SnO2 NANOCRYSTALLITE: NOVEL SYNTHETIC ROUTE FROM DEEP EUTECTIC SOLVENT AND LITHIUM STORAGE PERFORMANCE

2011 ◽  
Vol 04 (04) ◽  
pp. 377-381 ◽  
Author(s):  
C. D. GU ◽  
Y. J. MAI ◽  
J. P. ZHOU ◽  
J. P. TU

A new synthetic route to ~4 nm grain-sized SnO 2 was proposed which involved a homogeneous precipitation in a deep eutectic solvent (DES) at room temperature. The white SnO 2 precipitate was obtained from SnCl 2 ⋅ 2 H 2 O dissolved DES by injecting slow drop-wise H 4 N 2 ⋅ H 2 O under stirring. The as-prepared nanocrystalline SnO 2 has a Brunauer–Emmett–Teller surface area of 65.12m2/g with an average Barretl–Joyner–Halenda pore diameter of 3.5 nm. As anode for lithium ion batteries, the nanocrystalline SnO 2 electrode delivered an initial charge capacity as high as 1045 mAh/g and its capacity retention is 58% after 30 cycles.

Nanoscale ◽  
2018 ◽  
Vol 10 (15) ◽  
pp. 6832-6836 ◽  
Author(s):  
Wei Wang ◽  
Na Wu ◽  
Jin-Ming Zhou ◽  
Feng Li ◽  
Yu Wei ◽  
...  

F-Doped MnWO4 nano-particles were prepared and showed superior lithium storage performance with a high theoretical capacity and a long cycle life, as demonstrated by a capacity retention of more than 85% after cycling for 150 cycles.


2017 ◽  
Vol 5 (44) ◽  
pp. 23221-23227 ◽  
Author(s):  
Hao Wang ◽  
Ziliang Chen ◽  
Yang Liu ◽  
Hongbin Xu ◽  
Licheng Cao ◽  
...  

Hybrid nanocomposites constructed from starfish-like ZnxCo1−xS rooted in porous carbon and strongly coupled carbon nanotubes have been rationally designed and they exhibit excellent lithium-storage performance.


RSC Advances ◽  
2016 ◽  
Vol 6 (29) ◽  
pp. 24366-24372 ◽  
Author(s):  
Fengqi Lu ◽  
Qiang Chen ◽  
Yibin Wang ◽  
Yonghao Wu ◽  
Pengcheng Wei ◽  
...  

The free-standing CC@TiOxNy@SnS2 nanocomposites have been synthesized via two steps hydrothermal process and exhibited excellent lithium storage performance.


2021 ◽  
Vol 248 ◽  
pp. 01040
Author(s):  
Shi Xiaoyan ◽  
Ma Leilei ◽  
Wang Jiantao

Pre-charge as a key step in the battery manufacture processes, which has a great impact on the film-forming properties and electrochemical performances, especially the Li-rich system batteries. As a key influence factor, it is necessary to clarify the effect of pre-charge temperature on battery performance. In this paper, we mainly studied the influence of different pre-charge temperatures (25°C, 40°C, 60°C) on the gas production and electrochemical performance of the batteries. The results show that the increase of the pre-charge temperature will result in the increase of gas production, and the gas components are mainly CO2, H2. After the long-term cycle, the sample under 40°C maintains the highest capacity retention rate, and as the pre-charge temperature increases, the median voltage of the battery can be effectively increased. In addition, compared with room temperature pre-charge, high pre-charge temperature samples have more excellent rate performance.


2020 ◽  
Vol 49 (31) ◽  
pp. 10909-10917
Author(s):  
Li Sun ◽  
Yuanxing Zhang ◽  
Yi Gong ◽  
Haochen Si ◽  
Yan Shi ◽  
...  

Red P was first decorated with Sn and then interwoven into a CNT framework, achieving greatly shortened electron transfer paths and enhanced lithium storage performance.


2020 ◽  
Vol 4 (9) ◽  
pp. 4780-4788 ◽  
Author(s):  
Qiang Ma ◽  
Jiakang Qu ◽  
Xiang Chen ◽  
Zhuqing Zhao ◽  
Yan Zhao ◽  
...  

Low-cost feedstocks and rationally designed structures are the keys to determining the lithium-storage performance and practical applications of Si-based anodes for lithium-ion batteries (LIBs).


2020 ◽  
Vol 56 (55) ◽  
pp. 7629-7632 ◽  
Author(s):  
Xiaoyu Wu ◽  
Chen Qian ◽  
Huayu Wu ◽  
Lin Xu ◽  
Lingli Bu ◽  
...  

Based on the confined growth strategy and hydrogen thermal reduction, we constructed and synthesized uniform yolk–shell structured Sn@NHMCSs, which exhibit high specific capacity and good cycling stability as an anode material in lithium ion batteries.


2019 ◽  
Vol 48 (13) ◽  
pp. 4413-4419 ◽  
Author(s):  
Xuxu Tang ◽  
Ming Liang ◽  
Yanfeng Zhang ◽  
Weiwei Sun ◽  
Yong Wang

A metal–organic-framework template approach was used to fabricate ultrafine ternary metal oxide nanoparticles embedded in CNTs, which exhibit larger-than-theoretical reversible capacities for lithium-ion batteries.


2018 ◽  
Vol 6 (16) ◽  
pp. 7070-7079 ◽  
Author(s):  
Long Pan ◽  
Zheng-Wei Zhou ◽  
Yi-Tao Liu ◽  
Xu-Ming Xie

A universal strategy is proposed for thein situsynthesis of TiO2(B) nanosheets on pristine carbon nanomaterials. Benefiting from a remarkable synergistic effect, the resulting nanohybrids exhibit superior high-rate lithium storage performance. In this sense, our strategy may open the door to next-generation, high-power and high-energy anode materials for lithium-ion batteries.


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