scholarly journals Eight sages over five centuries share oxygen's discovery

2016 ◽  
Vol 40 (3) ◽  
pp. 370-376 ◽  
Author(s):  
John W. Severinghaus

During the last century, historians have discovered that between the 13th and 18th centuries, at least six sages discovered that the air we breathe contains something that we need and use. Ibn al-Nafis (1213–1288) in Cairo and Michael Servetus (1511–1553) in France accurately described the pulmonary circulation and its effect on blood color. Michael Sendivogius (1566–1636) in Poland called a part of air “the food of life” and identified it as the gas made by heating saltpetre. John Mayow (1641–1679) in Oxford found that one-fifth of air was a special gas he called “spiritus nitro aereus.” Carl Wilhelm Scheele (1742–1786) in Uppsala generated a gas he named “fire air” by heating several metal calcs. He asked Lavoisier how it fit the phlogiston theory. Lavoisier never answered. In 1744, Joseph Priestley (1733–1804) in England discovered how to make part of air by heating red calc of mercury. He found it brightened a flame and supported life in a mouse in a sealed bottle. He called it “dephlogisticated air.” He published and personally told Lavoisier and other chemists about it. Lavoisier never thanked him. After 9 years of generating and studying its chemistry, he couldn't understand whether it was a new element. He still named it “principe oxigene.” He was still not able to disprove phlogiston. Henry Cavendish (1731–1810) made an inflammable gas in 1766. He and Priestley noted that its flame made a dew. Cavendish proved the dew was pure water and published this in 1778, but all scientists called it impossible to make water, an element. In 1783, on June 24th, Lavoisier was urged to try it, and, when water appeared, he realized that water was not an element but a compound of two gases, proving that oxygen was an element. He then demolished phlogiston and began the new chemistry revolution.

Science, medicine and dissent: Joseph Priestley (1733-1804) (papers celebrating the 250th anniversary of the birth of Joseph Priestley together with a catalogue of an exhibition held at the Royal Society and the Wellcome Institute for the History of Medicine) , edited by R. G. W. Anderson & C. Lawrence (pp. ix + 105). Published by Wellcome Trust and Science Museum, London, 1987, £9.95. The contents of this book are described accurately by a title of 18th- century amplitude. Priestley is remembered by chemists as the man who did most to establish the technique of pneumatic chemistry, for his discovery of ‘dephlogisticated air’ or oxygen, and for his refusal to abandon the phlogiston theory when confronted with Lavoisier’s revolution. He is occasionally remembered by physicists for his interest in electricity and optics. He was, however, a man of many other parts and the essays in this book deal, almost entirely, with these other aspects of his thought. Perhaps their scope is best illustrated by brief quotations from each of them since these are sometimes more revealing, in both substance and style, than the titles. They are as follows: C. Lawrence, ‘In this paper I shall outline Priestley’s biography and point to some areas in it where medicine was of importance.’ J. H. Brooke, ‘The paper had its origin in the realisation that I had been studying Whewell and Priestley, with different objects in view, and largely disregarding the stereotypes to which they have often been assimilated. It occurred to me that, despite the obvious problem of chronology, a comparison between their respective apologias for science might be instructive,...’.


2014 ◽  
Vol 307 (11) ◽  
pp. L811-L816 ◽  
Author(s):  
John B. West

Carl Wilhelm Scheele (1742–1786) has an important place in the history of the discovery of respiratory gases because he was undoubtedly the first person to prepare oxygen and describe some of its properties. Despite this, his contributions have often been overshadowed by those of Joseph Priestley and Antoine Lavoisier, who also played critical roles in preparing the gas and understanding its nature. Sadly, Scheele was slow to publish his discovery and therefore Priestley is rightly recognized as the first person to report the preparation of oxygen. This being said, the thinking of both Scheele and Priestley was dominated by the phlogiston theory, and it was left to Lavoisier to elucidate the true nature of oxygen. In addition to his work on oxygen, Scheele was enormously productive in other areas of chemistry. Arguably he discovered seven new elements and many other compounds. However, he kept a low profile during his life as a pharmacist, and he did not have strong links with contemporary prestigious institutions such as the Royal Society in England or the French Académie des Sciences. He was elected to the Royal Swedish Academy of Science but only attended one meeting. Partly as a result, he remains a somewhat nebulous figure despite the critical contribution he made to the history of respiratory gases and his extensive researches in other areas of chemistry. His death at the age of 43 may have been hastened by his habit of tasting the chemicals that he worked on.


Author(s):  
H. Gross ◽  
H. Moor

Fracturing under ultrahigh vacuum (UHV, p ≤ 10-9 Torr) produces membrane fracture faces devoid of contamination. Such clean surfaces are a prerequisite foe studies of interactions between condensing molecules is possible and surface forces are unequally distributed, the condensate will accumulate at places with high binding forces; crystallites will arise which may be useful a probes for surface sites with specific physico-chemical properties. Specific “decoration” with crystallites can be achieved nby exposing membrane fracture faces to water vopour. A device was developed which enables the production of pure water vapour and the controlled variation of its partial pressure in an UHV freeze-fracture apparatus (Fig.1a). Under vaccum (≤ 10-3 Torr), small container filled with copper-sulfate-pentahydrate is heated with a heating coil, with the temperature controlled by means of a thermocouple. The water of hydration thereby released enters a storage vessel.


2018 ◽  
Vol 138 (8) ◽  
pp. 441-448 ◽  
Author(s):  
Norimitsu Takamura ◽  
Nobutaka Araoka ◽  
Seiya Kamohara ◽  
Yuta Hino ◽  
Takuya Beppu ◽  
...  

1999 ◽  
Vol 26 (5-6) ◽  
pp. 584-596 ◽  
Author(s):  
K. Sundaravadivelu ◽  
Prem Kumar Kandaswamy

2008 ◽  
pp. 19-25
Author(s):  
Sumingkrat Sumingkrat ◽  
Hartini Hartini ◽  
Adrian Yusuf
Keyword(s):  

Lim bah industri klor alkali termasuk limbah 83 dari sumber yang spesifik. Pembakaran lirnbah padat industri kimia terpadu, yang memproduksi kaustik soda, VCM dan PVC akan menghasilkan abu. Limbah cair media proses polimerisasi PVC setelah pengendapan disebut spent pure water (SPW). Abu sisa pernbakaran, Solid Waste /ncenerator (SWI) ini dapat dimanfaatkan sebagai adsorben  untuk SPW. Sesuai dengan model Freundlich isoterm, SW! mempunyai daya adsorpsi terhadap biru metilen lebih baik dari pada karbon aktif, dan mampu menurunkan turbiditas SPW sampai sekitar 95%.


2020 ◽  
Author(s):  
Xiangwen Wang ◽  
Dimitrios Toroz ◽  
Seonmyeong Kim ◽  
Simon Clegg ◽  
Gun-Sik Park ◽  
...  

<div> <p>As natural aqueous solutions are far from being pure water, being rich in ions, the properties of solvated ions are of relevance for a wide range of systems, including biological and geochemical environments. We conducted ab initio and classical MD simulations of the alkaline earth metal ions Mg<sup>2+</sup> and Ca<sup>2+</sup> and of the alkali metal ions Li<sup>+</sup>, Na<sup>+</sup>, K<sup>+</sup> and Cs<sup>+</sup> in pure water and electrolyte solutions containing the counterions Cl<sup>–</sup> and SO<sub>4</sub><sup>2–</sup>. Through a detailed analysis of these simulations, this study reports on the effect of solution chemistry (composition and concentration of the solution) to the ion–water structural properties and interaction strength, and to the dynamics, hydrogen bond network, and low-frequency dynamics of the ionic solvation shell. Except for the ion–water radial distribution function, which is weakly dependent on the counter-ions and concentrations, we found that all other properties can be significantly influenced by the chemical characteristics of the solution. Calculation of the velocity autocorrelation function of magnesium ions, for example, shows that chlorine ions located in the second coordination shell of Mg<sup>2+</sup> weaken the Mg(H<sub>2</sub>O)<sub>6</sub><sup>2+</sup> hydration ‘cage’ of the cation. The result reported in this study suggest that ionic solvation shell can be significantly influenced by the interactions between other ions present in solution ions, especially those of opposite charge. In more general terms, the chemical characteristics of the solution, including the balance between ion-solvent and ion-ion interactions, could result in significant differences in behavior and function of the ionic solvation shell.</p> </div>


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