Effect of Forming Gas Furnace Annealing on the Ferroelectricity and Wake-Up Effect of Hf0.5Zr0.5O2 Thin Films

2020 ◽  
Vol 9 (2) ◽  
pp. 024011 ◽  
Author(s):  
Aniruddh Shekhawat ◽  
Glen Walters ◽  
Ching-Chang Chung ◽  
Roberto Garcia ◽  
Yang Liu ◽  
...  
Keyword(s):  
1994 ◽  
Vol 346 ◽  
Author(s):  
M.C. Gust ◽  
L.A. Momoda ◽  
M.L. Mecartney

ABSTRACTThin films of BaTiO3 were prepared by the sol-gel route using barium titanium methoxypropoxide in methoxypropanol. Sols with water of hydrolysis varying between h=0 and h=2 were spun onto (100) Si and Ge coated (100) Si substrates. XRD and analytical TEM were used to study the microstructure and crystallization behavior of these films. Polycrystalline BaTiO3 was obtained by heat treating the films at temperatures between 600 and 750°C using either conventional furnace annealing or rapid thermal annealing. Films prepared from sols having the highest water content tended to crystallize first. The BaTiO3 thin films exhibited a fine grain size on the order of 25–50 nm. No preferred orientation was observed. The effects of the hydrolysis conditions of the sol, the type of heat treatment, and the choice of substrate on the final microstructure of the films are discussed.


2008 ◽  
Vol 205 (8) ◽  
pp. 1745-1748 ◽  
Author(s):  
F. Celegato ◽  
M. Coïsson ◽  
E. Olivetti ◽  
P. Tiberto ◽  
F. Vinai

2021 ◽  
Vol 21 (9) ◽  
pp. 4763-4767
Author(s):  
Yu-Xin Zhang ◽  
Chien-Hung Wu ◽  
Li-Wei Yeh ◽  
Yi-Ming Chen ◽  
Kow-Ming Chang ◽  
...  

Transparent conductive oxide (TCO) semiconductors are attracted considerable attention due to a wide range of applications, such as flat panel display (FPD), touch panels, solar cells, and other optoelectronic devices. Owing to the different carrier conduction paths between n-type and P-type TCOs, the n-type TCO used in TFTs usually have high Ion/Ioff current ratio (>107) and high electron mobility (>10 cm2/V·s), P-type TCO TFTs are both lower than that of n-type one. For complementary circuits design and applications, however, both P-type and n-type semiconductor materials are equally important. For SnO thin films, it is important to adjust the ratio of Sn2+ (SnO P-type) and Sn4+ (SnO2 n-type) in order to modulate the electrical characteristics. In this investigation of post treatment for SnO thin films, both microwave annealing (MWA) and furnace annealing process with 02 ambient are studied. The results show that SnO thin films are optimized at 300 °C, 30 minutes furnace annealing, the P-type SnO/SnO2 thin film shows surface mean roughness 0.168 nm, [Sn2+]/[Sn4+] ratio as 0.838, at least 80% transmittance between 380 nm-700 nm visible light. Withthe results, SnO can be even used to fabricate high performance P-type thin film transistors (TFTs) device for future applications.


1993 ◽  
Vol 321 ◽  
Author(s):  
Seok-Woon Lee ◽  
Yoo-Chan Jeon ◽  
Seung-Ki Joo

ABSTRACTSilicon thin films were deposited by Electron Cyclotron Resonance PECVD using silane as a source gas at room temperature. Deposited films were crystallized either by conventional furnace annealing(FA) or by rapid thermal annealing (RTA) process. The films deposited on SiO2/Si wafer substrates were Amorphous or microcrystalline depending on the microwave power. Deposited films were annealed at 600TC in a furnace. As expected, higher crystallinity was obtained in the case of the Amorphous films than the microcrystalline films after 7.5 hours annealing. It took 15 hours at 600δC for the Amorphous films to reach their maximum crystallinity in case of FA, but it only took 1 second at 900 δC for RTA. In addition, it was shown that RTA can be applied to the rapid crystallization of Amorphous silicon thin films deposited on a fused quartz substrate utilizing a new film structure.


1989 ◽  
Vol 03 (14) ◽  
pp. 1039-1043 ◽  
Author(s):  
VALENTÍN GARCÍA-VÁZQUEZ ◽  
KIM D. POWERS ◽  
J. A. LEAVITT ◽  
L. McINTYRE ◽  
CHARLES M. FALCO

We report the fabrication of YBa 2 Cu 3 O 7−x thin films by a combination of dc triode sputtering from Y and Cu targets, and simultaneous thermal evaporation from a BaF 2 source. A composition near the ideal 1:2:3 stoichiometry, with a resistive transition onset at 92 K and zero resistance at 80 K have been obtained by deposition on SrTiO 3 substrates, followed by furnace annealing.


2012 ◽  
Vol 512-515 ◽  
pp. 1317-1320
Author(s):  
Fann Wei Yang ◽  
Kai Huang Chen ◽  
Chien Min Cheng

We have investigated the structure and ferroelectric properties of the Bi3.25La0.75Ti3O12 (BLT) thin films on SiO2/Si substrate fabricated by sol-gel method. We used the BLT films were annealed at various temperatures of 600, 650, and 700°C for one hour by conventional furnace annealing (CTA). The temperature dependence of leakage currents densities of ferroelectric BLT thin films. The crystalline structure of the prepared BLT thin films was analyzed by X-ray diffraction (XRD). Field emission scanning electron microscopy (FESEM) was used to observe the film thickness and the surface morphology including grain size and porosity. The leakage current density and capacitance of thin film were measured by HP4156C.


2019 ◽  
Vol 677 ◽  
pp. 142-149 ◽  
Author(s):  
Aniruddh Shekhawat ◽  
Glen Walters ◽  
Ching-Chang Chung ◽  
Roberto Garcia ◽  
Yang Liu ◽  
...  
Keyword(s):  

1990 ◽  
Vol 5 (7) ◽  
pp. 1392-1396 ◽  
Author(s):  
A. J. Drehman ◽  
M. W. Dumais ◽  
J. A. Horrigan ◽  
G-C. Wang ◽  
Y-F. Liew

The surface morphology and near-surface chemical composition of high temperature superconducting Y–Ba–Cu–O thin films have been studied by Scanning Electron Microscopy (SEM) and Auger Electron Spectroscopy (AES) depth profiling. These films were fabricated on SrTiO3 substrates by RF diode sputter deposition and subsequent furnace annealing in oxygen. The chemical composition at and near the surface of thin films was found to differ from the bulk composition. At about 500 Å below the surface the Y, Ba, and Cu stoichiometry, as determined by AES, gradually approach that of the film interior. These results suggest that, for furnace annealed films, there may exist a minimum deposited Y–Ba–Cu–O film thickness in which superconductivity is possible. It was also found that the calculated copper concentration determined by AES during depth profiling is significantly lower than its actual value.


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