scholarly journals Corrosion Assessment of ASME Qualified Welding Procedures for Grade 2101 Lean Duplex Stainless Steel

CORROSION ◽  
10.5006/3257 ◽  
2019 ◽  
Vol 75 (10) ◽  
pp. 1216-1229 ◽  
Author(s):  
L.H. Guilherme ◽  
P. Reccagni ◽  
A.V. Benedetti ◽  
C.S. Fugivara ◽  
D.L. Engelberg
Keyword(s):  
Stainless Steel ◽  
Duplex Stainless Steel ◽  
Potentiodynamic Polarization ◽  
Electrochemical Corrosion ◽  
Localized Corrosion ◽  
Corrosion Performance ◽  
Kelvin Probe ◽  
Lean Duplex Stainless Steel ◽  
Degree Of Sensitization ◽  
Weld Parameters

ASME qualified welding procedures do not guarantee suitable corrosion and passivation properties for lean duplex stainless steel welds. An evaluation of two ASME qualified welding procedures to optimize the corrosion performance of tungsten inert gas (TIG) welded grade 2101 duplex stainless steel using ER2209 weld consumable was conducted. The evolution of the microstructure was examined by optical and electron microscopy, ferrite-scope measurements, and scanning Kelvin probe force microscopy. An electrochemical mini-cell was then used to characterize the electrochemical behavior of different weld regions using the techniques such as the double loop electrochemical potentiokinetic reactivation test, standard potentiodynamic polarization tests, and cyclic potentiodynamic polarization. The fusion line was the most critical zone for localized corrosion for both welding procedures, due to the formation of Cr- and Mo-depleted zones, resulting in the highest degree of sensitization. The best performance was attributed to the weld face, due to the presence of higher Cr and Mo contents, highlighting the pitting corrosion resistance. A heat input range of 1.6 kJ/mm to 1.9 kJ/mm and low current density (WPS 1) indicated better corrosion performance of all weld regions. The electrochemical corrosion response was in all cases related to microstructural characteristics of the weld regions. The influence of weld parameters on microstructure development and corrosion performance is discussed.

scholarly journals Investigation on the Corrosion Behavior of Lean Duplex Stainless Steel 2404 after Aging within the 650–850 °C Temperature Range

Metals ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 529 ◽  
Author(s):  
Federica Zanotto ◽  
Vincenzo Grassi ◽  
Andrea Balbo ◽  
Fabrizio Zucchi ◽  
Cecilia Monticelli
Keyword(s):  
Stainless Steel ◽  
Grain Boundaries ◽  
Duplex Stainless Steel ◽  
Corrosion Behavior ◽  
Thermal Aging ◽  
Focused Ion Beam ◽  
Ion Beam ◽  
Localized Corrosion ◽  
Fast Diffusion ◽  
Lean Duplex Stainless Steel

This paper reports the effects of thermal aging between 650 and 850 °C on the localized corrosion behavior of lean duplex stainless steel (LDSS 2404). Critical pitting temperature (CPT) and double loop electrochemical potentiokinetic reactivation (DL-EPR) tests were performed. The localization of pitting attack and intergranular corrosion (IGC) attack after DL-EPR was investigated by optical (OM) and scanning electron microscopy (SEM) and by focused ion beam (FIB) coupled to SEM. Thermal aging caused the precipitation of mainly chromium nitrides at grain boundaries. Aging at 650 °C or short aging times (5 min) at 750 °C caused nitride precipitation mainly at α/α grain boundaries as a result of fast diffusion of chromium in this phase. Aging at 850 °C or aging times from 10 to 60 min at 750 °C also allowed the precipitation at the α/γ interface. Nitrides at γ/γ grain boundaries were observed rarely and only after long aging times (60 min) at 850 °C. Electrochemical tests showed that in as-received samples, pitting attack only affected the α phase. Conversely, in aged samples, pitting and IGC attack were detected close to nitrides in correspondence of α/α and α/γ grain boundaries depending on aging temperatures and times.

scholarly journals Combating the Tribo-Corrosion of LDX2404 Lean Duplex Stainless Steel by Low Temperature Plasma Nitriding

Lubricants ◽  
2018 ◽  
Vol 6 (4) ◽  
pp. 93 ◽  
Author(s):  
Xiaoying Li ◽  
Wenbo Dou ◽  
Linhai Tian ◽  
Hanshan Dong
Keyword(s):  
Stainless Steel ◽  
Low Temperature ◽  
Duplex Stainless Steel ◽  
Plasma Nitriding ◽  
Nitrided Layer ◽  
Surface Hardness ◽  
Electrochemical Corrosion ◽  
Treatment Temperature ◽  
Temperature Plasma ◽  
Lean Duplex Stainless Steel

A lean duplex stainless steel, LDX2404, was DC plasma nitrided under a range of treatment conditions. The microstructure characterisation evaluation of the treated samples revealed that a dense, super-hard surface layer can be produced by low-temperature (<450 °C) plasma treatments. The original austenite phase became S-phase and the ferrite phase was supersaturated with nitrogen and ε-Fe3N nitride precipitated from it. When plasma nitriding was carried out at above 450 °C, chromium nitrides precipitated in the surface nitrided layer. Compared to the untreated samples, the surface hardness of the lean duplex stainless steel (DSS) is increased up to four times. The dry wear resistance increased when increasing the treatment temperature. In contrast, the low-temperature treated samples showed the best performance in the electrochemical corrosion and corrosion-wear tests; the performance of the high temperature (>450 °C) plasma nitrided samples was found to be significantly worse than that of the untreated material.

Macro and Micro Electrochemical Techniques to Study Influence of Sigma Phase Formation in a Duplex Stainless Steel

2013 ◽  
Vol 794 ◽  
pp. 583-591 ◽  
Author(s):  
B. Sunil Kumar ◽  
Vivekanand Kain
Keyword(s):  
Stainless Steel ◽  
Duplex Stainless Steel ◽  
Pitting Corrosion ◽  
Potentiodynamic Polarization ◽  
Sigma Phase ◽  
Electrochemical Techniques ◽  
Chloride Ion ◽  
Heat Treatments ◽  
Localized Corrosion ◽  
Chromium Depletion

In the present study macro electrochemical (anodic polarization) and micro electrochemical (scanning electrochemical microscopy (SECM) area scan measurements at passive potential) techniques have been used to study the influence of sigma phase and/or the resultant chromium depletion regions on localized corrosion behavior of aged type 2205 duplex stainless steel (DSS) in neutral chloride ion solution. DSS type 2205 was subjected to aging at 750 °C for 30 min, 10 h and 48 h. The formation and growth of the sigma phase with heat treatments was assessed by optical microscopy, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction. The influence of formation of sub-microscopic and bulky sigma phase on intergranular corrosion (IGC) and pitting corrosion was investigated by various electrochemical techniques including electrochemical potentiokinetic reactivation (EPR), potentiodynamic polarization and SECM. Apart from EPR tests, ASTM A 262 Practice B test was carried out to evaluate the presence of chromium depletion regions with heat treatments. The results showed that with increasing aging duration, the degree of sensitization and IGC rates initially increased and then decreased with heat treatment. The pitting potentials decreased continuously with increase in aging duration up to 10 h as assessed by potentiodynamic polarization tests. The SECM area scan measurements showed more metastable pitting corrosion events for 30 min and 10 h aged specimens compared to the 48 h aged specimen at passive potential in 0.1M neutral chloride ion solution.

ZERON 100

Alloy Digest ◽  
1993 ◽  
Vol 42 (11) ◽  
Keyword(s):  
Fracture Toughness ◽  
Stainless Steel ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Duplex Stainless Steel ◽  
Heat Treating ◽  
Super Duplex Stainless Steel ◽  
Corrosion Performance ◽  
Temperature Performance ◽  
Offshore Oil

Abstract ZERON 100 is a super duplex stainless steel which is manufactured to give a guaranteed corrosion performance by using an equation to control the chemistry in those elements which will determine the corrosion resistance of the material. Major usages in seawater applications, particularly offshore oil gathering systems. This datasheet provides information on composition, hardness, and tensile properties as well as fracture toughness. It also includes information on low and high temperature performance as well as heat treating, machining, and joining. Filing Code: SS-555. Producer or source: Weir Material Services Ltd.

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