Polyphase gold mineralisation at the Yaou deposit, French Guiana

2021 ◽  
pp. SP516-2020-29
Author(s):  
Vincent Combes ◽  
Aurélien Eglinger ◽  
Anne-Sylvie Andre-Mayer ◽  
Yoram Teitler ◽  
Arnauld Heuret ◽  
...  
Keyword(s):  
Shear Zone ◽  
French Guiana ◽  
Primary Source ◽  
Gold Deposits ◽  
Low Grade ◽  
Gold Content ◽  
Icp Ms ◽  
Multiple Deformation ◽  
Penetrative Foliation

AbstractThe Yaou deposit, located in French Guiana within the Guiana Shield, is one of the most promising gold deposits of the regional Palaeoproterozoic greenstone belt. It displays numerous quartz monzodiorite bodies aligned along a sinistral shear zone where a five-deformation phases model is established at the camp scale. The ductile D1/2YA phase is responsible for the main penetrative foliation while the D3YA phase is related to shearing. An intrusive event is identified as being pre to syn-D3YA. The following phase D4YA represents a brittle quartz-carbonate veining set hosted preferentially within intrusive bodies and along the shear zone. A local D5YA brecciation event crosscuts the D4YA veins. Among this deformation history, two auriferous events (D3YA and D4YA) control the overall grade of the Yaou gold deposit. More specifically, most of the Au grade is associated with the main economic D4YA veining event, where the gold is visible and linked to Py4 within an ankerite/hematite rich alteration halo. At the microscopic scale, results of in situ analyses using LA-ICP-MS on pyrite show that metasediment-hosted Py0 is a primary source of submicroscopic gold having a low contribution to the total endowment. Py3 shows some gold content due to possible remobilisation of AuD0YA. Gold in Py4 is found as submicroscopic gold, as micro-inclusions and as infilling fractures in association with elements such as Te, Ag and Bi. Most contribution to the Au grade is from micro-inclusions and, to a lesser extent, from free and submicroscopic gold. The ore shoot locations are lithologically controlled for AuD0YA (metasedimentary unit-hosted), structurally controlled (shear zone-hosted) for AuD3YA and rheologically controlled for the AuD4YA (intrusion-hosted). The deposit is clearly polyphase both at the macroscopic and the microscopic scales, invisible gold is associated with As whereas visible gold is observed as inclusions in pyrite with high contents of Ag, Te and Bi. We define an early low-grade enrichment of AuD0YA to AuD3YA followed by a later high-grade event, AuD4YA supporting polyphase mineralisation processes. This study confirms that orogenic gold deposits can be formed by remobilisation and/or new gold inputs during multiple deformation, veining and hydrothermal events.

scholarly journals A NEW GOLD ORE REGION IN TANZANIA

2018 ◽  
pp. 55-59
Author(s):  
V. Mykhailov ◽  
А. Tots
Keyword(s):  
Gold Deposit ◽  
Shear Zone ◽  
Gold Mineralization ◽  
Lake Victoria ◽  
Gold Deposits ◽  
Mobile Belt ◽  
Gold Content ◽  
Gold Ore ◽  
Metallogenic Zone ◽  
The Republic

Tanzania is one of the leading gold mining countries in the world and the discovery of new gold resources on its territory is an actual task. Known gold deposits are concentrated mainly in the northwest of the country, in the metallogenic zone of Lake Victoria, where they are associated with the Archean greenstone belts, and to a lesser extent – in the southwest, in the ore regions of Lupa and Mpanda, confined to the Ubendian Paleoproterozoic mobile belt. With regard to the eastern regions of Tanzania, where the Proterozoic structures of the Uzagaran mobile belt are developed, until recently in this region any significant manifestations of gold mineralization were not known. As a result of our research in the northern part of the Morogoro province of the Republic of Tanzania, a new previously unknown gold deposit Mananila was discovered. It is represented by a large volume, up to 400–450 m long, up to 60–80 m thick, mineralized shear zone over intensely leached and schistosed migmatites, gneisses, amphibolites, penetrated by echelon systems of quartz veins and veinlet, steeply dipping bodies of quartz breccia up to 1.0–1.5 m thick. Gold contents range from 0.61 to 8.11 g/t, the average zone content is 2.5–3.0 g/t. Parallel to the main zone, similar structures are developed on the site, although they are of lower thickness. The forecast resources of the deposit are estimated at 20 tons of gold. 2.8 km to the east from the Mananila field, the recently discovered Mazizi gold deposit is located, and a number of small occurrences of gold are also known in the region. All these objects are located within a large shear zone of the northeastern strike, up to 4–5 km width, over 20 km in length. This serves as the basis for the identification of a new gold ore region in the northern part of the Morogoro province of the United Republic of Tanzania, within the Proterozoic mobile belt of Usagaran, the possible gold content of which has never been previously discussed in geological literature.

Geology of the shear-hosted Brookbank gold prospect in the Beardmore–Geraldton belt, Wabigoon subprovince, Ontario

2007 ◽  
Vol 44 (7) ◽  
pp. 925-946 ◽  
Author(s):  
Jerry C DeWolfe ◽  
Bruno Lafrance ◽  
Greg M Stott
Keyword(s):  
Shear Zone ◽  
Hanging Wall ◽  
Shear Zones ◽  
Gold Deposits ◽  
Iron Formation ◽  
Alteration Zone ◽  
Gold Deposition ◽  
Low Grade ◽  
Metasedimentary Rocks ◽  
Polymictic Conglomerate

The Beardmore–Geraldton belt consists of steeply dipping, intercalated panels of metavolcanic and metasedimentary rocks along the southern margin of the granite–greenstone Wabigoon subprovince in the Archean Superior Province, Ontario. It is an important past-producing gold belt that includes classic epigenetic iron-formation-hosted deposits near Geraldton and turbidite-hosted deposits, north of Beardmore. The Brookbank gold prospect belongs to a third group of related gold deposits that formed along dextral shear zones localized at contacts between panels of metasedimentary and metavolcanic rocks. The Brookbank prospect occurs along a steeply dipping shear zone at the contact between footwall polymictic conglomerate and hanging-wall calc-alkaline arc basalt. Early during shearing the basalt acted as a structural and chemical trap that localized brittle deformation, veining, and gold deposition, ankerite–sericite–chlorite–epidote–pyrite alteration, and the replacement of metamorphic magnetite and ilmenite by gold-bearing pyrite. This produced a low grade (≤5 g/t Au) ankerite-rich alteration zone that extends up to 20 m into the hanging-wall basalt. Later during shearing, gold was deposited within higher grade (≤20 g/t Au) quartz–orthoclase–pyrite alteration zones superimposed on the wider ankerite-rich alteration zone. Auriferous quartz–carbonate veins oriented clockwise and counter-clockwise to the shear zone walls are folded and boudinaged, respectively, consistent with dextral slip along the shear zone. A key finding of the study is that different groups of gold deposits in the belt, including epigenetic iron formation gold deposits near Geraldton, formed during post-2690 Ma regional dextral transpression across the belt.

scholarly journals Early Cambrian U-Pb zircon age and Hf-isotope data from the Guasayán pluton, Sierras Pampeanas, Argentina: implications for the northwestern boundary of the Pampean arc

2016 ◽  
Vol 43 (1) ◽  
pp. 137 ◽  
Author(s):  
Juan A. Dahlquist ◽  
Sebastián O. Verdecchia ◽  
Edgardo G. Baldo ◽  
Miguel A.S. Basei ◽  
Pablo H. Alasino ◽  
...  
Keyword(s):  
Central Area ◽  
Magma Source ◽  
Western Boundary ◽  
Low Grade ◽  
Early Cambrian ◽  
Zircon Age ◽  
Sierras Pampeanas ◽  
Metasedimentary Rocks ◽  
Icp Ms

An Early Cambrian pluton, known as the Guasayán pluton, has been identified in the central area of Sierra de Guasayán, northwestern Argentina. A U-Pb zircon Concordia age of 533±4 Ma was obtained by LA-MC-ICP-MS and represents the first report of robustly dated Early Cambrian magmatism for the northwestern Sierras Pampeanas. The pluton was emplaced in low-grade metasedimentary rocks and its magmatic assemblage consists of K-feldspar (phenocrysts)+plagioclase+quartz+biotite, with zircon, apatite, ilmenite, magnetite and monazite as accessory minerals. Geochemically, the granitic rock is a metaluminous subalkaline felsic granodiorite with SiO2=69.24%, Na2O+K2O=7.08%, CaO=2.45%, Na2O/ K2O=0.71 and FeO/MgO=3.58%. Rare earth element patterns show moderate slope (LaN/YbN=8.05) with a slightly negative Eu anomalies (Eu/Eu*=0.76). We report the first in situ Hf isotopes data (εHft=-0.12 to -4.76) from crystallized zircons in the Early Cambrian granites of the Sierras Pampeanas, helping to constrain the magma source and enabling comparison with other Pampean granites. The Guasayán pluton might provide a link between Early Cambrian magmatism of the central Sierras Pampeanas and that of the Eastern Cordillera, contributing to define the western boundary of the Pampean paleo-arc.

scholarly journals In-situ Lu – Hf geochronology of calcite

2022 ◽  
Author(s):  
Alexander Simpson ◽  
Stijn Glorie ◽  
Martin Hand ◽  
Carl Spandler ◽  
Sarah Gilbert ◽  
...  
Keyword(s):  
Earth Science ◽  
Wide Spectrum ◽  
Low Grade ◽  
Geological Time ◽  
Inductively Coupled ◽  
Great Utility ◽  
Icp Ms ◽  
Science Community ◽  
Ancient Rock

Abstract. The ability to constrain the age of calcite formation is of great utility to the Earth Science community, due to the ubiquity of calcite across a wide spectrum of geological systems. Here, we present the first in-situ laser ablation inductively coupled tandem mass spectrometry (LA-ICP-MS/MS) Lu–Hf ages for calcite, demonstrating geologically meaningful ages for IOCG and skarn mineralisation, carbonatite intrusion and low grade metamorphism. The analysed samples range in age between ca. 0.9 Ga and ca. 2 Ga with uncertainties between 1.4 % and 0.5 % obtained from calcite with Lu concentrations as low as ca. 0.5 ppm. The Lu–Hf system in calcite appears to be able to preserve primary precipitation ages over a significant amount of geological time, although further research is required to constrain the closure temperature. The in-situ approach allows calcite to be rapidly dated while maintaining its petrogenetic context with mineralization and other associated mineral processes. Therefore, LA-ICP-MS/MS Lu–Hf dating of calcite can be used to resolve the timing of complex mineral paragenetic sequences that are a feature of many ancient rock systems.

Unravelling the enigmatic Grampian Shear Zone: In-situ monazite and titanite U-Pb analysis of the juxtaposed Badenoch and Grampian Groups

2021 ◽  
Author(s):  
Lewis Evason ◽  
Anna Bird ◽  
Eddie Dempsey ◽  
Kit Hardman ◽  
Martin Smith ◽  
...  
Keyword(s):  
Shear Zone ◽  
Major Elements ◽  
Metamorphic Rocks ◽  
High Grade ◽  
Icp Ms ◽  
Wide Range ◽  
Caledonian Orogeny ◽  
Detailed Picture ◽  
Spot Analysis

<p>The Grampian Shear Zone (GSZ) represents a highly deformed tectonostratigraphic contact between the Proterozoic metamorphic rocks of the Dalradian Group from the underlying high grade metamorphic Neoproterozoic rocks of the Badenoch Group within the Grampian Highlands. The nature (tectonic suture or palaeo-unconformity), age and structure of the GSZ and indeed the underling Badenoch Group are poorly constrained. Previous studies of the GSZ and synkinematic (intruded during shearing) pegmatites found therein, yielded metamorphic/deformation (and magmatic) ages ranging from c.a. 808 to 440 M. This study reinvestigates this shearzone using in-situ (within section) petrochonological analysis on a range of U-Pb and Rb-Sr chronometers – Monazite, zircon, titanite, rutile and mica. Carrying out this analysis in-situ and using a variety of minerals allows us to directly date deformation fabrics over a wide range of deformation temperatures, giving us a far more detailed picture of the events recorded within these rocks. Large monazite grains (≥100μm) were mapped using in-situ LA-ICP-MS to show within grain variation of major elements and REEs. Monazite U-Pb spot analysis from the GSZ has yielded ages ranging from 784.11 ± 1.2Ma to 442.58 ± 0.58Ma. The same analysis was performed on a sample from the Grampian group which yielded an age of 441.34 ± 037Ma. In addition to this monazite data, in-situ U-Pb Titanite analysis from the Badenoch Group gave ages of 526.96 ± 1.33 Ma from a metabasite sample, with a metasedimentary sample giving a range of titanite U Pb ages from 540 to 460Ma. These age ranges show that the Badnoch Group and the GSZ have recorded a complex polyorogenic history relative to the “simple” overlying Dalradian metasediments. We propose that the Grampian Shear Zone represents a deep-seated Knoydartian (808 to 784Ma) age shear zone within the meso-Neoproterozoic Badenoch Group. This shear zone was then reactivated during the Grampian phase of the Caledonian Orogeny resulting in the tectonic emplacement of the Dalradian metasediments above the Badenoch group.</p>

Early Neoproterozoic Gold Deposits of the Alto Guaporé Province, Southwestern Amazon Craton, Western Brazil

2021 ◽  
Author(s):  
Rodrigo Prudente de Melo ◽  
Marcos Aurélio Farias de Oliveira ◽  
Richard J. Goldfarb ◽  
Craig A. Johnson ◽  
Erin E. Marsh ◽  
...  
Keyword(s):  
Shear Zone ◽  
Isotope Geochemistry ◽  
Shear Zones ◽  
Gold Deposits ◽  
Geochemical Data ◽  
Low Grade ◽  
Reverse Fault ◽  
Southeastern Part ◽  
Hydrous Minerals ◽  
Early Neoproterozoic

Abstract The Alto Guaporé gold province, southwestern Amazon craton, contains gold deposits that have been mined since the beginning of the 18th century and these deposits, together, have modern-day, pre-mining gold resources of at least 1.8 Moz. The ore is associated with quartz vein systems along the southeastern part of the Aguapei belt, a ~35 km wide and ~500 km long, NNW-trending shear zone formed due to reactivation of a terrane-bounding suture. The Aguapei belt evolved by ca. 1150–1100 Ma rifting and deposition of siliciclastic sediments in an aulacogen basin, followed by deformation and low-grade metamorphism of the sedimentary sequences during 1100–900 Ma terrane collision along the craton margin. The deformation was characterized by a compressional regime until ca. 950 Ma and transition to a transpressional setting during the final 50 m.y. The gold deposits are hosted in a variety of structures that are second-order to the main Aguapei shear zone. The Ernesto and Pau-a-Pique deposits are located ~40 km apart and at jogs along the Aguapei belt. They are marginal to pre-ore igneous rocks, with Ernesto hosted in the basal part of the metasedimentary Fortuna Formation that overlies tonalite and Pau-a-Pique at the contact between metasedimentary rocks and diorite. Three deformational phases comprise the compressional (D1 to D2) to transpressional (D3) tectonic events. In the Pau-a-Pique deposit and the deeper level of the Ernesto deposit, the ore-bearing veins are bedding parallel and follow D2 strike-slip and reverse fault zones, respectively. However, the veins formed during D3 reactivation of the older structures by an array of oblique accommodation faults. In contrast, ores at shallower levels of Ernesto, both in discordant and bedding-parallel veins, are hosted within a ~20-m-thick rigid metaconglomerate with associated dilation due to the structural complexity as sedimentary rocks of the Aguapei Group were folded around the dome-shaped roof of the pre-ore tonalite. The ores in both deposits, as well as in many other deposits of the province, are characterized by disseminated and vein-hosted pyrite. Gold occurs mainly as inclusions in the pyrite, with other hydrothermal phases comprising muscovite, Fe-Ti oxides, and minor apatite, chalcopyrite, and galena. Fluid inclusion data, coupled with stable isotope geochemistry and geothermometry, indicate that gold precipitated from a low-salinity, CO2-rich fluid at ~300°C and ~2.5 kbar. The source for the fluid and gold was the interbedded pelites during devolatilization of the Aguapei Group sequence. The aqueous-carbonic fluid inclusions and the narrow range of δ18O values of quartz (12 ± 1‰) from many auriferous veins from the central part of the province represent a regional ore-forming fluid. The broad range of δD for hydrous minerals (–116 to –55‰) reflects influx of small amounts of meteoric water into the steeply dipping shear zones during postgold exhumation. The 40Ar/39Ar geochronology from hydrothermal muscovite indicates a widespread hydrothermal event along the belt between 928 and 920 Ma. Collectively, the geological, geochronological, and geochemical data suggest that metamorphic fluids migrated laterally into and then upward along the Aguapei belt and deposited gold in lower-order structures where strain gradients existed between lithounits. The province has many characteristics of large orogenic gold provinces worldwide and represents a highly prospective and underexplored target region for early Neoproterozoic gold, a time period that generally is not well endowed in gold ores.

scholarly journals Intra-Cystic (In Situ) Mucoepidermoid Carcinoma: A Clinico-Pathological Study of 14 Cases

2020 ◽  
Vol 9 (4) ◽  
pp. 1157
Author(s):  
Saverio Capodiferro ◽  
Giuseppe Ingravallo ◽  
Luisa Limongelli ◽  
Mauro Mastropasqua ◽  
Angela Tempesta ◽  
...  
Keyword(s):  
Alcian Blue ◽  
Tumor Invasion ◽  
Conservative Surgery ◽  
Low Grade ◽  
Mucin Production ◽  
Cystic Component ◽  
Early Growth Phase ◽  
Hematoxylin Eosin

Aims: To report on the clinico-pathological features of a series of 14 intra-oral mucoepidermoid carcinomas showing exclusive intra-cystic growth. Materials and methods: All mucoepidermoid carcinomas diagnosed in the period 1990–2012 were retrieved; the original histological preparations were reviewed to confirm the diagnosis and from selected cases, showing exclusive intra-cystic neoplastic components, additional sections were cut at three subsequent 200 m intervals and stained with Hematoxylin–Eosin, PAS, Mucicarmine and Alcian Blue, to possibly identify tumor invasion of the adjacent tissues, which could have been overlooked in the original histological preparations. Additionally, pertinent findings collected from the clinical charts and follow-up data were analyzed. Results: We identified 14 intraoral mucoepidermoid carcinomas treated by conservative surgery and with a minimum follow up of five years. The neoplasms were located in the hard palate (nine cases), the soft palate (two), the cheek (two) and the retromolar trigone (one). In all instances, histological examination revealed the presence of a single cystic space, containing clusters of columnar, intermediate, epidermoid, clear and mucous-producing cells, the latter exhibiting distinct intra-cytoplasmic mucin production, as confirmed by PAS, Mucicarmine and Alcian Blue stains. The cysts were entirely circumscribed by fibrous connective tissue, and no solid areas or infiltrating tumor cell clusters were detected. Conservative surgical resection was performed in all cases, and no recurrences or nodal metastases were observed during follow up. Conclusions: Mucoepidermoid carcinomas showing prominent (>20%) intra-cystic proliferation currently are considered low-grade tumors. In addition, we also unveil the possibility that mucoepidermoid carcinomas, at least in their early growth phase, may display an exclusive intra-cystic component and might be considered as in situ carcinomas, unable to infiltrate adjacent tissues and metastasize.

scholarly journals Expression of Semaphorin 3A in Malignant and Normal Bladder Tissue: Immunohistochemistry Staining and Morphometric Evaluation

Biology ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 109
Author(s):  
Ilan Bejar ◽  
Jacob Rubinstein ◽  
Jacob Bejar ◽  
Edmond Sabo ◽  
Hilla K Sheffer ◽  
...  
Keyword(s):  
Urothelial Carcinoma ◽  
Carcinoma In Situ ◽  
Urothelial Cancer ◽  
Basal Layer ◽  
Low Grade ◽  
High Grade ◽  
Bladder Tissue ◽  
Normal Bladder ◽  
Normal Bladder Tissue

Introduction: Our previous studies showed elevated levels of Semaphorin3a (Sema3A) in the urine of patients with urothelial cancer compared to healthy patients. The aim of this study was to analyze the extent of Sema3A expression in normal and malignant urothelial tissue using immune-staining microscopic and morphometric analysis. Materials and Methods: Fifty-seven paraffin-embedded bladder samples were retrieved from our pathology archive and analyzed: 14 samples of normal urothelium, 21 samples containing low-grade urothelial carcinoma, 13 samples of patients with high-grade urothelial carcinoma, 7 samples containing muscle invasive urothelial carcinoma, and 2 samples with pure urothelial carcinoma in situ. All samples were immunostained with anti Sema3A antibodies. The area of tissue stained with Sema3A and its intensity were analyzed using computerized morphometry and compared between the samples’ groups. Results: In normal bladder tissue, very light Sema3A staining was demonstrated on the mucosal basal layer and completely disappeared on the apical layer. In low-grade tumor samples, cells in the basal layer of the mucosa were also lightly stained with Sema3A, but Seama3A expression intensified upon moving apically, reaching its highest level on apical cells exfoliating to the urine. In high grade urothelial tumors, Seama3A staining was intense in the entire thickness of the mucosa. In samples containing carcinoma in situ, staining intensity was high and homogenous in all the neoplastic cells. Conclusions: Sema3A may be serve as a potential non-invasive marker of urothelial cancer.

In situ Fe isotopic analyses of fourteen reference materials using a synthetic Cr standard for mass bias and isobaric interference corrections by femtosecond LA-MC-ICP-MS

2021 ◽  
Author(s):  
Lei Xu ◽  
Wen Zhang ◽  
Tao Luo ◽  
Jin-Hui Yang ◽  
Zhaochu Hu
Keyword(s):  
Reference Materials ◽  
Isotope Ratios ◽  
Isobaric Interference ◽  
Analytical Technique ◽  
Mass Bias ◽  
Icp Ms ◽  
Isotopic Analyses

High precise and accurate measurements of Fe isotope ratios for fourteen reference materials from the USGS, MPI-DING and CGSG were successfully carried out using a developed analytical technique by fs...

Sign in / Sign up

Export Citation Format

Share Document