SnO2 NANOCRYSTALLITE: NOVEL SYNTHETIC ROUTE FROM DEEP EUTECTIC SOLVENT AND LITHIUM STORAGE PERFORMANCE
2011 ◽
Vol 04
(04)
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pp. 377-381
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Keyword(s):
A new synthetic route to ~4 nm grain-sized SnO 2 was proposed which involved a homogeneous precipitation in a deep eutectic solvent (DES) at room temperature. The white SnO 2 precipitate was obtained from SnCl 2 ⋅ 2 H 2 O dissolved DES by injecting slow drop-wise H 4 N 2 ⋅ H 2 O under stirring. The as-prepared nanocrystalline SnO 2 has a Brunauer–Emmett–Teller surface area of 65.12m2/g with an average Barretl–Joyner–Halenda pore diameter of 3.5 nm. As anode for lithium ion batteries, the nanocrystalline SnO 2 electrode delivered an initial charge capacity as high as 1045 mAh/g and its capacity retention is 58% after 30 cycles.
2017 ◽
Vol 5
(44)
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pp. 23221-23227
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Keyword(s):
Keyword(s):
2018 ◽
Vol 6
(16)
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pp. 7070-7079
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Keyword(s):