Localized Corrosion of Lean–Duplex Stainless Steel Reinforcements in Alkaline Solution

Metals ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 529 ◽  
Author(s):  
Federica Zanotto ◽  
Vincenzo Grassi ◽  
Andrea Balbo ◽  
Fabrizio Zucchi ◽  
Cecilia Monticelli

This paper reports the effects of thermal aging between 650 and 850 °C on the localized corrosion behavior of lean duplex stainless steel (LDSS 2404). Critical pitting temperature (CPT) and double loop electrochemical potentiokinetic reactivation (DL-EPR) tests were performed. The localization of pitting attack and intergranular corrosion (IGC) attack after DL-EPR was investigated by optical (OM) and scanning electron microscopy (SEM) and by focused ion beam (FIB) coupled to SEM. Thermal aging caused the precipitation of mainly chromium nitrides at grain boundaries. Aging at 650 °C or short aging times (5 min) at 750 °C caused nitride precipitation mainly at α/α grain boundaries as a result of fast diffusion of chromium in this phase. Aging at 850 °C or aging times from 10 to 60 min at 750 °C also allowed the precipitation at the α/γ interface. Nitrides at γ/γ grain boundaries were observed rarely and only after long aging times (60 min) at 850 °C. Electrochemical tests showed that in as-received samples, pitting attack only affected the α phase. Conversely, in aged samples, pitting and IGC attack were detected close to nitrides in correspondence of α/α and α/γ grain boundaries depending on aging temperatures and times.


CORROSION ◽  
10.5006/3257 ◽  
2019 ◽  
Vol 75 (10) ◽  
pp. 1216-1229 ◽  
Author(s):  
L.H. Guilherme ◽  
P. Reccagni ◽  
A.V. Benedetti ◽  
C.S. Fugivara ◽  
D.L. Engelberg

ASME qualified welding procedures do not guarantee suitable corrosion and passivation properties for lean duplex stainless steel welds. An evaluation of two ASME qualified welding procedures to optimize the corrosion performance of tungsten inert gas (TIG) welded grade 2101 duplex stainless steel using ER2209 weld consumable was conducted. The evolution of the microstructure was examined by optical and electron microscopy, ferrite-scope measurements, and scanning Kelvin probe force microscopy. An electrochemical mini-cell was then used to characterize the electrochemical behavior of different weld regions using the techniques such as the double loop electrochemical potentiokinetic reactivation test, standard potentiodynamic polarization tests, and cyclic potentiodynamic polarization. The fusion line was the most critical zone for localized corrosion for both welding procedures, due to the formation of Cr- and Mo-depleted zones, resulting in the highest degree of sensitization. The best performance was attributed to the weld face, due to the presence of higher Cr and Mo contents, highlighting the pitting corrosion resistance. A heat input range of 1.6 kJ/mm to 1.9 kJ/mm and low current density (WPS 1) indicated better corrosion performance of all weld regions. The electrochemical corrosion response was in all cases related to microstructural characteristics of the weld regions. The influence of weld parameters on microstructure development and corrosion performance is discussed.


CORROSION ◽  
10.5006/3746 ◽  
2021 ◽  
Author(s):  
Víctor Vargas ◽  
Apolinar Albiter-Hernandez ◽  
Marco Dominguez Aguilar ◽  
Gerardo Altamirano-Guerrero ◽  
Cuahtemoc Maldonado

The effect of weld passes and single V grove designs, on the corrosion resistance of dissimilar welds of a low alloy steel and a super-duplex stainless steel, was studied in synthetic brine. Welds were manufactured in argon by gas tungsten arc (GTA) technique and joined by a high nickel wire of super-duplex stainless steel. Samples of weld regions were characterized by composition scans, electrochemical measurements, micro-hardness and scanning electron microscopy. In X52/ER2594, a transition region (TR) of grain boundaries type II and a band of martensite were formed. The base metal of X52 underwent the highest corrosion rate and localized corrosion occurred in the heat affected zone. Interface ER2594/25Cr7Ni and 25Cr7Ni showed the presence of pitting near intermetallics.


2010 ◽  
Vol 50 (2) ◽  
pp. 286-293 ◽  
Author(s):  
Y. L. Fang ◽  
Z. Y. Liu ◽  
W. Y. Xue ◽  
H. M. Song ◽  
L. Z. Jiang

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