properties

Evaluation of DOPO and Nano-Silica Modified Epoxy Resin Systems as Low Viscous, Flame Retardant Additives for Infusion and Injection Processing of Carbon Fiber Reinforced Plastics

2019 ◽  
Vol 809 ◽  
pp. 3-8
Author(s):  
Markus Häublein ◽  
Karin Peter ◽  
Alexander Brückner ◽  
Volker Altstädt
Keyword(s):  
Carbon Fiber ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Volume Content ◽  
Cone Calorimeter ◽  
Fiber Reinforced ◽  
Fiber Volume ◽  
Carbon Fiber Reinforced ◽  
Flame Retardant Properties ◽  
Modified Epoxy

In the present study, a low viscous (complex viscosity between 200 to 500 mPas at 60 °C), flame retardant epoxy resin formulation is prepared and transferred to the carbon fiber reinforced plastic (CFRP) laminate using resin transfer molding (RTM) method. For the laminate production, a 12k carbon fiber fabric with an areal weight of 400 g/m2 is used to achieve a fiber volume content of approximately 60 vol % carbon fibers. Subsequently the unmodified laminate is produced, varying carbon fiber volume content to study its effect on flame retardant properties. As additives, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) modified epoxy resin and nanosilica particles delivered in an epoxy novolac masterbatch are added to the neat novolac resin system. The mixture is cured with isophorone diamine (IPDA) and polyetheramine hardener blend, resulting in a glass transition temperature of 104 °C for the unmodified laminate. Flame retardant properties of the materials are tested using cone calorimeter and thermal gravimetrical analysis. In addition, the mechanical behavior of the systems is evaluated via three-point bending method in static and dynamical loadings. In order to get deeper information on the resulting flame retardant mechanisms of the additives, the residual cone calorimeter char is analyzed with scanning electron microscopy, indicating the different flame retardant mechanisms of phosphorous and silica as well as the combination of both additives.

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